{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T14:08:21Z","timestamp":1785420501713,"version":"3.56.0"},"reference-count":52,"publisher":"American Chemical Society (ACS)","issue":"30","license":[{"start":{"date-parts":[[2026,7,19]],"date-time":"2026-07-19T00:00:00Z","timestamp":1784419200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100031478","name":"NextGenerationEU","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/100031478","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003407","name":"Ministero dell?Istruzione, dell?Universit? e della Ricerca","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100003407","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,7,30]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Sodium-ion batteries are cost-effective and sustainable alternatives to lithium-ion batteries. Recently, metal anode batteries have gained prominence over metal-ion systems due to their higher theoretical capacities. However, sodium metal batteries employing conventional organic electrolytes face persistent challenges, including dendrite formation and unstable solid-electrolyte interphase (SEI) layers. Thus, the choice of electrolyte plays a critical role in improving battery stability and performance. Ionic liquids (ILs) offer a promising pathway to improved performance owing to their high thermal and electrochemical stability and excellent ionic conductivity. In this work, we employ density functional theory (DFT) and ab initio molecular dynamics (AIMD) simulations to gain atomistic insights into SEI formation and stability by investigating the interactions of the IL containing N,N-methylpropylpyrrolidinium (PYR13+) cation, bis(fluorosulfonyl)amide (FSI\u2013) and bis(trifluoromethylsulfonyl)-amide (TFSI\u2013) anions (PYR13FSI and PYR13TFSI), along with sodium salts NaFSI and NaTFSI, with the Na(110) metallic surface. Detailed geometric and electronic structure analyses capture the anode\/electrolyte interfacial chemistry, encompassing both IL and salt interactions and their decomposition pathways to model the early stages of SEI formation. Our results show that FSI\u2013 interacts more strongly than TFSI\u2013 and undergoes spontaneous dissociation upon structural relaxation, whereas PYR13+ and TFSI\u2013 remain intact. AIMD trajectories at 298 K over 5\u201310 ps reveal the formation of decomposition products, primarily NaF, which is known to contribute to SEI stabilization. Compared to FSI\u2013, TFSI\u2013 exhibits delayed decomposition, and PYR13+ cation remains intact throughout. Overall, these findings unravel the distinct interfacial behaviors of FSI\u2013 and TFSI\u2013 and highlight the critical role of anion chemistry in governing SEI formation and stability in sodium metal batteries.<\/jats:p>","DOI":"10.1021\/acs.jpcc.6c02391","type":"journal-article","created":{"date-parts":[[2026,7,19]],"date-time":"2026-07-19T12:55:01Z","timestamp":1784465701000},"page":"10520-10532","source":"Crossref","is-referenced-by-count":0,"title":["Adsorption and\nReactivity of Na+ Salt and\nRoom-Temperature Ionic Liquid at Na Metal Surface"],"prefix":"10.1021","volume":"130","author":[{"given":"Ranjini","family":"Sarkar","sequence":"first","affiliation":[{"name":"University of Naples Federico II , , Comp. Univ. Monte Sant\u2019Angelo via Cintia 21 , ,","place":["Napoli, Italy, 80126"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9008-6044","authenticated-orcid":true,"given":"Francesca","family":"Fasulo","sequence":"additional","affiliation":[{"name":"University of Naples Federico II , , Comp. Univ. Monte Sant\u2019Angelo via Cintia 21 , ,","place":["Napoli, Italy, 80126"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9940-7358","authenticated-orcid":true,"given":"Ana Bele\u0301n","family":"Mun\u0303oz-Garci\u0301a","sequence":"additional","affiliation":[{"name":"University of Naples Federico II , , Comp. Univ. 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