{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,17]],"date-time":"2026-04-17T00:06:15Z","timestamp":1776384375019,"version":"3.51.2"},"reference-count":29,"publisher":"American Chemical Society (ACS)","issue":"8","license":[{"start":{"date-parts":[[2023,2,22]],"date-time":"2023-02-22T00:00:00Z","timestamp":1677024000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","award":["EP\/R002605X\/1"],"award-info":[{"award-number":["EP\/R002605X\/1"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","award":["EP\/S033181\/1"],"award-info":[{"award-number":["EP\/S033181\/1"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000288","name":"Royal Society","doi-asserted-by":"publisher","award":["URF191320"],"award-info":[{"award-number":["URF191320"]}],"id":[{"id":"10.13039\/501100000288","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100010663","name":"H2020 European Research Council","doi-asserted-by":"publisher","award":["CoG-816268"],"award-info":[{"award-number":["CoG-816268"]}],"id":[{"id":"10.13039\/100010663","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100010663","name":"H2020 European Research Council","doi-asserted-by":"publisher","award":["StG-851504"],"award-info":[{"award-number":["StG-851504"]}],"id":[{"id":"10.13039\/100010663","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Phys. Chem. Lett."],"published-print":{"date-parts":[[2023,3,2]]},"DOI":"10.1021\/acs.jpclett.3c00034","type":"journal-article","created":{"date-parts":[[2023,2,22]],"date-time":"2023-02-22T18:24:26Z","timestamp":1677090266000},"page":"2193-2200","source":"Crossref","is-referenced-by-count":12,"title":["Measurement of the Quantum Tunneling Gap in a Dysprosocenium Single-Molecule Magnet"],"prefix":"10.1021","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3911-1731","authenticated-orcid":true,"given":"William J. A.","family":"Blackmore","sequence":"first","affiliation":[{"name":"Department of Chemistry, School of Natural Sciences, University of Manchester, Oxford Road, Manchester M13 9PL, U.K."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrea","family":"Mattioni","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Natural Sciences, University of Manchester, Oxford Road, Manchester M13 9PL, U.K."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1683-2667","authenticated-orcid":true,"given":"Sophie C.","family":"Corner","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Natural Sciences, University of Manchester, Oxford Road, Manchester M13 9PL, U.K."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peter","family":"Evans","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Natural Sciences, University of Manchester, Oxford Road, Manchester M13 9PL, U.K."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7579-4226","authenticated-orcid":true,"given":"Gemma K.","family":"Gransbury","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Natural Sciences, University of Manchester, Oxford Road, Manchester M13 9PL, U.K."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1575-7754","authenticated-orcid":true,"given":"David P.","family":"Mills","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Natural Sciences, University of Manchester, Oxford Road, Manchester M13 9PL, U.K."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8604-0171","authenticated-orcid":true,"given":"Nicholas F.","family":"Chilton","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Natural Sciences, University of Manchester, Oxford Road, Manchester M13 9PL, U.K."}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2023,2,22]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1146\/annurev-matsci-081420-042553"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1038\/nature23447"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1126\/science.abl5470"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1126\/science.aav0652"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC03907K"},{"key":"ref6\/cit6","doi-asserted-by":"crossref","DOI":"10.1093\/acprof:oso\/9780198567530.001.0001","volume-title":"Molecular Nanomagnets","author":"Gatteschi D.","year":"2006"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.99.180408"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1063\/1.373379"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.72.214429"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1098\/rspa.1932.0165"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/jp040627u"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1063\/1.361837"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.55.5858"},{"key":"ref14\/cit14","first-page":"179","volume-title":"Exploring the Quantum Classical Frontier: Recent Advances in Macroscopic Quantum Phenomena","author":"Friedman J. R.","year":"2003"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1007\/s10909-005-6016-3"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462638"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.95.184403"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.63.2512"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1063\/1.345921"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1016\/S0304-8853(97)00799-3"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1209\/epl\/i2000-00305-x"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.79.104423"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC06722F"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.82.3903"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRev.46.1002"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1103\/RevModPhys.15.1"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.120.147202"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.87.195412"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2014.10.012"}],"container-title":["The Journal of Physical Chemistry Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpclett.3c00034","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpclett.3c00034","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,3,2]],"date-time":"2023-03-02T10:24:55Z","timestamp":1677752695000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.jpclett.3c00034"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,2,22]]},"references-count":29,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2023,3,2]]}},"alternative-id":["10.1021\/acs.jpclett.3c00034"],"URL":"https:\/\/doi.org\/10.1021\/acs.jpclett.3c00034","relation":{},"ISSN":["1948-7185","1948-7185"],"issn-type":[{"value":"1948-7185","type":"print"},{"value":"1948-7185","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,2,22]]}}}