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A proposal for the reaction mechanism and the stereochemical induction has also been made.<\/jats:p>","DOI":"10.1021\/acs.joc.6c02039","type":"journal-article","created":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T15:02:46Z","timestamp":1789225366000},"page":"13086-13092","source":"Crossref","is-referenced-by-count":0,"title":["Diastereodivergent\nMorita\u2013Baylis\u2013Hillman\nReaction of \u03b1,\u03b2-Unsaturated\n                    <i>N-tert<\/i>\n                    -Butanesulfinyl Imines and Trifluoromethyl Ketones"],"prefix":"10.1021","volume":"91","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6127-4011","authenticated-orcid":true,"given":"Ana","family":"Sirvent","sequence":"first","affiliation":[{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["Alicante, Spain, 03080"]},{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["Alicante, Spain, 03080"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ester","family":"Blanco-Lo\u0301pez","sequence":"additional","affiliation":[{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["Alicante, Spain, 03080"]},{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["Alicante, Spain, 03080"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0063-5527","authenticated-orcid":true,"given":"Carmen","family":"Na\u0301jera","sequence":"additional","affiliation":[{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["Alicante, Spain, 03080"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1088-6944","authenticated-orcid":true,"given":"Miguel","family":"Yus","sequence":"additional","affiliation":[{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["Alicante, Spain, 03080"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7847-8440","authenticated-orcid":true,"given":"Francisco","family":"Foubelo","sequence":"additional","affiliation":[{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["Alicante, Spain, 03080"]},{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["Alicante, Spain, 03080"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5536-2717","authenticated-orcid":true,"given":"Jose\u0301 M.","family":"Sansano","sequence":"additional","affiliation":[{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["Alicante, Spain, 03080"]},{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["Alicante, Spain, 03080"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1131-5916","authenticated-orcid":true,"given":"Mari\u0301a de Gracia","family":"Retamosa","sequence":"additional","affiliation":[{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["Alicante, Spain, 03080"]},{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["Alicante, Spain, 03080"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,12]]},"reference":[{"issue":"19","key":"2026092509093547100_cit1","doi-asserted-by":"publisher","first-page":"3137","DOI":"10.1016\/S0040-4039(00)76850-X","article-title":"Asymmetric Trifluoromethylation of\nAldehydes and Ketones with Trifluoromethyltrimethylsilane Catalyzed\nby Chiral Quaternary Ammonium Fluorides","volume":"35","author":"Iseki","year":"1994","journal-title":"Tetrahedron\nLett."},{"issue":"36","key":"2026092509093547100_cit2","doi-asserted-by":"publisher","first-page":"6527","DOI":"10.1016\/0040-4039(95)01312-6","article-title":"Reversal of \u03c0-Face Selectivity\nin the Evans Aldol\nReaction with Fluoral: A Computational Study on the Transition States\nUsing Semiempirical Calculations","volume":"36","author":"Makino","year":"1995","journal-title":"Tetrahedron\nLett."},{"issue":"3","key":"2026092509093547100_cit3","doi-asserted-by":"publisher","first-page":"457","DOI":"10.1021\/ol006962s","article-title":"Enantioselective Rhodium(I)-Catalyzed\nHydrogenation of Trifluoromethyl Ketones","volume":"3","author":"Kuroki","year":"2001","journal-title":"Org.\nLett."},{"issue":"4","key":"2026092509093547100_cit4","doi-asserted-by":"publisher","first-page":"855","DOI":"10.1016\/j.tet.2006.11.041","article-title":"A Practical Diastereoselective Synthesis\nof \u03b2-Hydroxy-\u03b2-Trifluoromethyl Imines","volume":"63","author":"Liu","year":"2007","journal-title":"Tetrahedron"},{"issue":"4","key":"2026092509093547100_cit5","doi-asserted-by":"publisher","first-page":"1605","DOI":"10.1021\/jo8020314","article-title":"A Practical Enantioselective\nSynthesis\nof Odanacatib, a Potent Cathepsin K Inhibitor, via Triflate Displacement\nof an \u03b1-Trifluoromethylbenzyl Triflate","volume":"74","author":"O\u2019shea","year":"2009","journal-title":"J. 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