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Even more interesting is the possibility to dynamically access different heat conduction states, as it potentially leads to the real-time control of heat flow. Here, we leverage phase-engineering in MoTe2, a 2D van der Waals transition metal dichalcogenide, showing that the thermal conductivity undergoes a giant increase (\u223c270% at room temperature) upon the phase transition between the common 2H and 1T\u2032 polymorphs. Our first-principles calculations trace back this very large change to the different effects that four-phonon processes have on the two crystal phases. Importantly, the 2H \u2194 1T\u2032 phase transition is ultrafast and reversible and can be triggered by external electric fields, light absorption, and THz pulses.<\/jats:p>","DOI":"10.1021\/acs.jpclett.5c03836","type":"journal-article","created":{"date-parts":[[2026,1,19]],"date-time":"2026-01-19T18:58:22Z","timestamp":1768849102000},"page":"1262-1270","source":"Crossref","is-referenced-by-count":3,"title":["RETRACTED: Giant Thermal Switching via Phase Transition\nin MoTe2"],"prefix":"10.1021","volume":"17","author":[{"given":"Zhuyao","family":"Chang","sequence":"first","affiliation":[{"name":"Hebei Normal University , , ,","place":["Shijiazhuang, China, 050024"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nemo","family":"McIntosh","sequence":"additional","affiliation":[{"name":"Institut de Cie\u0300ncia de Materials de Barcelona, ICMAB-CSIC, Campus UAB , ,","place":["Bellaterra, Spain, 08193"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhao","family":"Liu","sequence":"additional","affiliation":[{"name":"Hebei Normal University , , ,","place":["Shijiazhuang, China, 050024"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4086-4191","authenticated-orcid":true,"given":"Riccardo","family":"Rurali","sequence":"additional","affiliation":[{"name":"Institut de Cie\u0300ncia de Materials de Barcelona, ICMAB-CSIC, Campus UAB , ,","place":["Bellaterra, Spain, 08193"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,1,19]]},"reference":[{"key":"2026091812074816500_cit1","doi-asserted-by":"publisher","first-page":"699","DOI":"10.1038\/nnano.2012.193","article-title":"Electronics\nand optoelectronics of two-dimensional transition metal dichalcogenides","volume":"7","author":"Wang","year":"2012","journal-title":"Nat. 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Rev."},{"key":"2026091812074816500_cit11","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218016","article-title":"2D Transition Metal\nDichalcogenides for Photocatalysis","volume":"62","author":"Yang","year":"2023","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026091812074816500_cit12","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.105.136805","article-title":"Atomically Thin\nMoS2: A New Direct-Gap Semiconductor","volume":"105","author":"Mak","year":"2010","journal-title":"Phys. Rev. Lett."},{"key":"2026091812074816500_cit13","doi-asserted-by":"publisher","first-page":"111","DOI":"10.1038\/nnano.2013.277","article-title":"Direct observation of the transition from indirect to direct bandgap\nin atomically thin epitaxial MoSe2","volume":"9","author":"Zhang","year":"2014","journal-title":"Nat. Nanotechnol."},{"key":"2026091812074816500_cit14","doi-asserted-by":"publisher","first-page":"1136","DOI":"10.1021\/nl2021575","article-title":"Ambipolar MoS2 Thin Flake\nTransistors","volume":"12","author":"Zhang","year":"2012","journal-title":"Nano Lett."},{"key":"2026091812074816500_cit15","doi-asserted-by":"publisher","first-page":"6275","DOI":"10.1021\/nl502603d","article-title":"Chloride Molecular\nDoping Technique on 2D Materials: WS2 and MoS2","volume":"14","author":"Yang","year":"2014","journal-title":"Nano Lett."},{"key":"2026091812074816500_cit16","doi-asserted-by":"publisher","first-page":"4908","DOI":"10.1364\/OE.21.004908","article-title":"Photoluminescence\nemission and Raman response of monolayer MoS2, MoSe2, and WSe2","volume":"21","author":"Tonndorf","year":"2013","journal-title":"Opt. 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Mater."},{"key":"2026091812074816500_cit31","doi-asserted-by":"publisher","first-page":"4214","DOI":"10.1038\/ncomms5214","article-title":"Structural phase transitions in two-dimensional\nMo- and W-dichalcogenide monolayers","volume":"5","author":"Duerloo","year":"2014","journal-title":"Nat. Commun."},{"key":"2026091812074816500_cit32","doi-asserted-by":"publisher","first-page":"4083","DOI":"10.1021\/acsphotonics.4c00896","article-title":"Locally Phase-Engineered MoTe2 for Near-Infrared Photodetectors","volume":"11","author":"Hidding","year":"2024","journal-title":"ACS\nPhotonics"},{"key":"2026091812074816500_cit33","doi-asserted-by":"publisher","DOI":"10.1063\/5.0238421","article-title":"Electrically tunable metal\u2013semiconductor behavior\nin 2H-MoTe2","volume":"137","author":"Manoj Kumar","year":"2025","journal-title":"J.\nAppl. Phys."},{"key":"2026091812074816500_cit34","doi-asserted-by":"publisher","first-page":"5905","DOI":"10.1038\/s41467-023-41291-w","article-title":"Intrinsic 1T\u2032 phase induced in atomically\nthin 2H-MoTe2 by a single terahertz pulse","volume":"14","author":"Shi","year":"2023","journal-title":"Nat. Commun."},{"key":"2026091812074816500_cit35","doi-asserted-by":"publisher","first-page":"1036","DOI":"10.1039\/D1MH01772A","article-title":"Ultrafast and stable\nphase transition realized in MoTe2-based memristive devices","volume":"9","author":"He","year":"2022","journal-title":"Mater. Horiz."},{"key":"2026091812074816500_cit36","doi-asserted-by":"publisher","first-page":"6708","DOI":"10.1021\/acsnano.2c12610","article-title":"Gate and Temperature Driven Phase Transitions in Few-Layer\nMoTe2","volume":"17","author":"Kowalczyk","year":"2023","journal-title":"ACS Nano"},{"key":"2026091812074816500_cit37","doi-asserted-by":"publisher","first-page":"19964","DOI":"10.1039\/C8NR06115G","article-title":"Controllable 2H-to-1T\u2032 phase transition in few-layer MoTe2","volume":"10","author":"Tan","year":"2018","journal-title":"Nanoscale"},{"key":"2026091812074816500_cit38","doi-asserted-by":"publisher","first-page":"1045","DOI":"10.1103\/RevModPhys.84.1045","article-title":"Colloquium: Phononics: Manipulating Heat Flow with Electronic Analogs\nand Beyond","volume":"84","author":"Li","year":"2012","journal-title":"Rev. Mod. Phys."},{"key":"2026091812074816500_cit39","doi-asserted-by":"publisher","first-page":"530","DOI":"10.1038\/s41578-024-00690-1","article-title":"Using oxides to compute\nwith heat","volume":"9","author":"Nataf","year":"2024","journal-title":"Nat. Rev. Mater."},{"key":"2026091812074816500_cit40","doi-asserted-by":"publisher","DOI":"10.1063\/1.5001072","article-title":"Thermal diodes,\nregulators, and switches: Physical mechanisms and potential applications","volume":"4","author":"Wehmeyer","year":"2017","journal-title":"Appl. Phys. Rev."},{"key":"2026091812074816500_cit41","doi-asserted-by":"publisher","first-page":"14","DOI":"10.1038\/s41699-020-0147-x","article-title":"Sub-picosecond photo-induced displacive\nphase transition in two-dimensional MoTe2","volume":"4","author":"Peng","year":"2020","journal-title":"npj 2D Mater. 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Matter"},{"key":"2026091812074816500_cit57","doi-asserted-by":"publisher","first-page":"204","DOI":"10.1080\/21663831.2016.1174163","article-title":"Physically\nfounded phonon dispersions of few-layer materials and the case of\nborophene","volume":"4","author":"Carrete","year":"2016","journal-title":"Mater. Res. Lett."},{"key":"2026091812074816500_cit58","doi-asserted-by":"publisher","first-page":"1747","DOI":"10.1016\/j.cpc.2014.02.015","article-title":"ShengBTE: a solver\nof the Boltzmann transport equation for phonons","volume":"185","author":"Li","year":"2014","journal-title":"Comput. Phys. Commun."},{"key":"2026091812074816500_cit59","doi-asserted-by":"publisher","DOI":"10.1016\/j.cpc.2021.108179","article-title":"FourPhonon:\nAn extension module to ShengBTE for computing four-phonon scattering\nrates and thermal conductivity","volume":"270","author":"Han","year":"2022","journal-title":"Comput. Phys.\nCommun."},{"key":"2026091812074816500_cit60","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.86.174307","article-title":"Thermal conductivity\nof bulk and nanowire Mg2SixSn1\u2013x alloys from first principles","volume":"86","author":"Li","year":"2012","journal-title":"Phys. Rev. B"},{"key":"2026091812074816500_cit61","doi-asserted-by":"publisher","first-page":"858","DOI":"10.1103\/PhysRevB.27.858","article-title":"Isotope scattering\nof dispersive phonons in Ge","volume":"27","author":"Tamura","year":"1983","journal-title":"Phys. Rev. B"},{"key":"2026091812074816500_cit62","doi-asserted-by":"publisher","first-page":"482","DOI":"10.1038\/nphys3314","article-title":"Bandgap opening in few-layered monoclinic\nMoTe 2","volume":"11","author":"Keum","year":"2015","journal-title":"Nat. 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