{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T15:32:44Z","timestamp":1786116764110,"version":"build-2736575974"},"reference-count":57,"publisher":"American Chemical Society (ACS)","issue":"31","license":[{"start":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T00:00:00Z","timestamp":1785110400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T00:00:00Z","timestamp":1785110400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T00:00:00Z","timestamp":1785110400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/na","name":"National Science Foundation","doi-asserted-by":"publisher","award":["2029387"],"award-info":[{"award-number":["2029387"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"Department of Science and Technology","doi-asserted-by":"publisher","award":["WISE-PDF\/CS-89\/2023"],"award-info":[{"award-number":["WISE-PDF\/CS-89\/2023"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The unique properties, renewability, and market availability of glycerol (and related molecules) make it an attractive candidate for transformation in numerous applications. The present work utilizes molecules containing glycerol skeletons for the preparation of deep eutectic solvents (DESs). The field of chemical sciences is rapidly adopting DESs as an alternative medium. Not only are the components of DESs inexpensive and often greener than conventional alternatives, but there is a large variety of identified components that can be combined to form DESs with different physicochemical properties. This study examines a class of ternary DESs that are derived from H-bond donors (HBDs) based on a symmetric 1,3-diether-2-propanol motif obtained from the reaction of epichlorohydrin with small alcohols, with choline chloride (CC) acting as the H-bond acceptor. Here we study the density, dynamic viscosity, and refractive index (RI) of these ternary DESs within the temperature range 293.15\u2013353.15 K. Featuring DTEP as an HBD2 component in DES- DTEP:CC:DFE exhibits a higher density compared to other DESs that have been prepared, which can be explained by the higher concentration of F atoms in its structural framework.<\/jats:p>","DOI":"10.1021\/acs.jpcb.6c00159","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:11:41Z","timestamp":1785849101000},"page":"7945-7954","source":"Crossref","is-referenced-by-count":0,"title":["Deep Eutectic Solvents Containing Symmetric 1,3-Diether-2-propanol\nHydrogen Bond Donors Based on Glycerol Skeletons"],"prefix":"10.1021","volume":"130","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8549-2830","authenticated-orcid":true,"family":"Bhawna","sequence":"first","affiliation":[{"name":"Indian Institute of Technology Delhi , , , ,","place":["Hauz Khas, New Delhi, India, 110016"]},{"name":"The University of Alabama , , , ,","place":["Tuscaloosa, Alabama, United States, 35487-0203"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3175-5353","authenticated-orcid":true,"given":"Siddharth","family":"Pandey","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Delhi , , , ,","place":["Hauz Khas, New Delhi, India, 110016"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5817-6867","authenticated-orcid":true,"given":"Shuai","family":"Qian","sequence":"additional","affiliation":[{"name":"The University of Alabama , , , ,","place":["Tuscaloosa, Alabama, United States, 35487-0203"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sophia Chioma","family":"Ezendu","sequence":"additional","affiliation":[{"name":"The University of Alabama , , , ,","place":["Tuscaloosa, Alabama, United States, 35487-0203"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4218-1570","authenticated-orcid":true,"given":"Tibor","family":"Szilva\u0301si","sequence":"additional","affiliation":[{"name":"The University of Alabama , , , ,","place":["Tuscaloosa, Alabama, United States, 35487-0203"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8351-2145","authenticated-orcid":true,"given":"Jason E.","family":"Bara","sequence":"additional","affiliation":[{"name":"The University of Alabama , , , ,","place":["Tuscaloosa, Alabama, United States, 35487-0203"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,27]]},"reference":[{"issue":"3","key":"2026080608123856200_cit1","doi-asserted-by":"publisher","first-page":"987","DOI":"10.1016\/j.rser.2009.11.010","article-title":"Recent progress on innovative and\npotential technologies for glycerol transformation into fuel additives:\nA critical review","volume":"14","author":"Rahmat","year":"2010","journal-title":"Renewable and Sustainable\nEnergy Reviews"},{"issue":"22","key":"2026080608123856200_cit2","doi-asserted-by":"publisher","first-page":"6208","DOI":"10.1039\/c1cc10620a","article-title":"Glycerol and\nderived solvents: new sustainable reaction media for organic synthesis","volume":"47","author":"Di\u0301az-A\u0301lvarez","year":"2011","journal-title":"Chem. 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Mol. Liq."},{"issue":"8","key":"2026080608123856200_cit9","doi-asserted-by":"publisher","first-page":"1299","DOI":"10.1007\/BF02542409","article-title":"A convenient\nsynthesis of long-chain 1-O-Alkyl glyceryl ethers","volume":"65","author":"Urata","year":"1988","journal-title":"J Americ Oil Chem Soc"},{"issue":"8","key":"2026080608123856200_cit10","doi-asserted-by":"publisher","first-page":"1905","DOI":"10.1021\/acs.jced.2c00008","article-title":"Properties of Imidazolium\nIonic Liquids with Glycerol-Derived\nFunctional Groups","volume":"67","author":"Qian","year":"2022","journal-title":"Journal of Chemical &\nEngineering Data"},{"key":"2026080608123856200_cit11","doi-asserted-by":"publisher","first-page":"2010","DOI":"10.1039\/b106357j","article-title":"Preparation\nof novel, moisture-stable, Lewis-acidic\nionic liquids containing quaternary ammonium salts with functional\nside chains","volume":"19","author":"Abbott","year":"2001","journal-title":"Chem. 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Purif.\nTechnol."},{"key":"2026080608123856200_cit24","doi-asserted-by":"publisher","first-page":"2405","DOI":"10.3390\/molecules15042405","article-title":"Recent\nApplications of Ionic Liquids in Separation\nTechnology","volume":"15","author":"Han","year":"2010","journal-title":"Molecules"},{"issue":"1","key":"2026080608123856200_cit25","doi-asserted-by":"publisher","first-page":"15","DOI":"10.1016\/j.fluid.2010.02.006","article-title":"Modeling ionic liquids\nand the solubility of gases in them: Recent advances and perspectives","volume":"294","author":"Vega","year":"2010","journal-title":"Fluid Phase Equilib."},{"key":"2026080608123856200_cit26","doi-asserted-by":"publisher","first-page":"788","DOI":"10.1016\/j.jiec.2024.12.005","article-title":"Thermophysical Characterization\nof Sustainable Pathways for Hydrofluorocarbons Separation Utilizing\nDeep Eutectic Solvents","volume":"146","author":"Alencar","year":"2025","journal-title":"Journal of Industrial\nand Engineering Chemistry"},{"issue":"3","key":"2026080608123856200_cit27","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2023.110255","article-title":"Process design for the recovery of\nwaste refrigerants using deep eutectic solvents","volume":"11","author":"Codera","year":"2023","journal-title":"Journal of Environmental Chemical Engineering"},{"issue":"24","key":"2026080608123856200_cit28","doi-asserted-by":"publisher","first-page":"6249","DOI":"10.1021\/acs.jpclett.4c01085","article-title":"Fluoride-Based\nDeep Eutectic Solvents with Amide Dual-Hydrogen-Bond Donors","volume":"15","author":"Yamamoto","year":"2024","journal-title":"J. Phys. Chem. Lett."},{"issue":"29","key":"2026080608123856200_cit29","doi-asserted-by":"publisher","first-page":"13246","DOI":"10.1021\/acs.iecr.0c01893","article-title":"Absorption of Fluorinated\nGreenhouse Gases in Deep Eutectic Solvents","volume":"59","author":"Castro","year":"2020","journal-title":"Ind. Eng. Chem. Res."},{"issue":"22","key":"2026080608123856200_cit30","doi-asserted-by":"publisher","first-page":"4536","DOI":"10.1021\/acs.jpcb.0c01860","article-title":"Deep Eutectic Solvents\nMixed with Fluorinated Refrigerants for Absorption Refrigeration:\nA Molecular Simulation Study","volume":"124","author":"Abedin","year":"2020","journal-title":"J. Phys. 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Cryst."},{"issue":"4","key":"2026080608123856200_cit33","doi-asserted-by":"publisher","first-page":"540","DOI":"10.1080\/02678292.2019.1662116","article-title":"New room\ntemperature\nnematogens by cyano tail termination of alkoxy and alkylcyanobiphenyls\nand their anchoring behavior on metal salt-decorated surface","volume":"47","author":"Wang","year":"2020","journal-title":"Liq. Cryst."},{"issue":"3","key":"2026080608123856200_cit34","doi-asserted-by":"publisher","first-page":"397","DOI":"10.1080\/02678292.2018.1502373","article-title":"Synthesis\nand properties of hydroxy\ntail-terminated cyanobiphenyl liquid crystals","volume":"46","author":"Wang","year":"2019","journal-title":"Liq. 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Theory Comput."},{"issue":"5","key":"2026080608123856200_cit37","doi-asserted-by":"publisher","first-page":"2847","DOI":"10.1021\/acs.jctc.9b00143","article-title":"Exploration\nof Chemical Compound, Conformer, and Reaction Space with Meta-Dynamics\nSimulations Based on Tight-Binding Quantum Chemical Calculations","volume":"15","author":"Grimme","year":"2019","journal-title":"J. Chem. Theory Comput."},{"issue":"12","key":"2026080608123856200_cit38","doi-asserted-by":"publisher","first-page":"15120","DOI":"10.1021\/acsomega.9b02011","article-title":"Calculation of Electron\nIonization Mass Spectra with\nSemiempirical GFNn-xTB Methods","volume":"4","author":"Koopman","year":"2019","journal-title":"ACS Omega"},{"issue":"22","key":"2026080608123856200_cit39","doi-asserted-by":"publisher","DOI":"10.1016\/j.heliyon.2024.e40521","article-title":"Exploring the dynamic world of ternary deep eutectic\nsolvents: Synthesis, characterization, and key properties unveiled","volume":"10","author":"Alotaibi","year":"2024","journal-title":"Heliyon"},{"key":"2026080608123856200_cit40","doi-asserted-by":"publisher","first-page":"84","DOI":"10.3390\/chemengineering9040084","article-title":"Ternary Choline\nChloride-Based Deep Eutectic Solvents: A Review","volume":"9","author":"Ibrahim","year":"2025","journal-title":"ChemEngineering"},{"key":"2026080608123856200_cit41","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2023.123777","article-title":"Physico-chemical\ncharacterisation of glycerol- and ethylene glycol-based deep eutectic\nsolvents","volume":"394","author":"Meredith","year":"2024","journal-title":"J. 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Acta"},{"issue":"48","key":"2026080608123856200_cit46","doi-asserted-by":"publisher","first-page":"21383","DOI":"10.1039\/c1cp22554e","article-title":"Molecular\nmotion and ion diffusion in choline chloride based deep eutectic solvents\nstudied by 1H pulsed field gradient NMR spectroscopy","volume":"13","author":"D\u2019Agostino","year":"2011","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026080608123856200_cit47","doi-asserted-by":"publisher","DOI":"10.1016\/j.jct.2023.107179","article-title":"Volumetric\nand viscometric properties of aqueous choline chloride + methyldiethanolamine\ndeep eutectic solvents","volume":"188","author":"Liu","year":"2024","journal-title":"J. Chem. Thermodyn."},{"issue":"1","key":"2026080608123856200_cit48","doi-asserted-by":"publisher","first-page":"8","DOI":"10.1016\/j.gee.2019.03.002","article-title":"Overview of\nacidic deep eutectic solvents on synthesis, properties and applications","volume":"5","author":"Qin","year":"2020","journal-title":"Green Energy & Environment"},{"key":"2026080608123856200_cit49","doi-asserted-by":"publisher","first-page":"67","DOI":"10.1016\/j.jct.2017.08.032","article-title":"Densities and dynamic viscosities\nof ionic liquids\nhaving 1-butyl-3-methylimidazolium cation with different anions and\nbis(trifluoromethylsulfonyl)imide anion with different cations in\nthe temperature range (283.15 to 363.15)K","volume":"116","author":"Yadav","year":"2018","journal-title":"J.\nChem. Thermodyn."},{"key":"2026080608123856200_cit50","doi-asserted-by":"publisher","first-page":"167","DOI":"10.1016\/j.jelechem.2003.12.050","article-title":"Temperature dependence of viscosity\nfor room temperature\nionic liquids","volume":"568","author":"Okoturo","year":"2004","journal-title":"J. Electroanal. Chem."},{"issue":"15","key":"2026080608123856200_cit51","doi-asserted-by":"publisher","first-page":"5178","DOI":"10.1039\/c2cp00007e","article-title":"Physicochemical properties\ndetermined by \u0394pKa\nfor protic ionic liquids based on an organic super-strong base with\nvarious Bro\u0337nsted acids","volume":"14","author":"Miran","year":"2012","journal-title":"Phys. Chem. Chem.\nPhys."},{"issue":"1","key":"2026080608123856200_cit52","doi-asserted-by":"publisher","first-page":"81","DOI":"10.1021\/jp076462h","article-title":"Physical properties\nof ionic liquids consisting of the 1-butyl-3-methylimidazolium cation\nwith various anions and the bis(trifluoromethylsulfonyl)imide anion\nwith various cations","volume":"112","author":"Jin","year":"2008","journal-title":"J. Phys. Chem. 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