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The reaction proceeds smoothly over a broad range of substrates with excellent regioselectivity, affording the corresponding selenium-containing quinoline derivatives in good to high yields. The protocol does not require external ligands, is amenable to scale-up, and tolerates a wide variety of functional groups. Preliminary synthetic applications demonstrate the potential utility of this method in medicinal chemistry.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01719","type":"journal-article","created":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T22:12:45Z","timestamp":1788214365000},"page":"12084-12094","source":"Crossref","is-referenced-by-count":0,"title":["Palladium(II)-Catalyzed\nRegioselective C(sp3)\u2013H Selenylation of 8-Methylquinoline\nDerivatives"],"prefix":"10.1021","volume":"91","author":[{"given":"Xiaochun","family":"Cao","sequence":"first","affiliation":[{"name":"Chengdu University , , ,","place":["Chengdu, People\u2019s Republic of China, 610106"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ran","family":"He","sequence":"additional","affiliation":[{"name":"Chengdu University , , ,","place":["Chengdu, People\u2019s Republic of China, 610106"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengcui","family":"Xiong","sequence":"additional","affiliation":[{"name":"Chengdu University , , ,","place":["Chengdu, People\u2019s Republic of China, 610106"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9690-3639","authenticated-orcid":true,"given":"Wenbo","family":"Ma","sequence":"additional","affiliation":[{"name":"Chengdu University , , ,","place":["Chengdu, People\u2019s Republic of China, 610106"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6786-5947","authenticated-orcid":true,"given":"Linghui","family":"Gu","sequence":"additional","affiliation":[{"name":"Chengdu University , , ,","place":["Chengdu, People\u2019s Republic of China, 610106"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,25]]},"reference":[{"key":"2026090408100016600_cit1a","doi-asserted-by":"publisher","first-page":"8103","DOI":"10.1039\/D1DT04371D","article-title":"Organosulphur and organoselenium\ncompounds as emerging building blocks for catalytic systems for O-arylation of phenols, a C\u2013O coupling reaction","volume":"51","author":"Sharma","year":"2022","journal-title":"Dalton Trans."},{"key":"2026090408100016600_cit1b","doi-asserted-by":"publisher","first-page":"8852","DOI":"10.1039\/C9NJ00964G","article-title":"Organoselenium\nsmall molecules as catalysts for the oxidative functionalization of\norganic molecules","volume":"43","author":"Rathore","year":"2019","journal-title":"New J. 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