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This transformation can be carried out under mild and additive-free conditions, employing NaNO2 and S8 as the NO source and sulfur source, respectively. A wide variety of \u03b1-dithiophosphinate oximes could be accessed via this method in moderate to good yields, and the reaction showed good tolerance to diverse functional groups.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01493","type":"journal-article","created":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T17:02:11Z","timestamp":1786640531000},"page":"11840-11849","source":"Crossref","is-referenced-by-count":1,"title":["Oximophosphinothiolation\nof Alkenes with Sodium Nitrite,\nElemental Sulfur, and Secondary Arylphosphines"],"prefix":"10.1021","volume":"91","author":[{"given":"Yanan","family":"Hou","sequence":"first","affiliation":[{"name":"Qufu Normal University , , , ,","place":["Qufu, Shandong, P. R. 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