{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,28]],"date-time":"2026-10-28T05:44:42Z","timestamp":1793166282236,"version":"4.5.0"},"reference-count":62,"publisher":"American Chemical Society (ACS)","issue":"37","license":[{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["517122340"],"award-info":[{"award-number":["517122340"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Generating triplet states in dye molecules that do not undergo conventional intersystem crossing is of interest for a variety of applications. In this work, the photophysical processes that occur in a terrylene bisimide (TBI) cyclophane and in its host\u2013guest complex with 1,6-dibromopyrene (Ka = 1.5 \u00d7 104 M\u20131 in dichloromethane at 293 K) are studied. First, the pristine cyclophane was studied by transient absorption (TA) spectroscopy measurements in nonpolar toluene and polar dichloromethane. For toluene, the TA data indicate only two relaxation pathways, fluorescence (with a fluorescence quantum yield of 40%) and internal conversion to the ground state. In the more polar solvent dichloromethane, the pristine TBI cyclophane undergoes symmetry breaking charge separation (SBCS) after excitation to the S1 state based on clearly identified TBI radical anion and radical cation spectral signatures, with subsequent relaxation to the ground state without any evidence for triplet state population. In contrast, for the complex with dibromopyrene, the formation of a long-lived triplet state (a lifetime of \u03c4 = 8.47 \u03bcs) is formed from the SBCS state, which is attributed to the external heavy atom effect.<\/jats:p>","DOI":"10.1021\/acs.jpcb.6c02940","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T22:01:59Z","timestamp":1788472919000},"page":"9561-9568","source":"Crossref","is-referenced-by-count":1,"title":["Triplet Generation\nin a Terrylene Bisimide Cyclophane\nby External Heavy Atom Effect of Encapsulated Brominated Pyrene Guest"],"prefix":"10.1021","volume":"130","author":[{"given":"Jessica","family":"Ru\u0308he","sequence":"first","affiliation":[{"name":"Universita\u0308t Wu\u0308rzburg , , , ,","place":["Am Hubland, Wu\u0308rzburg, Germany, 97074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paul","family":"Mentzel","sequence":"additional","affiliation":[{"name":"Universita\u0308t Wu\u0308rzburg , , , ,","place":["Am Hubland, Wu\u0308rzburg, Germany, 97074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Schmiedel","sequence":"additional","affiliation":[{"name":"Universita\u0308t Wu\u0308rzburg , , , ,","place":["Am Hubland, Wu\u0308rzburg, Germany, 97074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marco","family":"Holzapfel","sequence":"additional","affiliation":[{"name":"Universita\u0308t Wu\u0308rzburg , , , ,","place":["Am Hubland, Wu\u0308rzburg, Germany, 97074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Menyha\u0301rt","family":"Sa\u0301rosi","sequence":"additional","affiliation":[{"name":"Universita\u0308t Wu\u0308rzburg , , , ,","place":["Am Hubland, Wu\u0308rzburg, Germany, 97074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9652-9165","authenticated-orcid":true,"given":"Christoph","family":"Lambert","sequence":"additional","affiliation":[{"name":"Universita\u0308t Wu\u0308rzburg , , , ,","place":["Am Hubland, Wu\u0308rzburg, Germany, 97074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7245-0471","authenticated-orcid":true,"given":"Frank","family":"Wu\u0308rthner","sequence":"additional","affiliation":[{"name":"Universita\u0308t Wu\u0308rzburg , , , ,","place":["Am Hubland, Wu\u0308rzburg, Germany, 97074"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,3]]},"reference":[{"key":"2026091708472013800_cit1","doi-asserted-by":"publisher","first-page":"6122","DOI":"10.1039\/D0CS00484G","article-title":"Access to\nthe triplet excited states of organic chromophores","volume":"49","author":"Sasikumar","year":"2020","journal-title":"Chem. Soc. Rev."},{"key":"2026091708472013800_cit2","doi-asserted-by":"publisher","first-page":"6975","DOI":"10.1021\/acs.chemrev.7b00617","article-title":"Spin-Vibronic Mechanism\nfor Intersystem Crossing","volume":"118","author":"Penfold","year":"2018","journal-title":"Chem. Rev."},{"key":"2026091708472013800_cit3","doi-asserted-by":"publisher","first-page":"617","DOI":"10.1146\/annurev-physchem-061020-053433","article-title":"Understanding\nand Controlling Intersystem Crossing in Molecules","volume":"72","author":"Marian","year":"2021","journal-title":"Annu. Rev. Phys. Chem."},{"key":"2026091708472013800_cit4","doi-asserted-by":"publisher","first-page":"6891","DOI":"10.1021\/cr1002613","article-title":"Singlet Fission","volume":"110","author":"Smith","year":"2010","journal-title":"Chem. Rev."},{"key":"2026091708472013800_cit5","doi-asserted-by":"publisher","first-page":"361","DOI":"10.1146\/annurev-physchem-040412-110130","article-title":"Recent Advances in\nSinglet Fission","volume":"64","author":"Smith","year":"2013","journal-title":"Annu. Rev.\nPhys. Chem."},{"key":"2026091708472013800_cit6","doi-asserted-by":"publisher","first-page":"4194","DOI":"10.1021\/jp800561g","article-title":"Intersystem\nCrossing Mediated by\nPhotoinduced Intramolecular Charge Transfer: Julolidine\u2013Anthracene\nMolecules with Perpendicular \u03c0 Systems","volume":"112","author":"Dance","year":"2008","journal-title":"J. Phys. Chem. A"},{"key":"2026091708472013800_cit7","doi-asserted-by":"publisher","first-page":"5428","DOI":"10.1039\/C6SC01574C","article-title":"Guest and\nsolvent modulated photo-driven charge separation and triplet generation\nin a perylene bisimide cyclophane","volume":"7","author":"Spenst","year":"2016","journal-title":"Chem. Sci."},{"key":"2026091708472013800_cit8","doi-asserted-by":"publisher","first-page":"15604","DOI":"10.1021\/jacs.5b08257","article-title":"Nonparallel Stacks of Donor and Acceptor\nChromophores Evade Geminate Charge Recombination","volume":"137","author":"Mallia","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"2026091708472013800_cit9","doi-asserted-by":"publisher","first-page":"4908","DOI":"10.1039\/D1SC00285F","article-title":"Long-lived triplet\ncharge-separated state in naphthalenediimide based donor\u2013acceptor\nsystems","volume":"12","author":"Aster","year":"2021","journal-title":"Chem. Sci."},{"key":"2026091708472013800_cit10","doi-asserted-by":"publisher","first-page":"3264","DOI":"10.1021\/acs.jpclett.8b01237","article-title":"Manipulating\nTriplet Yield through Control of Symmetry-Breaking Charge Transfer","volume":"9","author":"Das","year":"2018","journal-title":"J. Phys. Chem. Lett."},{"key":"2026091708472013800_cit11","doi-asserted-by":"publisher","first-page":"1470","DOI":"10.1126\/science.abl4254","article-title":"Readout of\nspin quantum beats in a charge-separated radical pair by pump-push\nspectroscopy","volume":"374","author":"Mims","year":"2021","journal-title":"Science"},{"key":"2026091708472013800_cit12","doi-asserted-by":"publisher","first-page":"23068","DOI":"10.1021\/jacs.5c06173","article-title":"Revealing the impactof g tensor anisotropy on the charge\nrecombination in donor acceptor dyads under high magnetic fields","volume":"147","author":"Mentzel","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026091708472013800_cit13","doi-asserted-by":"publisher","first-page":"6280","DOI":"10.1021\/acs.jpcb.1c03189","article-title":"Does Twisted \u03c0-Conjugation\nFramework Always Induce Efficient Intersystem Crossing? A Case Study\nwith Benzo[b]- and [a]Phenanthrene-Fused BODIPY Derivatives and Identification\nof a Dark State","volume":"125","author":"Yan","year":"2021","journal-title":"J. Phys. Chem. B"},{"key":"2026091708472013800_cit14","doi-asserted-by":"publisher","first-page":"10490","DOI":"10.1021\/jp075248q","article-title":"Intersystem\ncrossing processes in\nnonplanar aromatic heterocyclic molecules","volume":"111","author":"Schmidt","year":"2007","journal-title":"J.\nPhys. Chem. A"},{"key":"2026091708472013800_cit15","doi-asserted-by":"publisher","first-page":"8443","DOI":"10.1021\/acs.jpcc.6b00755","article-title":"Access to\nTriplet Excited State in Core-Twisted Perylenediimide","volume":"120","author":"Nagarajan","year":"2016","journal-title":"J. Phys. Chem. C"},{"key":"2026091708472013800_cit16","doi-asserted-by":"publisher","first-page":"1183","DOI":"10.1002\/anie.201507961","article-title":"Cethrene:\nA Helically Chiral Biradicaloid Isomer of Heptazethrene","volume":"55","author":"Ravat","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026091708472013800_cit17","doi-asserted-by":"publisher","first-page":"6982","DOI":"10.1002\/anie.201901672","article-title":"Persistent\nSolid-State Phosphorescence and Delayed Fluorescence at Room Temperature\nby a Twisted Hydrocarbon","volume":"58","author":"Salla","year":"2019","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026091708472013800_cit18","doi-asserted-by":"publisher","first-page":"5379","DOI":"10.1021\/cr300471v","article-title":"Excited state aromaticity\nand antiaromaticity: opportunities for photophysical and photochemical\nrationalizations","volume":"114","author":"Rosenberg","year":"2014","journal-title":"Chem. Rev."},{"key":"2026091708472013800_cit19","doi-asserted-by":"publisher","first-page":"418","DOI":"10.1038\/nchem.2233","article-title":"Reversal of Hu\u0308ckel (anti)aromaticity\nin the lowest triplet states of hexaphyrins and spectroscopic evidence\nfor Baird\u2019s rule","volume":"7","author":"Sung","year":"2015","journal-title":"Nat. Chem."},{"key":"2026091708472013800_cit20","doi-asserted-by":"publisher","first-page":"13867","DOI":"10.1021\/jacs.9b06346","article-title":"Exploiting\nExcited-State Aromaticity To Design Highly Stable Singlet Fission\nMaterials","volume":"141","author":"Fallon","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"2026091708472013800_cit21","doi-asserted-by":"publisher","first-page":"905","DOI":"10.1063\/1.1747085","article-title":"Triplet-Singlet\nTransitions in Organic Molecules. Lifetime Measurements of the Triplet\nState","volume":"17","author":"McClure","year":"1949","journal-title":"J. Chem. Phys."},{"key":"2026091708472013800_cit22","doi-asserted-by":"publisher","first-page":"205","DOI":"10.1038\/nchem.984","article-title":"Activating efficient\nphosphorescence from purely organic materials by crystal design","volume":"3","author":"Bolton","year":"2011","journal-title":"Nat. Chem."},{"key":"2026091708472013800_cit23","doi-asserted-by":"publisher","first-page":"2589","DOI":"10.1021\/jp5013347","article-title":"Evidence\nfor the Rapid Conversion\nof Primary Photoexcitations to Triplet States in Seleno- and Telluro-\nAnalogues of Poly(3-hexylthiophene)","volume":"118","author":"Pensack","year":"2014","journal-title":"J. Phys.\nChem. B"},{"key":"2026091708472013800_cit24","doi-asserted-by":"publisher","first-page":"208","DOI":"10.1016\/j.trechm.2025.03.001","article-title":"Control of\nphotoluminescence properties by tailored\nsupramolecular matrices","volume":"7","author":"Wu\u0308rthner","year":"2025","journal-title":"Trends Chem."},{"key":"2026091708472013800_cit25","doi-asserted-by":"publisher","first-page":"9068","DOI":"10.1002\/anie.200902532","article-title":"The Rylene\nColorant Family Tailored Nanoemitters for Photonics Research and Applications","volume":"49","author":"Weil","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026091708472013800_cit26","doi-asserted-by":"publisher","first-page":"8493","DOI":"10.1039\/c2dt30765k","article-title":"Transition\nmetal complexes meet the rylenes","volume":"41","author":"Castellano","year":"2012","journal-title":"Dalton Trans."},{"key":"2026091708472013800_cit27","doi-asserted-by":"publisher","first-page":"6867","DOI":"10.1021\/acs.jpcb.0c03281","article-title":"Near-Quantitative\nTriplet State Population via Ultrafast Intersystem Crossing in Perbromoperylenediimide","volume":"124","author":"Mohan","year":"2020","journal-title":"J. Phys. Chem. B"},{"key":"2026091708472013800_cit28","doi-asserted-by":"publisher","first-page":"26254","DOI":"10.1039\/D2CP02723B","article-title":"Excited states and spin\u2013orbit coupling in chalcogen\nsubstituted perylene diimides and their radical anions","volume":"24","author":"Mentzel","year":"2022","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026091708472013800_cit29","doi-asserted-by":"publisher","first-page":"13319","DOI":"10.1021\/acs.jpcc.2c03847","article-title":"Ultrafast\nIntersystem Crossing in Selenium-Annulated\nPerylene Bisimide","volume":"126","author":"Sivanarayanan","year":"2022","journal-title":"J. Phys. Chem. C"},{"key":"2026091708472013800_cit30","doi-asserted-by":"publisher","first-page":"2207331","DOI":"10.1002\/adma.202207331","article-title":"Activating\nOrganic Phosphorescence via Heavy Metal\u2212\u03c0 Interaction\nInduced Intersystem Crossing","volume":"34","author":"Sun","year":"2022","journal-title":"Adv. Mater."},{"key":"2026091708472013800_cit31","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202411102","article-title":"2,3:6,7-Naphthalene\nBis(dicarboximide) Cyclophane: A Photofunctional Host for Ambient\nDelayed Fluorescence in Solution","volume":"136","author":"Garain","year":"2024","journal-title":"Angew. Chem."},{"key":"2026091708472013800_cit32","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202520184","article-title":"Guest-Induced\nActivation of Multicolor Photoluminescence in Naphthalene Bisimide\nLiquid Crystals","volume":"38","author":"Nowarra","year":"2026","journal-title":"Adv. Mater."},{"key":"2026091708472013800_cit33","doi-asserted-by":"publisher","first-page":"1031","DOI":"10.1016\/j.matt.2020.08.021","article-title":"Advances in Physicochemically\nStimuli-Responsive Materials for On-Demand Transient Electronic Systems","volume":"3","author":"Lee","year":"2020","journal-title":"Matter"},{"key":"2026091708472013800_cit34","doi-asserted-by":"publisher","first-page":"71","DOI":"10.1063\/1.1700199","article-title":"Collisional\nPerturbation of Spin-Orbital Coupling and the Mechanism of Fluorescence\nQuenching. A Visual Demonstration of the Perturbation","volume":"20","author":"Kasha","year":"1952","journal-title":"J. Chem. Phys."},{"key":"2026091708472013800_cit35","doi-asserted-by":"publisher","first-page":"22","DOI":"10.1021\/j100390a006","article-title":"Mechanism of external\nheavy atom effect on intersystem crossing in\nfluid solutions. Analysis based on fluorescence decay data","volume":"86","author":"Shimizu","year":"1982","journal-title":"J. Phys. Chem."},{"key":"2026091708472013800_cit36","doi-asserted-by":"publisher","first-page":"6578","DOI":"10.1021\/acs.jpca.8b05813","article-title":"Boosting\nthe Heavy Atom Effect by Cavitand Encapsulation: Room Temperature\nPhosphorescence of Pyrene in the Presence of Oxygen","volume":"122","author":"Easley","year":"2018","journal-title":"J. Phys. Chem. A"},{"key":"2026091708472013800_cit37","doi-asserted-by":"publisher","first-page":"11113","DOI":"10.1021\/acs.analchem.7b03377","article-title":"Selective\nHeavy Element Sensing with a Simple Host\u2013Guest\nFluorescent Array","volume":"89","author":"Liu","year":"2017","journal-title":"Anal. Chem."},{"key":"2026091708472013800_cit38","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202318451","article-title":"A Terrylene\nBisimide based Universal Host for Aromatic Guests to Derive Contact\nSurface-Dependent Dispersion Energies","volume":"63","author":"Ru\u0308he","year":"2024","journal-title":"Angew.\nChem., Int. Ed."},{"key":"2026091708472013800_cit39","doi-asserted-by":"publisher","first-page":"3959","DOI":"10.1002\/chem.200401177","article-title":"Synthesis\nand Modification of Terrylenediimides as High-Performance Fluorescent\nDyes","volume":"11","author":"Nolde","year":"2005","journal-title":"Chem.\u2500Eur. J."},{"key":"2026091708472013800_cit40","doi-asserted-by":"publisher","first-page":"385","DOI":"10.1016\/j.jlumin.2012.08.017","article-title":"Rhodamine 800 as reference substance\nfor fluorescence quantum yield measurements in deep red emission range","volume":"134","author":"Alessi","year":"2013","journal-title":"J. Lumin."},{"key":"2026091708472013800_cit41","doi-asserted-by":"publisher","first-page":"9013","DOI":"10.1039\/C9CP00908F","article-title":"Dynamic exciton\nlocalisation in a pyrene\u2013BODIPY\u2013pyrene dye conjugate","volume":"21","author":"Auerhammer","year":"2019","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026091708472013800_cit42","unstructured":"Gaussian 16, Revision C.01, Frisch, M. J.; et al.; Gaussian Inc., Wallingford, CT, 2016."},{"key":"2026091708472013800_cit43","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.70019","article-title":"Software update:\nthe ORCA program system, version 6.0","volume":"15","author":"Neese","year":"2025","journal-title":"WIRES\nComput. Mol. Sci."},{"key":"2026091708472013800_cit44","doi-asserted-by":"publisher","first-page":"104109","DOI":"10.1063\/5.0058766","article-title":"An improved\nchain of spheres for exchange algorithm","volume":"155","author":"Helmich-Paris","year":"2021","journal-title":"J.\nChem. Phys."},{"key":"2026091708472013800_cit45","doi-asserted-by":"publisher","first-page":"154122","DOI":"10.1063\/1.5090222","article-title":"A generally applicable\natomic-charge dependent London dispersion correction","volume":"150","author":"Caldeweyher","year":"2019","journal-title":"J. Chem. Phys."},{"key":"2026091708472013800_cit46","doi-asserted-by":"publisher","first-page":"7069","DOI":"10.1021\/acs.chemrev.7b00581","article-title":"Expanded Theory\nof H- and J-Molecular Aggregates: The\nEffects of Vibronic Coupling and Intermolecular Charge Transfer","volume":"118","author":"Hestand","year":"2018","journal-title":"Chem. Rev."},{"key":"2026091708472013800_cit47","doi-asserted-by":"publisher","first-page":"77","DOI":"10.1021\/jp208794t","article-title":"Absorption,\nCircular Dichroism, and Photoluminescence in Perylene Diimide Bichromophores:\nPolarization-Dependent H- and J-Aggregate Behavior","volume":"116","author":"Kistler","year":"2012","journal-title":"J. Phys. Chem. B"},{"key":"2026091708472013800_cit48","doi-asserted-by":"publisher","first-page":"149","DOI":"10.1055\/s-0040-1709998","article-title":"Perylene Bisimide\nCyclophanes: Structure\u2013Property Relationships upon Variation\nof the Cavity Size","volume":"02","author":"Ru\u0308he","year":"2020","journal-title":"Org. Mater."},{"key":"2026091708472013800_cit49","doi-asserted-by":"publisher","first-page":"350","DOI":"10.1039\/D1MH01019K","article-title":"Substituent-dependent absorption and fluorescence properties\nof perylene bisimide radical anions and dianions","volume":"9","author":"Renner","year":"2022","journal-title":"Mater. Horiz."},{"key":"2026091708472013800_cit50","doi-asserted-by":"publisher","first-page":"3199","DOI":"10.1021\/jp026459s","article-title":"Intramolecular Directional Energy Transfer Processes\nin Dendrimers Containing Perylene and Terrylene Chromophores","volume":"107","author":"Schweitzer","year":"2003","journal-title":"J. Phys. Chem. A"},{"key":"2026091708472013800_cit51","doi-asserted-by":"publisher","first-page":"61","DOI":"10.1039\/b409346c","article-title":"Photophysical study of photoinduced\nelectron transfer in a bis-thiophene substituted peryleneimide","volume":"4","author":"Fron","year":"2005","journal-title":"Photochem. Photobiol. Sci."},{"key":"2026091708472013800_cit52","doi-asserted-by":"publisher","first-page":"3513","DOI":"10.1021\/ja984188m","article-title":"Electrochemistry, Spectroscopy and Electrogenerated\nChemiluminescence of Perylene, Terrylene, and Quaterrylene Diimides\nin Aprotic Solution","volume":"121","author":"Lee","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"2026091708472013800_cit53","doi-asserted-by":"publisher","first-page":"10408","DOI":"10.1021\/acs.jpcc.0c02382","article-title":"Reversible Symmetry-Breaking Charge\nSeparation in a Series of Perylenediimide Cyclophanes","volume":"124","author":"Coleman","year":"2020","journal-title":"J. Phys. Chem. C"},{"key":"2026091708472013800_cit54","doi-asserted-by":"publisher","first-page":"9184","DOI":"10.1021\/jacs.8b04830","article-title":"Singlet Fission in Covalent Terrylenediimide Dimers:\nProbing the Nature of the Multiexciton State Using Femtosecond Mid-Infrared\nSpectroscopy","volume":"140","author":"Chen","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"2026091708472013800_cit55","doi-asserted-by":"publisher","first-page":"6945","DOI":"10.1021\/acs.jpcb.1c02476","article-title":"Temperature Tuning of Coherent Mixing\nbetween States Driving Singlet Fission in a Spiro-Fused Terrylenediimide\nDimer","volume":"125","author":"Zhao","year":"2021","journal-title":"J. Phys. Chem. B"},{"key":"2026091708472013800_cit56","doi-asserted-by":"publisher","first-page":"1120","DOI":"10.1038\/nchem.2589","article-title":"Enabling\nsinglet fission by controlling\nintramolecular charge transfer in \u03c0-stacked covalent terrylenediimide\ndimers","volume":"8","author":"Margulies","year":"2016","journal-title":"Nat. Chem."},{"key":"2026091708472013800_cit57","doi-asserted-by":"publisher","first-page":"1957","DOI":"10.1021\/acs.accounts.0c00397","article-title":"Mixed Electronic States in Molecular Dimers: Connecting\nSinglet Fission, Excimer Formation, and Symmetry-Breaking Charge Transfer","volume":"53","author":"Young","year":"2020","journal-title":"Acc. Chem. Res."},{"key":"2026091708472013800_cit58","doi-asserted-by":"publisher","first-page":"1919","DOI":"10.1021\/acs.jpclett.9b00357","article-title":"Solvent-Modulated Charge-Transfer\nResonance Enhancement in the Excimer State of a Bay-Substituted Perylene\nBisimide Cyclophane","volume":"10","author":"Kim","year":"2019","journal-title":"J. Phys. Chem. Lett."},{"key":"2026091708472013800_cit59","doi-asserted-by":"publisher","first-page":"3081","DOI":"10.1039\/D4CC06070A","article-title":"F. Photofunctional\ncyclophane host\u2013guest systems","volume":"61","author":"Garain","year":"2025","journal-title":"Chem.\nCommun."},{"key":"2026091708472013800_cit60","first-page":"28222","article-title":"Guest-Mediated\nModulation of Photophysical Pathways\nin a Coronene Bisimide Cyclophane","volume":"146","author":"Ru\u0308he","year":"2024","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026091708472013800_cit61","doi-asserted-by":"publisher","first-page":"1827","DOI":"10.1016\/S0021-9258(18)96076-X","article-title":"Kinetics\nof Cofactor-activated Enzyme-catalyzed Reactions","volume":"242","author":"Alben","year":"1967","journal-title":"J. Biol. Chem."},{"key":"2026091708472013800_cit62","doi-asserted-by":"publisher","first-page":"919","DOI":"10.1038\/sj.emboj.7600585","article-title":"Mechanisms\nof photoprotection and nonphotochemical quenching in pea light-harvesting\ncomplex at 2.5 \u00c5 resolution","volume":"24","author":"Standfuss","year":"2005","journal-title":"EMBO J."}],"container-title":["The Journal of Physical\nChemistry B"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpcb.6c02940","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jpcbfk\/article-pdf\/130\/37\/9561\/68309193\/acs.jpcb.6c02940.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jpcbfk\/article-pdf\/130\/37\/9561\/68309193\/acs.jpcb.6c02940.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T13:03:21Z","timestamp":1789650201000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jpcbfk\/article\/130\/37\/9561\/5415296\/Triplet-Generation-in-a-Terrylene-Bisimide"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,3]]},"references-count":62,"journal-issue":{"issue":"37","published-online":{"date-parts":[[2026,9,3]]},"published-print":{"date-parts":[[2026,9,17]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.jpcb.6c02940","relation":{},"ISSN":["1520-6106","1520-5207"],"issn-type":[{"value":"1520-6106","type":"print"},{"value":"1520-5207","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,3]]}}}