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The mechanism involves two key single-electron reduction steps: first, activation of the C\u2013Cl bond; and second, reduction of the resulting benzylic radical to a benzylic carbanion. This strategy enables efficient activation and alkylation of aryl C\u2013Cl bonds.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01396","type":"journal-article","created":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T13:02:13Z","timestamp":1786626133000},"page":"11797-11808","source":"Crossref","is-referenced-by-count":0,"title":["Visible-Light Photoredox-Catalyzed\nReductive Coupling\nof Heteroaryl Chlorides with Alkenes"],"prefix":"10.1021","volume":"91","author":[{"given":"Yu-Qing","family":"Tang","sequence":"first","affiliation":[{"name":"Yangzhou University , , ,","place":["Yangzhou, P. R. China, 250009"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhong-Yi","family":"Kou","sequence":"additional","affiliation":[{"name":"Yangzhou University , , ,","place":["Yangzhou, P. R. 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