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This work combines a molecular level understanding using molecular dynamics simulations of a potential greener electrolyte formed using surfactant-free microemulsion systems and comparing their responses when subjected to temperatures ranging from 273 to 343 K. Two different systems n-butanol\u2013ethanol\u2013water (BEW) and triethyl citrate\u2013pentanediol\u2013water (PTW) were first mixed with organic zinc acetate salt and then were subjected to a temperature gradient. The insights after analyses reveal that the systems comprise preferential solvation and the ions are encapsulated by the organic compound layer. Thermodynamic analyses comprising of interaction energy and solvation free energy reveal that the systems maintain a balance between the enthalpic loss by compensating it with entropic gain. The PTW system surpasses BEW in structural stability and thermal resilience.<\/jats:p>","DOI":"10.1021\/acs.jpcb.6c02691","type":"journal-article","created":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T08:02:28Z","timestamp":1786608148000},"page":"8667-8679","source":"Crossref","is-referenced-by-count":0,"title":["Surfactant-Free\nMicroemulsion Electrolyte with Topological\nSolvation and Thermal Resilience for Zinc-Ion Batteries"],"prefix":"10.1021","volume":"130","author":[{"given":"Animesh Kumar","family":"Singh","sequence":"first","affiliation":[{"name":"Indian Institute of Technology Jodhpur , , ,","place":["Jodhpur, India, 342037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9038-608X","authenticated-orcid":true,"given":"Praveenkumar","family":"Sappidi","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Jodhpur , , ,","place":["Jodhpur, India, 342037"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,13]]},"reference":[{"issue":"7","key":"2026090114353039600_cit1","doi-asserted-by":"publisher","first-page":"1415","DOI":"10.1016\/j.joule.2023.06.007","article-title":"Zinc-ion batteries\nfor stationary energy storage","volume":"7","author":"Gourley","year":"2023","journal-title":"Joule"},{"issue":"10","key":"2026090114353039600_cit2","doi-asserted-by":"publisher","first-page":"3527","DOI":"10.1039\/D0EE01538E","article-title":"An aqueous\nhybrid electrolyte for low-temperature zinc-based energy\nstorage devices","volume":"13","author":"Chang","year":"2020","journal-title":"Energy Environ. 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