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The conventional Wittig reaction relies on phosphonium salts as carbon synthons, yet their synthesis requires alkyl halides that are often inaccessible for structurally complex substrates. Herein, we employ Cu(I)-photosensitizer catalysis to transform commercially available vinyl phosphonium salt into various elongated Wittig precursors under visible light irradiation, which subsequently react with aldehydes in a one-pot fashion to afford structurally diverse alkenes. This protocol synergistically combines the advantages of photoredox catalysis and the Wittig reaction, operates under mild conditions with excellent functional group tolerance, and accommodates readily available 1,4-dihydropyridines or silicates as modular radical sources, underscoring the practicality and flexibility of this approach.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01921","type":"journal-article","created":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T14:02:10Z","timestamp":1791554530000},"page":"14472-14488","source":"Crossref","is-referenced-by-count":0,"title":["Cu(I)-Photosensitizer Catalysis: A Tool for Conjunctive Olefination of Aldehydes"],"prefix":"10.1021","volume":"91","author":[{"given":"Qinxu","family":"Sun","sequence":"first","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, People\u2019s Republic of China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengjie","family":"Hu","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, People\u2019s Republic of China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yifan","family":"Wang","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, People\u2019s Republic of China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianhao","family":"Lu","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, People\u2019s Republic of China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yin","family":"Xu","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, People\u2019s Republic of China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8614-458X","authenticated-orcid":true,"given":"Yunkui","family":"Liu","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, People\u2019s Republic of China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,9]]},"reference":[{"key":"2026103005085418700_cit1a","doi-asserted-by":"publisher","first-page":"568","DOI":"10.1016\/j.tetlet.2017.12.076","article-title":"Recent topics of the natural product synthesis by Horner\u2013Wadsworth\u2013Emmons reaction","volume":"59","author":"Kobayashi","year":"2018","journal-title":"Tetrahedron Lett."},{"key":"2026103005085418700_cit1b","doi-asserted-by":"publisher","first-page":"1095","DOI":"10.1039\/D2OB01969H","article-title":"Horner\u2013Wadsworth\u2013Emmons reaction as an excellent tool in the synthesis of fluoro-containing biologically important compounds","volume":"21","author":"Bilska-Markowska","year":"2023","journal-title":"Org. 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