{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,30]],"date-time":"2026-10-30T09:57:59Z","timestamp":1793354279721,"version":"4.5.0"},"reference-count":20,"publisher":"American Chemical Society (ACS)","issue":"43","license":[{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001412","name":"Council of Scientific and Industrial Research, India","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001412","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,30]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A site-selective reaction for the aminomethylation of imidazoheterocycles is developed using photoredox catalysis under mild conditions. A complementary metal free HFIP promoted reaction is also developed which gives corresponding anilines in good yields. Metal free conditions, scalability, less use of triazinanes, use of recyclable solvents, and ease of operation are the advantages of the developed protocol. Mechanistic studies were conducted to elucidate the mechanism underlying the alkylation reactions. Moreover, solvent recycling experiment has also been carried out to highlight the sustainability of the developed protocol.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01570","type":"journal-article","created":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T01:01:18Z","timestamp":1791248478000},"page":"14207-14217","source":"Crossref","is-referenced-by-count":0,"title":["Regioselective Aminomethylation and Benzylation of\n                    <i>N<\/i>\n                    -Heterocycles via Controllable Cleavage of Triazinanes under Ambient Conditions"],"prefix":"10.1021","volume":"91","author":[{"given":"Abhinay S.","family":"Chillal","sequence":"first","affiliation":[{"name":"Indian Institute of Technology Indore , , Khandwa Road , ,","place":["Indore, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Varsha","family":"Kumari","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Indore , , Khandwa Road , ,","place":["Indore, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mahesh","family":"Sasamal","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Indore , , Khandwa Road , ,","place":["Indore, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3224-7281","authenticated-orcid":true,"given":"Umesh A.","family":"Kshirsagar","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Indore , , Khandwa Road , ,","place":["Indore, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,5]]},"reference":[{"issue":"1","key":"2026103005081655300_cit1","doi-asserted-by":"publisher","DOI":"10.2174\/18741045-v16-e2209010","article-title":"A Review on The Medicinal And Industrial Applications of N-Containing Heterocycles","volume":"16","author":"Amin","year":"2022","journal-title":"Open Med. 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