{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T15:31:58Z","timestamp":1786116718597,"version":"build-2736575974"},"reference-count":63,"publisher":"American Chemical Society (ACS)","issue":"31","license":[{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100007185","name":"Total","doi-asserted-by":"publisher","award":["AW1010136"],"award-info":[{"award-number":["AW1010136"]}],"id":[{"id":"10.13039\/501100007185","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","award":["567589"],"award-info":[{"award-number":["567589"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>During the oxidation of ammonia (NH3), pyrolysis reactions strongly influence ignition delay times, intermediate radical populations, and production of nitrogen oxides (NOx), none of which are adequately predicted by NH3-containing chemical kinetic models. Moreover, simultaneous, multispecies data sets relevant to NH3 pyrolysis, useful for elucidating areas for model refinement, are generally lacking. Thus, the pyrolysis of 0.1\u20131.0% NH3 dilute in argon was studied behind reflected shock waves (2100\u20133500 K, pressures near 1 atm) using a combination of laser absorption diagnostics to measure postshock imidogen radical (NH, 336.1 nm), amino radical (NH2, 597.4 nm), and NH3 (225.3 nm) concentrations, as well as preshock NH3 concentrations (10.4 \u03bcm). In this way, the first simultaneous measurements of NH, NH2, and NH3 during NH3 pyrolysis were obtained, and refined measurements of the oscillator strength of the targeted NH2 absorption feature were enabled. Key discrepancies between these multispecies data and existing model predictions motivated the development of a refined NH3 pyrolysis model, resulting in improved predictions of measured time-histories. Predictions of late-time NH2 consumption and early-time NH formation were significantly improved. Remaining model discrepancies motivate the generation of similar multispecies data sets using hydrazines and hydrazoic acid as precursors for important NH3-relevant species.<\/jats:p>","DOI":"10.1021\/acs.jpca.6c01857","type":"journal-article","created":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T15:09:42Z","timestamp":1784819382000},"page":"6246-6259","source":"Crossref","is-referenced-by-count":0,"title":["Ammonia Pyrolysis\nbehind Reflected Shock Waves: Multispecies\nMeasurements and Modeling"],"prefix":"10.1021","volume":"130","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5737-2460","authenticated-orcid":true,"given":"Taylor M.","family":"Rault","sequence":"first","affiliation":[{"name":"Stanford University , , , ,","place":["Stanford, California, United States, 94305"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Padmanabha","family":"Prasanna Simha","sequence":"additional","affiliation":[{"name":"Stanford University , , , ,","place":["Stanford, California, United States, 94305"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Owen R.","family":"Trimble","sequence":"additional","affiliation":[{"name":"Stanford University , , , ,","place":["Stanford, California, United States, 94305"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sean","family":"Clees","sequence":"additional","affiliation":[{"name":"Stanford University , , , ,","place":["Stanford, California, United States, 94305"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ronald K.","family":"Hanson","sequence":"additional","affiliation":[{"name":"Stanford University , , , ,","place":["Stanford, California, United States, 94305"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,23]]},"reference":[{"key":"2026080608134932800_cit1","doi-asserted-by":"publisher","first-page":"31","DOI":"10.1016\/j.pecs.2018.01.002","article-title":"Modeling\nnitrogen chemistry in combustion","volume":"67","author":"Glarborg","year":"2018","journal-title":"Prog. Energy\nCombust. Sci."},{"key":"2026080608134932800_cit2","doi-asserted-by":"publisher","first-page":"109","DOI":"10.1016\/j.proci.2018.09.029","article-title":"Science and technology\nof ammonia combustion","volume":"37","author":"Kobayashi","year":"2019","journal-title":"Proc. Combust. Inst."},{"key":"2026080608134932800_cit3","doi-asserted-by":"publisher","first-page":"6964","DOI":"10.1021\/acs.energyfuels.0c03685","article-title":"Review\non ammonia as a potential fuel: from synthesis to economics","volume":"35","author":"Valera-Medina","year":"2021","journal-title":"Energy Fuels"},{"key":"2026080608134932800_cit4","doi-asserted-by":"publisher","first-page":"513","DOI":"10.1002\/kin.550220508","article-title":"A pyrolysis\nmechanism for ammonia","volume":"22","author":"Davidson","year":"1990","journal-title":"Int. J. Chem. Kinet."},{"key":"2026080608134932800_cit5","unstructured":"Naumann, C.; Braun-Unkhoff, M.; Frank, P.\n          A shock tube study on ammonia\ndecomposition and its reaction products\n          21st\nInt. Symp. Shock Waves\n          1997; Vol. 21."},{"key":"2026080608134932800_cit6","doi-asserted-by":"publisher","DOI":"10.1016\/j.combustflame.2021.111694","article-title":"An experimental\nand modeling study\nof ammonia pyrolysis","volume":"235","author":"Alturaifi","year":"2022","journal-title":"Combust. Flame"},{"key":"2026080608134932800_cit7","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfueco.2022.100050","article-title":"Shock-tube\nlaser absorption measurements\nof N2O time histories during ammonia oxidation","volume":"10","author":"Alturaifi","year":"2022","journal-title":"Fuel Commun."},{"key":"2026080608134932800_cit8","doi-asserted-by":"publisher","first-page":"233","DOI":"10.1016\/j.proci.2022.08.016","article-title":"A shock-tube study\nof NH3 and NH3\/H2 oxidation using\nlaser absorption\nof NH3 and H2O","volume":"39","author":"Alturaifi","year":"2023","journal-title":"Proc.\nCombust. Inst."},{"key":"2026080608134932800_cit9","doi-asserted-by":"publisher","DOI":"10.1016\/j.combustflame.2022.112389","article-title":"Investigation on the NO formation of ammonia oxidation in a shock\ntube applying tunable diode laser absorption spectroscopy","volume":"246","author":"Zhu","year":"2022","journal-title":"Combust. Flame"},{"key":"2026080608134932800_cit10","doi-asserted-by":"publisher","DOI":"10.1016\/j.combustflame.2023.112830","article-title":"Experimental study\nof the methane\/hydrogen\/ammonia and ethylene\/ammonia\noxidation: Multi-parameter measurements using a shock tube combined\nwith laser absorption spectroscopy","volume":"254","author":"Zheng","year":"2023","journal-title":"Combust.\nFlame"},{"key":"2026080608134932800_cit11","doi-asserted-by":"publisher","first-page":"4365","DOI":"10.1016\/j.proci.2022.07.259","article-title":"Shock tube study of\nthe interaction between ammonia and nitric oxide at high temperatures\nusing laser absorption spectroscopy","volume":"39","author":"Zheng","year":"2023","journal-title":"Proc. Combust.\nInst."},{"key":"2026080608134932800_cit12","doi-asserted-by":"publisher","DOI":"10.1016\/j.combustflame.2023.113260","article-title":"Multi-speciation\nand ignition delay time measurements of ammonia oxidation behind reflected\nshock waves","volume":"260","author":"Rault","year":"2024","journal-title":"Combust. Flame"},{"key":"2026080608134932800_cit13","doi-asserted-by":"publisher","DOI":"10.1016\/j.proci.2024.105286","article-title":"Simultaneous OH\nand OH* measurements during NH3 oxidation in a shock tube","volume":"40","author":"Clees","year":"2024","journal-title":"Proc. Combust. Inst."},{"key":"2026080608134932800_cit14","doi-asserted-by":"publisher","DOI":"10.1016\/j.proci.2024.105250","article-title":"Shock-tube study\nof the oxidation\nof ammonia by N2O","volume":"40","author":"Mathieu","year":"2024","journal-title":"Proc. Combust.\nInst."},{"key":"2026080608134932800_cit15","doi-asserted-by":"publisher","DOI":"10.1016\/j.combustflame.2025.114135","article-title":"Interaction of ammonia\nwith nitric oxide and nitrous oxide: Multi-species time-history measurements\nand comprehensive kinetic modeling","volume":"276","author":"Zou","year":"2025","journal-title":"Combust.\nFlame"},{"key":"2026080608134932800_cit16","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfueco.2022.100049","article-title":"Challenges\nin kinetic modeling of\nammonia pyrolysis","volume":"10","author":"Glarborg","year":"2022","journal-title":"Fuel Commun."},{"key":"2026080608134932800_cit17","doi-asserted-by":"publisher","DOI":"10.1016\/j.combustflame.2026.114968","article-title":"Applications\nof hydrazine for the study of NH2 kinetics-I: N2H4 Pyrolysis Reactions","volume":"288","author":"Rault","year":"2026","journal-title":"Combust.\nFlame"},{"key":"2026080608134932800_cit18","doi-asserted-by":"publisher","DOI":"10.1016\/j.combustflame.2026.114969","article-title":"Applications\nof hydrazine for the study of NH2 kinetics-II: Self-reaction\nof NH2 radicals","volume":"288","author":"Rault","year":"2026","journal-title":"Combust. Flame"},{"key":"2026080608134932800_cit19","doi-asserted-by":"publisher","first-page":"169","DOI":"10.1021\/cr60051a002","article-title":"Hydrazoic\nAcid and Its Inorganic Derivatives","volume":"15","author":"Audrieth","year":"1934","journal-title":"Chem. Rev."},{"key":"2026080608134932800_cit20","doi-asserted-by":"publisher","first-page":"1332","DOI":"10.1002\/bbpc.19940981020","article-title":"A direct measurement of the reaction\nNH3 + NH \u2192 2NH2","volume":"98","author":"Ro\u0308hrig","year":"1994","journal-title":"Ber. Bunsengesellschaft Phys. Chem."},{"key":"2026080608134932800_cit21","doi-asserted-by":"publisher","first-page":"90","DOI":"10.1016\/j.jqsrt.2016.02.002","article-title":"Line intensities\nand temperature-dependent\nline broadening coefficients of Q-branch transitions in the \u03bd2 band of ammonia near 10.4 \u03bcm","volume":"175","author":"Sur","year":"2016","journal-title":"J. Quant. Spectrosc. Radiat. Transfer"},{"key":"2026080608134932800_cit22","doi-asserted-by":"publisher","first-page":"241","DOI":"10.1006\/jmsp.2001.8473","article-title":"Infrared line strengths and pressure\nbroadening coefficients in the \u03bd12 vibrational band of hydrazine measured by infrared tunable diode\nlaser spectroscopy","volume":"211","author":"Plunkett","year":"2002","journal-title":"J. Mol. Spectrosc."},{"key":"2026080608134932800_cit23","doi-asserted-by":"publisher","first-page":"207","DOI":"10.1016\/0022-4073(89)90084-8","article-title":"Measurements of\nabsorption lineshapes in the A3\u03a0i \u2190\nX3\u03a3\u2013(0, 0) band\nof NH in the presence of Ar broadening","volume":"42","author":"Chang","year":"1989","journal-title":"J. Quant.\nSpectrosc. Radiat. Transfer"},{"key":"2026080608134932800_cit24","doi-asserted-by":"publisher","first-page":"553","DOI":"10.1098\/rsta.1959.0011","article-title":"The electronic absorption spectra\nof NH2 and ND2","volume":"251","author":"Dressler","year":"1959","journal-title":"Philos.\nTrans. A Math.\nPhys. Eng. Sci."},{"key":"2026080608134932800_cit25","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/0022-4073(89)90103-9","article-title":"Quantitative NH2 concentration determination in shock tube laser-absorption\nexperiments","volume":"42","author":"Kohse-Ho\u0308inghaus","year":"1989","journal-title":"J. Quant. Spectrosc. Radiat. Transfer"},{"key":"2026080608134932800_cit26","doi-asserted-by":"publisher","first-page":"655","DOI":"10.1002\/kin.550230802","article-title":"A shock\ntube study of H + HNCO \u2192 NH2 + CO","volume":"23","author":"Mertens","year":"1991","journal-title":"Int. J. Chem. Kinet."},{"key":"2026080608134932800_cit27","doi-asserted-by":"publisher","first-page":"323","DOI":"10.1002\/(SICI)1097-4601(1999)31:5&lt;323::AID-KIN1&gt;3.0.CO;2-X","article-title":"Shock tube study of\nmonomethylamine thermal decomposition and NH2 high temperature\nabsorption coefficient","volume":"31","author":"Votsmeier","year":"1999","journal-title":"Int. J. Chem. Kinet."},{"key":"2026080608134932800_cit28","doi-asserted-by":"crossref","unstructured":"Abulail, M.; Gre\u0301goire, C. M.; Mathieu, O.; Petersen, E. L. In  High-Temperature\nMeasurements of NH2 and NH3 for Resolving Ammonia\nKinetics; Turbo Expo ASME, 88797, V03BT04A002. 2025.","DOI":"10.1115\/GT2025-152983"},{"key":"2026080608134932800_cit29","doi-asserted-by":"publisher","DOI":"10.3390\/s24247920","article-title":"A rapidly\ntunable laser system for measurements of NH2 at 597 nm\nbehind reflected shock waves","volume":"24","author":"Clees","year":"2024","journal-title":"Sensors"},{"key":"2026080608134932800_cit30","doi-asserted-by":"publisher","first-page":"571","DOI":"10.1016\/j.proci.2022.07.045","article-title":"Reactions\nof hydrazine with the amidogen radical and atomic hydrogen","volume":"39","author":"Gao","year":"2023","journal-title":"Proc. Combust. Inst."},{"key":"2026080608134932800_cit31","doi-asserted-by":"publisher","DOI":"10.1016\/j.combustflame.2022.112374","article-title":"Re-evaluation\nof rate\nconstants for the reaction N2H4 (+ M) \u21ccNH2 + NH2 (+ M)","volume":"257","author":"Cobos","year":"2023","journal-title":"Combust. Flame"},{"key":"2026080608134932800_cit32","doi-asserted-by":"publisher","DOI":"10.1016\/j.proci.2025.105797","article-title":"A shock tube study\nof chaperon efficiencies\nfor the NH3 + M \u2192 NH2 + H + M reaction\nduring ammonia pyrolysis","volume":"41","author":"Simha","year":"2025","journal-title":"Proc. Combust. Inst."},{"key":"2026080608134932800_cit33","doi-asserted-by":"publisher","first-page":"1700","DOI":"10.1021\/acs.jpca.5c08194","article-title":"Direct laser absorption\nmeasurements of NH3-relevant pyrolysis reactions","volume":"130","author":"Rault","year":"2026","journal-title":"J. Phys. Chem. A"},{"key":"2026080608134932800_cit34","doi-asserted-by":"publisher","first-page":"586","DOI":"10.2514\/1.T4952","article-title":"Dependence of calculated\npostshock thermodynamic variables on vibrational equilibrium and input\nuncertainty","volume":"31","author":"Campbell","year":"2017","journal-title":"J. Thermophys. Heat Transfer"},{"key":"2026080608134932800_cit35","doi-asserted-by":"publisher","first-page":"554","DOI":"10.1016\/j.combustflame.2014.08.022","article-title":"Experimental and modeling\nstudy on the high-temperature\noxidation of Ammonia and related NOx chemistry","volume":"162","author":"Mathieu","year":"2015","journal-title":"Combust. Flame"},{"key":"2026080608134932800_cit36","doi-asserted-by":"publisher","first-page":"42653","DOI":"10.1364\/OE.571994","article-title":"Ring-amplified shock tube for variable-gain,\nmulti-wavelength\nabsorption spectroscopy","volume":"33","author":"Strand","year":"2025","journal-title":"Opt. Express"},{"key":"2026080608134932800_cit37","doi-asserted-by":"crossref","DOI":"10.1007\/978-3-319-23252-2","volume-title":"Spectroscopy and Optical\nDiagnostics for Gases","author":"Hanson","year":"2016"},{"key":"2026080608134932800_cit38","doi-asserted-by":"publisher","first-page":"1474","DOI":"10.1002\/bbpc.199800016","article-title":"The thermal decomposition of NH2 and NH\nradicals","volume":"102","author":"Deppe","year":"1998","journal-title":"Ber. Bunsengesellschaft Phys. Chem."},{"key":"2026080608134932800_cit39","doi-asserted-by":"publisher","first-page":"2121","DOI":"10.1063\/1.1701411","article-title":"Mass spectral\nstudies of kinetics behind shock waves. II. Thermal decomposition\nof hydrazine","volume":"39","author":"Diesen","year":"1963","journal-title":"J. Chem. Phys."},{"key":"2026080608134932800_cit40","doi-asserted-by":"publisher","first-page":"353","DOI":"10.1016\/S0082-0784(65)80182-5","article-title":"The pyrolysis and\noxidation of hydrazine behind shock\nwaves","volume":"10","author":"Michel","year":"1965","journal-title":"Symp. (Int.) Combust."},{"key":"2026080608134932800_cit41","doi-asserted-by":"publisher","first-page":"790","DOI":"10.1016\/j.combustflame.2011.01.001","article-title":"Shock tube\nmeasurements of species time-histories in monomethyl hydrazine pyrolysis","volume":"158","author":"Cook","year":"2011","journal-title":"Combust. Flame"},{"key":"2026080608134932800_cit42","doi-asserted-by":"publisher","first-page":"16","DOI":"10.1016\/j.combustflame.2013.07.023","article-title":"Shock tube\nstudy of the pressure\ndependence of monomethylhydrazine pyrolysis","volume":"161","author":"Li","year":"2014","journal-title":"Combust. Flame"},{"key":"2026080608134932800_cit43","doi-asserted-by":"publisher","first-page":"6214","DOI":"10.1021\/acs.jpca.0c03144","article-title":"Contributions of experimental\ndata obtained in concentrated\nmixtures to kinetic studies: application to monomethylhydrazine pyrolysis","volume":"124","author":"Die\u0301vart","year":"2020","journal-title":"J. Phys. Chem. A"},{"key":"2026080608134932800_cit44","doi-asserted-by":"publisher","DOI":"10.1080\/00268976.2021.1979674","article-title":"New reactions of diazene\nand related\nspecies for modelling combustion of amine fuels","volume":"119","author":"Marshall","year":"2021","journal-title":"Mol. Phys."},{"key":"2026080608134932800_cit45","doi-asserted-by":"publisher","first-page":"7192","DOI":"10.1021\/acs.jpca.6b05723","article-title":"Modeling\nnitrogen species as pollutants: thermochemical influences","volume":"120","author":"Bugler","year":"2016","journal-title":"J. Phys. Chem. A"},{"key":"2026080608134932800_cit46","doi-asserted-by":"publisher","first-page":"22482","DOI":"10.1021\/acs.energyfuels.4c03352","article-title":"Thermodynamic\nand Chemical Kinetic Parameters in Ammonia Oxidation: A Comparison\nof Recent Studies and Parameter Recommendations","volume":"38","author":"Grinberg Dana","year":"2024","journal-title":"Energy Fuels"},{"key":"2026080608134932800_cit47","unstructured":"Goos, E.; Burcat, A.; Ruscic, B.\n          Extended Third\nMillenium Ideal Gas Thermochemical Database with updates from Active\nThermochemical Tables. 2021."},{"key":"2026080608134932800_cit48","doi-asserted-by":"publisher","first-page":"6187","DOI":"10.1021\/acs.jpca.7b06017","article-title":"Enthalpy of formation\nof N2H4 (hydrazine) revisited","volume":"121","author":"Feller","year":"2017","journal-title":"J. Phys.\nChem. A"},{"key":"2026080608134932800_cit49","unstructured":"Ruscic, B.; Bross, D.\n          Active Thermochemical\nTables (ATcT), version 1.122p (available at ATcT.anl.gov)\naccessed April 2021."},{"key":"2026080608134932800_cit50","doi-asserted-by":"publisher","first-page":"106","DOI":"10.1016\/S0010-2180(00)00187-5","article-title":"Kinetic modeling of the decomposition and flames of\nhydrazine","volume":"124","author":"Konnov","year":"2001","journal-title":"Combust. Flame"},{"key":"2026080608134932800_cit51","doi-asserted-by":"publisher","first-page":"329","DOI":"10.1080\/00102209808952093","article-title":"Experimental\nand detailed kinetic modeling of nitric oxide reduction by a natural\ngas blend in simulated reburning conditions","volume":"139","author":"Dagaut","year":"1998","journal-title":"Combust. Sci. Technol."},{"key":"2026080608134932800_cit52","doi-asserted-by":"publisher","first-page":"125","DOI":"10.1007\/978-1-4612-1310-9_2","article-title":"Combustion chemistry\nof nitrogen","volume-title":"Gas-Phase Combustion Chemistry","author":"Dean","year":"2000"},{"key":"2026080608134932800_cit53","doi-asserted-by":"publisher","first-page":"287","DOI":"10.1016\/0360-1285(89)90017-8","article-title":"Mechanism and modeling\nof nitrogen chemistry in combustion","volume":"15","author":"Miller","year":"1989","journal-title":"Prog. Energy\nCombust. Sci."},{"key":"2026080608134932800_cit54","first-page":"476","article-title":"Thermal decomposition of NH3 in shock waves","author":"Roose","year":"1980","journal-title":"Shock Tubes and Waves"},{"key":"2026080608134932800_cit55","doi-asserted-by":"publisher","first-page":"863","DOI":"10.1016\/S0082-0784(81)80090-2","article-title":"Rate constants of chemical reactions in the high temperature pyrolysis\nof ammonia","volume":"18","author":"Yumura","year":"1981","journal-title":"Symp. (Int.) Combust."},{"key":"2026080608134932800_cit56","doi-asserted-by":"publisher","first-page":"689","DOI":"10.1139\/v79-112","article-title":"A shock-tube study\nof ammonia pyrolysis","volume":"57","author":"Dove","year":"1979","journal-title":"Can. J. Chem."},{"key":"2026080608134932800_cit57","doi-asserted-by":"publisher","first-page":"665","DOI":"10.1021\/j100797a030","article-title":"Further\nshock-tube studies by infrared emission of the decomposition of ammonia","volume":"67","author":"Jacobs","year":"1963","journal-title":"J. Phys. Chem. A"},{"key":"2026080608134932800_cit58","doi-asserted-by":"publisher","first-page":"2962","DOI":"10.1039\/TF9676302962","article-title":"Shock wave studies in nitrogen +\nhydrogen systems. Part 4.\u2013Thermal decomposition of ammonia","volume":"63","author":"Bradley","year":"1967","journal-title":"Trans. Faraday Soc."},{"key":"2026080608134932800_cit59","doi-asserted-by":"publisher","first-page":"769","DOI":"10.1016\/S0082-0784(81)80080-X","article-title":"On the thermal decomposition of ammonia behind shock\nwaves","volume":"18","author":"Holzrichter","year":"1981","journal-title":"Symp. (Int.) Combust."},{"key":"2026080608134932800_cit60","volume-title":"Aufbau und Charakterisierung\neiner Sto\u00dfwellenapparatur zur Untersuchung von Hochtemperaturreaktionen\ndes Formylradikals","author":"Colberg","year":"2006"},{"key":"2026080608134932800_cit61","doi-asserted-by":"publisher","first-page":"7193","DOI":"10.1021\/acs.energyfuels.0c03387","article-title":"Experimental study of the pyrolysis of NH3 under flow reactor conditions","volume":"35","author":"Bene\u0301s","year":"2021","journal-title":"Energy Fuels"},{"key":"2026080608134932800_cit62","doi-asserted-by":"publisher","first-page":"156","DOI":"10.1002\/bbpc.19940980204","article-title":"Elementary\nreactions of NH (a1\u0394) and NH (X3\u03a3) with\nN, O and NO","volume":"98","author":"Hack","year":"1994","journal-title":"Ber. Bunsengesellschaft Phys. Chem."},{"key":"2026080608134932800_cit63","doi-asserted-by":"publisher","first-page":"1096","DOI":"10.1021\/op7000645","article-title":"Explosion\nand decomposition characteristics of hydrazoic acid in the gas phase","volume":"11","author":"Wiss","year":"2007","journal-title":"Org. Process Res. Dev."}],"container-title":["The Journal of Physical\nChemistry A"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpca.6c01857","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jpcafh\/article-pdf\/130\/31\/6246\/66237215\/acs.jpca.6c01857.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jpcafh\/article-pdf\/130\/31\/6246\/66237215\/acs.jpca.6c01857.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,6]],"date-time":"2026-08-06T12:19:43Z","timestamp":1786018783000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jpcafh\/article\/130\/31\/6246\/5231224\/Ammonia-Pyrolysis-behind-Reflected-Shock-Waves"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,23]]},"references-count":63,"journal-issue":{"issue":"31","published-online":{"date-parts":[[2026,7,23]]},"published-print":{"date-parts":[[2026,8,6]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.jpca.6c01857","relation":{},"ISSN":["1089-5639","1520-5215"],"issn-type":[{"value":"1089-5639","type":"print"},{"value":"1520-5215","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,23]]}}}