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A compact theoretical expression is provided, along with an experimental protocol, based on INEPT (insensitive nuclei enhanced by polarization)-enhanced double-quantum-filtered inversion recovery measurements. The analysis of the build-up curves results in a set of cross-correlated relaxation rates for both the 13C and 1H spins at the two sites. It is demonstrated that the results can be given a consistent interpretation in terms of molecular-level properties, such as rotational correlation times, the Lipari\u2013Szabo order parameter, and interaction strength constants. The analysis yields the bound-site carbon-13 chemical shielding anisotropy, \u0394\u03c3C = \u221258 \u00b1 8 ppm, in good agreement with most recent liquid-crystal measurements and the corresponding proton shielding anisotropy, \u0394\u03c3H = 14 \u00b1 2 ppm.<\/jats:p>","DOI":"10.1021\/acs.jpcb.5b05218","type":"journal-article","created":{"date-parts":[[2015,8,12]],"date-time":"2015-08-12T16:51:57Z","timestamp":1439398317000},"page":"11760-11767","source":"Crossref","is-referenced-by-count":3,"title":["Chemical Shielding Anisotropies for Chloroform Exchanging\nbetween a Free Site and a Complex with Cryptophane-D: A Cross-Correlated\nNMR Relaxation Study"],"prefix":"10.1021","volume":"119","author":[{"given":"Emilie","family":"Steiner","sequence":"first","affiliation":[{"name":"Stockholm University , , ,","place":["Stockholm, Sweden, SE-106 91"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thierry","family":"Brotin","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie, (CNRS-UMR 5182) Ecole Normale Supe\u0301rieure de Lyon , 46 Alle\u0301e d\u2019Italie , cedex 07,","place":["Lyon, France, F-69364"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zoltan","family":"Takacs","sequence":"additional","affiliation":[{"name":"Stockholm University , , ,","place":["Stockholm, Sweden, SE-106 91"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jozef","family":"Kowalewski","sequence":"additional","affiliation":[{"name":"Stockholm University , , ,","place":["Stockholm, Sweden, SE-106 91"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2015,8,12]]},"reference":[{"key":"2026090219030506100_cit1","doi-asserted-by":"publisher","first-page":"204","DOI":"10.1021\/ja00391a045","article-title":"Circular-Dichroism\nand Absolute-Configuration of C3-Chiral\nDerivatives of Cyclotriveratrylene","volume":"103","author":"Collet","year":"1981","journal-title":"J. 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