{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:43:45Z","timestamp":1792784625374,"version":"4.5.0"},"reference-count":63,"publisher":"American Chemical Society (ACS)","issue":"40","license":[{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100014768","name":"Jiaxing University","doi-asserted-by":"publisher","award":["CD70523032"],"award-info":[{"award-number":["CD70523032"]}],"id":[{"id":"10.13039\/501100014768","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22001096"],"award-info":[{"award-number":["22001096"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Project of Jiaxing Science and Technology Plan-Special Project for Young Scientific and Technological Talents","award":["2023AY40031"],"award-info":[{"award-number":["2023AY40031"]}]},{"name":"Qin Shen Scholar Program of Jiaxing University","award":["CD70623026"],"award-info":[{"award-number":["CD70623026"]}],"id":[{"id":"https:\/\/ror.org\/00j2a7k55","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A visible-light-induced phosphonium salt catalyzed approach to site-selective aromatic C\u2013H halogenation and chalcogenation of arenes and heteroarenes is described. In this system, readily available phosphorus catalysts interact in situ with commercial halogenating and chalcogenating reagents to generate photoactive phosphonium salt species, which upon visible-light irradiation enable direct aromatic C\u2013H chlorination, bromination, iodination, thiocyanation, selenocyanation, and trifluoromethylthiolation under mild conditions. The method avoids transition-metal participation and shows good site selectivity across a range of arenes and heteroarenes, including amino acid derivatives and selected bioactive molecules. Mechanistic experiments support the involvement of electron donor\u2013acceptor (EDA) complex formation between the phosphine catalyst and the functionalization reagent, followed by photoinduced radical generation. This study establishes a visible-light phosphonium salt catalysis platform for the site-selective functionalization of aromatic frameworks relevant to amino acid derivatives and bioactive molecules.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01742","type":"journal-article","created":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T03:02:29Z","timestamp":1790305349000},"page":"13475-13481","source":"Crossref","is-referenced-by-count":0,"title":["Visible-Light-Induced\nPhosphonium Salt Catalysis for\nSite-Selective Aromatic C\u2013H Halogenation and Chalcogenation"],"prefix":"10.1021","volume":"91","author":[{"given":"Jiazhen","family":"Li","sequence":"first","affiliation":[{"name":"Zhejiang Sci-Tech University , , ,","place":["Hangzhou, P. R. China, 310018"]},{"name":"Jiaxing University , , 118 Jiahang Road , ,","place":["Jiaxing, P. R. China, 314001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhongmei","family":"Wang","sequence":"additional","affiliation":[{"name":"Zhejiang Sci-Tech University , , ,","place":["Hangzhou, P. R. China, 310018"]},{"name":"Jiaxing University , , 118 Jiahang Road , ,","place":["Jiaxing, P. R. China, 314001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen","family":"Gu","sequence":"additional","affiliation":[{"name":"Jiaxing University , , 118 Jiahang Road , ,","place":["Jiaxing, P. R. China, 314001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingyu","family":"Liu","sequence":"additional","affiliation":[{"name":"Jiaxing University , , 118 Jiahang Road , ,","place":["Jiaxing, P. R. China, 314001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meixing","family":"Xie","sequence":"additional","affiliation":[{"name":"Jiaxing University , , 118 Jiahang Road , ,","place":["Jiaxing, P. R. China, 314001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenhao","family":"Liang","sequence":"additional","affiliation":[{"name":"Jiaxing University , , 118 Jiahang Road , ,","place":["Jiaxing, P. R. China, 314001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7790-680X","authenticated-orcid":true,"given":"Shihui","family":"Liu","sequence":"additional","affiliation":[{"name":"Zhejiang Sci-Tech University , , ,","place":["Hangzhou, P. R. China, 310018"]},{"name":"Jiaxing University , , 118 Jiahang Road , ,","place":["Jiaxing, P. R. China, 314001"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,24]]},"reference":[{"key":"2026100909092217500_cit1","doi-asserted-by":"publisher","first-page":"7532","DOI":"10.1021\/acs.chemrev.8b00077","article-title":"Photoredox Catalysis for Building\nC\u2013C Bonds from C(sp2)\u2013H Bonds","volume":"118","author":"Wang","year":"2018","journal-title":"Chem. Rev."},{"key":"2026100909092217500_cit2","doi-asserted-by":"publisher","first-page":"2399","DOI":"10.1021\/jacs.1c10783","article-title":"A Perspective on Late-Stage Aromatic\nC\u2013H Bond\nFunctionalization","volume":"144","author":"Zhang","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026100909092217500_cit3","doi-asserted-by":"publisher","first-page":"6122","DOI":"10.1039\/D5CS00165J","article-title":"Metal-catalysed non-directed\nC(sp2)\u2013H bond activation","volume":"54","author":"Agrawal","year":"2025","journal-title":"Chem. Soc. Rev."},{"key":"2026100909092217500_cit4","doi-asserted-by":"publisher","first-page":"1041","DOI":"10.1039\/D4SC07491B","article-title":"Photocatalytic regioselective\nC\u2013H bond functionalizations in arenes","volume":"16","author":"Hu","year":"2025","journal-title":"Chem. Sci."},{"key":"2026100909092217500_cit5","doi-asserted-by":"publisher","first-page":"1767","DOI":"10.1021\/acs.accounts.5b00057","article-title":"Methods\nand Mechanisms for Cross-Electrophile Coupling of Csp2 Halides\nwith Alkyl Electrophiles","volume":"48","author":"Weix","year":"2015","journal-title":"Acc. Chem. Res."},{"key":"2026100909092217500_cit6","doi-asserted-by":"publisher","first-page":"6837","DOI":"10.1021\/acs.chemrev.5b00400","article-title":"Use of Bromine\nand Bromo-Organic\nCompounds in Organic Synthesis","volume":"116","author":"Saikia","year":"2016","journal-title":"Chem. Rev."},{"key":"2026100909092217500_cit7","doi-asserted-by":"publisher","first-page":"8169","DOI":"10.1039\/D1GC02602J","article-title":"Pd-Catalysed Suzuki\u2013Miyaura\ncross-coupling of\naryl chlorides at low catalyst loadings in water for the synthesis\nof industrially important fungicides","volume":"23","author":"Orecchia","year":"2021","journal-title":"Green\nChem."},{"key":"2026100909092217500_cit8","doi-asserted-by":"publisher","first-page":"581","DOI":"10.1021\/acs.orglett.2c03956","article-title":"Selective\nFluorosulfonylation of Thianthrenium Salts Enabled by Electrochemistry","volume":"25","author":"Kong","year":"2023","journal-title":"Org. Lett."},{"key":"2026100909092217500_cit9","doi-asserted-by":"publisher","first-page":"1951","DOI":"10.1021\/acs.accounts.4c00242","article-title":"Recent Advances in Halogen\u2013Metal\nExchange Reactions","volume":"57","author":"Wei","year":"2024","journal-title":"Acc. Chem. Res."},{"key":"2026100909092217500_cit10","doi-asserted-by":"publisher","first-page":"13058","DOI":"10.1039\/D4SC04461D","article-title":"Thianthrene\/TfOH-catalyzed\nelectrophilic halogenations\nusing N-halosuccinimides as the halogen source","volume":"15","author":"Shi","year":"2024","journal-title":"Chem. Sci."},{"key":"2026100909092217500_cit11","doi-asserted-by":"publisher","first-page":"47751","DOI":"10.1021\/jacs.5c18031","article-title":"Electrochemical\nDehydroxymethylative Functionalization of Unactivated\nAlcohols via Criegee\u2013Kolbe Radical Relay","volume":"147","author":"Chen","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026100909092217500_cit12","doi-asserted-by":"publisher","first-page":"2832","DOI":"10.1021\/jm401375q","article-title":"Data-Mining for Sulfur and Fluorine:\nAn Evaluation of Pharmaceuticals To Reveal Opportunities for Drug\nDesign and Discovery","volume":"57","author":"Ilardi","year":"2014","journal-title":"J. Med. Chem."},{"key":"2026100909092217500_cit13","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2025.118007","article-title":"Synthetic strategies\nand therapeutic applications of\nsulfur-containing molecules","volume":"298","author":"Shamsudin","year":"2025","journal-title":"Eur. J. Med. Chem."},{"key":"2026100909092217500_cit14","doi-asserted-by":"publisher","DOI":"10.1016\/j.bioorg.2024.107149","article-title":"Synthesis, antitumor activity evaluation\nof 2-selenocyano-3-selenocyanoalkyloxyestradiols with a bisselenocyanate\nstructure","volume":"144","author":"Huang","year":"2024","journal-title":"Bioorg. Chem."},{"key":"2026100909092217500_cit15","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmcl.2025.130533","article-title":"Synthesis and biological\nactivity evaluation of aromatic bisselenocyanate compounds","volume":"133","author":"Cai","year":"2026","journal-title":"Bioorg. Med. Chem. Lett."},{"key":"2026100909092217500_cit16","doi-asserted-by":"publisher","first-page":"13169","DOI":"10.1021\/acs.joc.3c01373","article-title":"Trifluoromethylthiolation\nof Tryptophan and Tyrosine Derivatives: A Tool for Enhancing the Local\nHydrophobicity of Peptides","volume":"88","author":"Gregorc","year":"2023","journal-title":"J. Org. Chem."},{"key":"2026100909092217500_cit17","doi-asserted-by":"publisher","first-page":"8473","DOI":"10.1021\/acs.joc.6c00904","article-title":"Incorporation\nof the Trifluoromethylthio Group (CF3S\u2212) into Biomolecules:\nA Versatile Tool for Advancing Life Sciences","volume":"91","author":"Gregorc","year":"2026","journal-title":"J. Org. Chem."},{"key":"2026100909092217500_cit18","doi-asserted-by":"publisher","first-page":"8003","DOI":"10.1021\/acs.chemrev.6b00089","article-title":"Modern Transition-Metal-Catalyzed Carbon\u2013Halogen\nBond Formation","volume":"116","author":"Petrone","year":"2016","journal-title":"Chem. Rev."},{"key":"2026100909092217500_cit19","doi-asserted-by":"publisher","first-page":"1571","DOI":"10.1039\/D3OB00019B","article-title":"Recent\nprogress in the oxidative\nbromination of arenes and heteroarenes","volume":"21","author":"Jiang","year":"2023","journal-title":"Org.\nBiomol. Chem."},{"key":"2026100909092217500_cit20","doi-asserted-by":"publisher","first-page":"3161","DOI":"10.1021\/acs.accounts.4c00501","article-title":"Late-Stage\nHalogenation of Complex\nSubstrates with Readily Available Halogenating Reagents","volume":"57","author":"Wang","year":"2024","journal-title":"Acc. Chem. Res."},{"key":"2026100909092217500_cit21","doi-asserted-by":"publisher","first-page":"1580","DOI":"10.1039\/D3OB02012F","article-title":"Recent\nadvances in oxidative chlorination","volume":"22","author":"Cui","year":"2024","journal-title":"Org. Biomol.\nChem."},{"key":"2026100909092217500_cit22","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202402261","article-title":"Halogen and\nChalcogen Activation by Nucleophilic Catalysis","volume":"30","author":"Mondal","year":"2024","journal-title":"Chem. - Eur. J."},{"key":"2026100909092217500_cit23","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.70407","article-title":"C\u2013H Halogenation via Directing Group Strategies With Earth-Abundant\nMetals (Cu, Co, Ni, Fe): Scope, Mechanism, and Limitations","volume":"368","author":"Cheng","year":"2026","journal-title":"Adv. Synth. Catal."},{"key":"2026100909092217500_cit24","doi-asserted-by":"publisher","first-page":"494","DOI":"10.1039\/C5CS00532A","article-title":"Recent advances in\nthe chemistry of organic thiocyanates","volume":"45","author":"Castanheiro","year":"2016","journal-title":"Chem.\nSoc. Rev."},{"key":"2026100909092217500_cit25","doi-asserted-by":"publisher","first-page":"287","DOI":"10.6023\/cjoc201807016","article-title":"Progress on the Synthesis\nand Applications of Thiocyanates","volume":"39","author":"Xu","year":"2019","journal-title":"Chin. J. Org.\nChem."},{"key":"2026100909092217500_cit26","doi-asserted-by":"publisher","first-page":"6145","DOI":"10.1002\/chem.202004974","article-title":"Design and\nUse of Electrophilic Thiocyanating\nand Selenocyanating Reagents: An Interesting Trend for the Construction\nof SCN- and SeCN-Containing Compounds","volume":"27","author":"Gao","year":"2021","journal-title":"Chem.\n- Eur. J."},{"key":"2026100909092217500_cit27","doi-asserted-by":"publisher","first-page":"6508","DOI":"10.1039\/D2OB01018F","article-title":"Recent progress of direct thiocyanation\nreactions","volume":"20","author":"Chen","year":"2022","journal-title":"Org. Biomol. Chem."},{"key":"2026100909092217500_cit28","doi-asserted-by":"publisher","DOI":"10.3390\/molecules29225365","article-title":"Recent Advances\nin the Synthesis of Organic Thiocyano (SCN) and Selenocyano (SeCN)\nCompounds, Their Chemical Transformations and Bioactivity","volume":"29","author":"Abonia","year":"2024","journal-title":"Molecules"},{"key":"2026100909092217500_cit29","doi-asserted-by":"publisher","first-page":"744","DOI":"10.6023\/A17050202","article-title":"Recent Progress on\nDirect Trifluoromethylthiolating\nReagents and Methods","volume":"75","author":"Zhang","year":"2017","journal-title":"Acta Chim. Sin."},{"key":"2026100909092217500_cit30","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.202500029","article-title":"Recent Advances in\nTransition Metal-Catalyzed\/Mediated C\u2013SCF3 Bond\nFormation Reaction","volume":"28","author":"Xu","year":"2025","journal-title":"Eur. J. Org.\nChem."},{"key":"2026100909092217500_cit31","doi-asserted-by":"publisher","first-page":"2145","DOI":"10.1021\/jo00212a029","article-title":"Regioselective\npara-chlorination of activated aromatic compounds","volume":"50","author":"Watson","year":"1985","journal-title":"J. Org. Chem."},{"key":"2026100909092217500_cit32","doi-asserted-by":"publisher","first-page":"2605","DOI":"10.1016\/S0040-4039(00)87408-0","article-title":"Gas phase reactions of hydroxyl radicals arenes","volume":"23","author":"Mulder","year":"1982","journal-title":"Tetrahedron Lett."},{"key":"2026100909092217500_cit33","doi-asserted-by":"publisher","first-page":"573","DOI":"10.1039\/jr9500000573","article-title":"108. The significance of the bromine\ncation in aromatic\nsubstitution. Part II. Preparative applicability","volume":"153","author":"Derbyshire","year":"1950","journal-title":"J. Chem. Soc."},{"key":"2026100909092217500_cit34","doi-asserted-by":"publisher","first-page":"6908","DOI":"10.1021\/ja5031744","article-title":"Palau\u2019chlor: A Practical and Reactive Chlorinating\nReagent","volume":"136","author":"Rodriguez","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"2026100909092217500_cit35","doi-asserted-by":"publisher","first-page":"14852","DOI":"10.1039\/C5CC05052A","article-title":"CFBSA: a novel\nand practical chlorinating reagent","volume":"51","author":"Lu","year":"2015","journal-title":"Chem. Commun."},{"key":"2026100909092217500_cit36","doi-asserted-by":"publisher","first-page":"1976","DOI":"10.1021\/acs.orglett.6b00547","article-title":"Story of an Age-Old\nReagent: An Electrophilic Chlorination of Arenes\nand Heterocycles by 1-Chloro-1,2-benziodoxol-3-one","volume":"18","author":"Wang","year":"2016","journal-title":"Org. Lett."},{"key":"2026100909092217500_cit37","doi-asserted-by":"publisher","first-page":"5024","DOI":"10.1021\/acs.orglett.1c01530","article-title":"Selective\nC\u2013H\nIodination of (Hetero)arenes","volume":"23","author":"Tanwar","year":"2021","journal-title":"Org. Lett."},{"key":"2026100909092217500_cit38","doi-asserted-by":"publisher","first-page":"1077","DOI":"10.1002\/adsc.201300062","article-title":"Efficient Oxidative\nChlorination of Aromatics on Saturated Sodium Chloride Solution","volume":"355","author":"Gu","year":"2013","journal-title":"Adv. Synth. Catal."},{"key":"2026100909092217500_cit39","doi-asserted-by":"publisher","first-page":"996","DOI":"10.1002\/asia.201600083","article-title":"Aromatic Monochlorination Photosensitized\nby DDQ with Hydrogen Chloride under Visible-Light Irradiation","volume":"11","author":"Ohkubo","year":"2016","journal-title":"Chem. - Asian J."},{"key":"2026100909092217500_cit40","doi-asserted-by":"publisher","first-page":"27","DOI":"10.1002\/ejoc.201801063","article-title":"Regioselective\nOxidative Chlorination\nof Arenols Using NaCl and Oxone","volume":"2019","author":"Uyanik","year":"2019","journal-title":"Eur. J. Org.\nChem."},{"key":"2026100909092217500_cit41","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2022.153929","article-title":"Efficient thiocyanation of aromatic\ncompounds using NH4SCN, DMSO and H2SO4","volume":"101","author":"Abbasi","year":"2022","journal-title":"Tetrahedron Lett."},{"key":"2026100909092217500_cit42","doi-asserted-by":"publisher","first-page":"2425","DOI":"10.6023\/cjoc202212035","article-title":"Transition\nMetal-Free C\u2013H Thiocyanation and\nSelenocyanation Based on Thermochemical, Photocatalytic and Electrochemical\nProcess","volume":"43","author":"Xu","year":"2023","journal-title":"Chin. J. Org. Chem."},{"key":"2026100909092217500_cit43","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.202300132","article-title":"Immobilized\nRose Bengal as Photocatalyst for Metal-Free Thiocyanation of Azaheterocycles\nunder Continuous Flow Conditions","volume":"106","author":"Colombo","year":"2023","journal-title":"Helv. Chim.\nActa"},{"key":"2026100909092217500_cit44","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202203541","article-title":"Diquat Based\nDyes: A New Class of Photoredox Catalysts and Their Use in Aerobic\nThiocyanation","volume":"29","author":"Meier","year":"2023","journal-title":"Chem. - Eur. J."},{"key":"2026100909092217500_cit45","doi-asserted-by":"publisher","DOI":"10.1038\/s42004-025-01831-5","article-title":"Visible-light promoted\nlate-stage\nchlorination and bromination of quinones and (hetero)arenes utilizing\naqueous HCl or HBr as halogen donors","volume":"9","author":"Zhang","year":"2026","journal-title":"Commun.\nChem."},{"key":"2026100909092217500_cit46","doi-asserted-by":"publisher","first-page":"892","DOI":"10.1021\/acs.joc.5c01914","article-title":"Nitrosonium Ion-Catalyzed\nOxidative Chlorination of Arenes","volume":"91","author":"Hsu","year":"2026","journal-title":"J. Org. Chem."},{"key":"2026100909092217500_cit47","doi-asserted-by":"publisher","first-page":"3373","DOI":"10.1002\/ejoc.201600485","article-title":"Highly Efficient and\nPractical Thiocyanation of Imidazopyridines Using an N-Chlorosuccinimide\/NaSCN Combination","volume":"2016","author":"Zhang","year":"2016","journal-title":"Eur.\nJ. Org. Chem."},{"key":"2026100909092217500_cit48","doi-asserted-by":"publisher","first-page":"1081","DOI":"10.1002\/cjoc.201600344","article-title":"Catalytic\nThiourea Promoted Electrophilic Thiocyanation of Indoles and Aromatic\nAmines with NCS\/NH4SCN","volume":"34","author":"Wang","year":"2016","journal-title":"Chin. J.\nChem."},{"key":"2026100909092217500_cit49","doi-asserted-by":"publisher","first-page":"1576","DOI":"10.1021\/acs.joc.7b02850","article-title":"N-Thiocyanatosaccharin:\nA \u201cSweet\u201d Electrophilic Thiocyanation Reagent and the\nSynthetic Applications","volume":"83","author":"Wu","year":"2018","journal-title":"J. Org. Chem."},{"key":"2026100909092217500_cit50","doi-asserted-by":"publisher","first-page":"417","DOI":"10.1016\/j.chempr.2018.11.007","article-title":"Site-Selective\nC\u2013H Functionalization of (Hetero)Arenes via Transient, Non-symmetric\nIodanes","volume":"5","author":"Fosu","year":"2019","journal-title":"Chem"},{"key":"2026100909092217500_cit51","doi-asserted-by":"publisher","first-page":"7131","DOI":"10.1039\/C9OB01340G","article-title":"N-Thiocyanato-dibenzenesulfonimide:\na new electrophilic\nthiocyanating reagent with enhanced reactivity","volume":"17","author":"Li","year":"2019","journal-title":"Org. Biomol. Chem."},{"key":"2026100909092217500_cit52","doi-asserted-by":"publisher","first-page":"7208","DOI":"10.1021\/acs.joc.3c00454","article-title":"Regioselective C\u2013H Thiocyanation\nof Arenes by Iron(III) Chloride Catalysis","volume":"88","author":"Waddell","year":"2023","journal-title":"J.\nOrg. Chem."},{"key":"2026100909092217500_cit53","doi-asserted-by":"publisher","first-page":"8389","DOI":"10.1021\/acs.orglett.5c02079","article-title":"Access to SCF3-Substituted Indolizines via\na Photocatalytic Late-Stage Functionalization Protocol","volume":"27","author":"Stefanoni","year":"2025","journal-title":"Org. Lett."},{"key":"2026100909092217500_cit54","doi-asserted-by":"publisher","first-page":"2257","DOI":"10.1021\/acs.joc.5c03183","article-title":"Regioselective\nIodination of Arenes\nUsing Iron- or Silver-Catalyzed Activation of N-Iodosaccharin","volume":"91","author":"Majhi","year":"2026","journal-title":"J. Org. Chem."},{"key":"2026100909092217500_cit55","doi-asserted-by":"publisher","first-page":"107","DOI":"10.1038\/s41929-019-0398-0","article-title":"DMSO-catalysed late-stage\nchlorination of (hetero)arenes","volume":"3","author":"Song","year":"2020","journal-title":"Nat. Catal."},{"key":"2026100909092217500_cit56","doi-asserted-by":"publisher","first-page":"5879","DOI":"10.1039\/D4GC00486H","article-title":"A solvent-free\nmechanochemical electrophilic C\u2013H thiocyanation of indoles\nand imidazo[1,2-a]pyridines using a cost-effective\ncombination of N-chlorosuccinimide-NaSCN and tandem C\u2013C and\nC\u2013S bond formation","volume":"26","author":"Saha","year":"2024","journal-title":"Green Chem."},{"key":"2026100909092217500_cit57","doi-asserted-by":"publisher","first-page":"1925","DOI":"10.1021\/acs.chemrev.1c00311","article-title":"Photoredox-Catalyzed\nC\u2013H Functionalization Reactions","volume":"122","author":"Holmberg-Douglas","year":"2022","journal-title":"Chem.\nRev."},{"key":"2026100909092217500_cit58","doi-asserted-by":"publisher","first-page":"4237","DOI":"10.1021\/acs.chemrev.2c00478","article-title":"Photocatalytic Late-Stage\nC\u2013H Functionalization","volume":"123","author":"Bellotti","year":"2023","journal-title":"Chem. Rev."},{"key":"2026100909092217500_cit59","doi-asserted-by":"publisher","first-page":"2997","DOI":"10.1016\/j.chempr.2023.06.022","article-title":"Organic charge-transfer\ncomplex induces chemoselective decarboxylation\nto aryl radicals for general functionalization","volume":"9","author":"Hu","year":"2023","journal-title":"Chem"},{"key":"2026100909092217500_cit60","doi-asserted-by":"publisher","first-page":"3433","DOI":"10.1021\/acs.accounts.4c00638","article-title":"Photocatalysis Meets\nCopper Catalysis: A New Opportunity for Asymmetric Multicomponent\nRadical Cross-Coupling Reactions","volume":"57","author":"Wang","year":"2024","journal-title":"Acc. Chem.\nRes."},{"key":"2026100909092217500_cit61","doi-asserted-by":"publisher","first-page":"11143","DOI":"10.1021\/acs.orglett.5c03758","article-title":"Halophosphonium Salts-Mediated Photochemical\nC(sp3)\u2013H Functionalization","volume":"27","author":"Sun","year":"2025","journal-title":"Org. Lett."},{"key":"2026100909092217500_cit62","doi-asserted-by":"publisher","first-page":"18826","DOI":"10.1039\/D5CC04649A","article-title":"Metal- and\nphotocatalyst-free benzylic C\u2013H halogenation via an electron\ndonor\u2013acceptor complex","volume":"61","author":"Cao","year":"2025","journal-title":"Chem. Commun."},{"key":"2026100909092217500_cit63","doi-asserted-by":"publisher","first-page":"2615","DOI":"10.1039\/D5CC06164D","article-title":"Photoinduced benzylic C\u2013H thiocyanation enabled\nby triphenylphosphine oxide and N-thiocyanophthalimide","volume":"62","author":"Wang","year":"2026","journal-title":"Chem. Commun."}],"container-title":["The Journal of Organic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.joc.6c01742","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/joceah\/article-pdf\/91\/40\/13475\/68645665\/acs.joc.6c01742.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/joceah\/article-pdf\/91\/40\/13475\/68645665\/acs.joc.6c01742.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T13:49:22Z","timestamp":1791553762000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/joceah\/article\/91\/40\/13475\/5438072\/Visible-Light-Induced-Phosphonium-Salt-Catalysis"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,24]]},"references-count":63,"journal-issue":{"issue":"40","published-online":{"date-parts":[[2026,9,24]]},"published-print":{"date-parts":[[2026,10,9]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.joc.6c01742","relation":{},"ISSN":["0022-3263","1520-6904"],"issn-type":[{"value":"0022-3263","type":"print"},{"value":"1520-6904","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,24]]}}}