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Despite their significance, the synthesis of germanium-substituted quinolines through germyl radical cyclization has remained unexplored to date. Herein, we report a dilauroyl peroxide (LPO)-mediated cascade protocol involving germylation, cyclization, and aromatization of N-propargyl aromatic amines with germanes, enabling efficient construction of 3-germanium-substituted quinolines. This transformation proceeds via a radical pathway and features high regioselectivity, broad substrate scope, and good functional group compatibility. Mechanistic investigations indicate that cleavage of the Ge\u2013H bond serves as the rate-determining step.<\/jats:p>","DOI":"10.1021\/acs.joc.6c01998","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T22:01:56Z","timestamp":1790719316000},"page":"13764-13770","source":"Crossref","is-referenced-by-count":0,"title":["Germyl Radical Cyclization\nof\n                    <i>N<\/i>\n                    -Propargyl\nAromatic Amines with Germanes: A Concise Route to Germanium-Containing\nQuinolines"],"prefix":"10.1021","volume":"91","author":[{"given":"Yue","family":"Zhang","sequence":"first","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanjun","family":"Wu","sequence":"additional","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haibin","family":"Xiao","sequence":"additional","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junhao","family":"Chen","sequence":"additional","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zihan","family":"Wu","sequence":"additional","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7929-1987","authenticated-orcid":true,"given":"Xiaolei","family":"Huang","sequence":"additional","affiliation":[{"name":"Zhejiang Normal University , , , ,","place":["Jinhua, Zhejiang, China, 321004"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,29]]},"reference":[{"key":"2026101608083752800_cit1","first-page":"1","article-title":"The Chemistry\nof the Cinchona Alkaloids","volume-title":"The Alkaloids.\nChemistry and Physiology","author":"Turner","year":"1953"},{"key":"2026101608083752800_cit2a","doi-asserted-by":"publisher","first-page":"155","DOI":"10.1038\/s41584-020-0372-x","article-title":"Mechanisms\nof action of hydroxychloroquine and chloroquine: implications for\nrheumatology","volume":"16","author":"Schrezenmeier","year":"2020","journal-title":"Nat. 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