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Thianthrenium salts serve as general precursors of alkyl and aryl radicals, enabling the efficient and diverse generation of alkyl or aryl sulfonyl radicals via in situ capture of sulfur dioxide while avoiding the use of highly toxic sulfonyl chlorides or sulfonyl hydrazines as sulfonyl sources. Meanwhile, a gram-scale experiment afforded the sulfonylated indole-fused 1,4-diazepinone in good yield and recovered thianthrene in high yield, demonstrating high atom and step economy via the formation of multiple C\u2013S and C\u2013C bonds in a single orchestrated operation.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01927","type":"journal-article","created":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T06:01:22Z","timestamp":1791266482000},"page":"14502-14515","source":"Crossref","is-referenced-by-count":0,"title":["Photoinduced Multicomponent Synthesis of Sulfonylated Indole-Fused 1,4-Diazepinones Using Thianthrenium Salts"],"prefix":"10.1021","volume":"91","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4682-1157","authenticated-orcid":true,"given":"Long-Jin","family":"Zhong","sequence":"first","affiliation":[{"name":"Hunan Institute of Science and Technology , , ,","place":["Yueyang, China, 414006"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mei-Jin","family":"Gao","sequence":"additional","affiliation":[{"name":"Hunan Institute of Science and Technology , , ,","place":["Yueyang, China, 414006"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5864-7841","authenticated-orcid":true,"given":"Quan","family":"Zhou","sequence":"additional","affiliation":[{"name":"Hunan Institute of Science and Technology , , ,","place":["Yueyang, China, 414006"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4555-8238","authenticated-orcid":true,"given":"Yu","family":"Liu","sequence":"additional","affiliation":[{"name":"Hunan Institute of Science and Technology , , ,","place":["Yueyang, China, 414006"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,6]]},"reference":[{"key":"2026103005083736000_cit1a","doi-asserted-by":"publisher","first-page":"5793","DOI":"10.1021\/jacs.6b02678","article-title":"Enantioselective Synthesis of Indole-Annulated Medium-Sized Rings","volume":"138","author":"Huang","year":"2016","journal-title":"J. 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