{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T14:08:15Z","timestamp":1789135695180,"version":"build-2803163510"},"reference-count":49,"publisher":"American Chemical Society (ACS)","issue":"36","license":[{"start":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T00:00:00Z","timestamp":1788134400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T00:00:00Z","timestamp":1788134400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T00:00:00Z","timestamp":1788134400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001412","name":"Council of Scientific and Industrial Research, India","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001412","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["ANRF\/PAIR\/2025\/000029\/PAIR-A"],"award-info":[{"award-number":["ANRF\/PAIR\/2025\/000029\/PAIR-A"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Quinones are privileged redox-active scaffolds in medicinal chemistry, yet their clinical utility is often limited by poor solubility and nonspecific toxicity. To address this, we developed a stereodivergent, one-pot strategy for the synthesis of quinone\u2013triazole [3 + 2] adducts as structurally defined polyol-based glycohybrids. The tandem process involves nucleophilic addition of 5-azido-2,3-dideoxy glycols to electrophilic 1,4-quinones, followed by intramolecular cycloaddition and proton transfer to furnish the fused products with an acyclic polyol chain. The protocol delivers a broad range of quinone\u2013triazole glycohybrids in good to excellent yields, with high functional group tolerance on both the quinone and glycol components, providing an efficient route to quinone-triazole redox-active small glycohybrids as privileged scaffolds.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01576","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T02:31:31Z","timestamp":1788402691000},"page":"12366-12376","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis of Stereodivergent\nChirally Pure Acyclic\nPolyols Based Quinone\u2013Triazole Glycohybrids as Privileged Scaffolds"],"prefix":"10.1021","volume":"91","author":[{"given":"Kavita","family":"Singh","sequence":"first","affiliation":[{"name":"Jawaharlal Nehru University , , - ,","place":["New Delhi, India, 110067"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yogesh","family":"Yadav","sequence":"additional","affiliation":[{"name":"Jawaharlal Nehru University , , - ,","place":["New Delhi, India, 110067"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ram","family":"Sagar","sequence":"additional","affiliation":[{"name":"Jawaharlal Nehru University , , - ,","place":["New Delhi, India, 110067"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,31]]},"reference":[{"key":"2026091109115677600_cit1a","doi-asserted-by":"publisher","first-page":"452","DOI":"10.1002\/anie.200604045","article-title":"Organic Electronics The Larger Acenes: Versatile Organic\nSemiconductors","volume":"47","author":"Anthony","year":"2008","journal-title":"Angew. 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