{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,18]],"date-time":"2026-06-18T08:53:30Z","timestamp":1781772810633,"version":"3.54.5"},"reference-count":86,"publisher":"American Chemical Society (ACS)","issue":"24","license":[{"start":{"date-parts":[[2026,5,19]],"date-time":"2026-05-19T00:00:00Z","timestamp":1779148800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,5,19]],"date-time":"2026-05-19T00:00:00Z","timestamp":1779148800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,5,19]],"date-time":"2026-05-19T00:00:00Z","timestamp":1779148800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["24KJ1460"],"award-info":[{"award-number":["24KJ1460"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003033","name":"Ministerio de Ciencia, Tecnolog?a e Innovaci?n","doi-asserted-by":"publisher","award":["CEX2023-001316-M"],"award-info":[{"award-number":["CEX2023-001316-M"]}],"id":[{"id":"10.13039\/501100003033","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003033","name":"Ministerio de Ciencia, Tecnolog?a e Innovaci?n","doi-asserted-by":"publisher","award":["PID2022-138470NB-I00"],"award-info":[{"award-number":["PID2022-138470NB-I00"]}],"id":[{"id":"10.13039\/501100003033","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Phys. Chem. Lett."],"published-print":{"date-parts":[[2026,6,18]]},"DOI":"10.1021\/acs.jpclett.6c00416","type":"journal-article","created":{"date-parts":[[2026,5,19]],"date-time":"2026-05-19T13:35:47Z","timestamp":1779197747000},"page":"6587-6595","source":"Crossref","is-referenced-by-count":0,"title":["Mechanistic Insights into the Delayed Fragmentation of Photoionized Ethanol"],"prefix":"10.1021","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-8580-4288","authenticated-orcid":true,"given":"Tomohiko","family":"Nakao","sequence":"first","affiliation":[{"name":"Department of Nuclear Engineering","place":["Kyoto, Japan"]},{"name":"Kyoto University","place":["Kyoto, Japan"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tatsuo","family":"Kaneyasu","sequence":"additional","affiliation":[{"name":"UVSOR Synchrotron Facility","place":["Okazaki, Japan"]},{"name":"Institute for Molecular Science","place":["Okazaki, Japan"]},{"name":"Sokendai (The Graduate University for Advanced Studies)","place":["Okazaki, Japan"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takuma","family":"Yanagawaya","sequence":"additional","affiliation":[{"name":"Department of Nuclear Engineering","place":["Kyoto, Japan"]},{"name":"Kyoto University","place":["Kyoto, Japan"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hiroshi","family":"Iwayama","sequence":"additional","affiliation":[{"name":"UVSOR Synchrotron Facility","place":["Okazaki, Japan"]},{"name":"Institute for Molecular Science","place":["Okazaki, Japan"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pablo","family":"Sanz","sequence":"additional","affiliation":[{"name":"Centro de Computaci\u00f3n Cient\u00edfica","place":["Madrid, Spain"]},{"name":"Universidad Aut\u00f3noma de Madrid","place":["Madrid, Spain"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2751-5592","authenticated-orcid":true,"given":"Fernando","family":"Aguilar-Galindo","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica, Universidad Aut\u00f3noma de Madrid","place":["Madrid, Spain"]},{"name":"Institute for Advanced Research in Chemistry, Universidad Aut\u00f3noma de Madrid","place":["Madrid, Spain"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6253-6343","authenticated-orcid":true,"given":"Sergio","family":"D\u00edaz-Tendero","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica, Universidad Aut\u00f3noma de Madrid","place":["Madrid, Spain"]},{"name":"Institute for Advanced Research in Chemistry, Universidad Aut\u00f3noma de Madrid","place":["Madrid, Spain"]},{"name":"Condensed Matter Physics Center, Universidad Aut\u00f3noma de Madrid","place":["Madrid, Spain"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2804-1915","authenticated-orcid":true,"given":"Takuya","family":"Majima","sequence":"additional","affiliation":[{"name":"Quantum Science and Engineering Center","place":["Uji, Japan"]},{"name":"Kyoto University","place":["Uji, Japan"]},{"name":"Department of Nuclear Engineering","place":["Kyoto, Japan"]},{"name":"Kyoto University","place":["Kyoto, Japan"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,5,19]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"crossref","DOI":"10.1093\/oso\/9780195074949.001.0001","volume-title":"Unimolecular Reaction Dynamics: Theory and Experiments","author":"Baer T.","year":"1996"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1016\/S1387-3806(00)00158-5"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1021\/jz4020234"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1039\/C5CP01628B"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-10571-9"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-07577-0"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1039\/D1CP04011A"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-49671-6"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-024-84531-9"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(93)87087-J"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1063\/1.465851"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1063\/1.2202317"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1063\/1.4720350"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.93.053405"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1088\/1367-2630\/aa81ab"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.98.062708"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.100.062707"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.102.062808"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.103.012810"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1063\/5.0293095"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1140\/epjs\/s11734-026-02253-7"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1139\/v63-455"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/ja00973a045"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1021\/ja01020a062"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1063\/1.1668196"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210090210"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1016\/0020-7381(80)85037-6"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1016\/0020-7381(83)87147-2"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210180607"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210181205"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1021\/j100273a019"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1063\/1.453693"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/ja00004a011"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1021\/j100193a012"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1039\/a906881c"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1002\/rcm.4438"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1063\/5.0098531"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1063\/1.2751502"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1063\/1.2827476"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.77.062513"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1063\/5.0215222"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1063\/1.1850895"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1140\/epjd\/e2014-50073-y"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.97.063407"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.103.012802"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1039\/D1CP05811H"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1039\/D3CP00608E"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1039\/D3CP05430F"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1063\/5.0278748"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.5c02619"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1063\/5.0307341"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1039\/c39750000978"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1016\/0020-7381(82)80055-7"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1063\/1.467843"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1063\/1.468640"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijms.2003.11.001"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1155\/2021\/6616439"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.80.032516"},{"key":"ref59\/cit59","unstructured":"Scientific Instrument\nServices.\n                      SIMION 8.0.8.1\n                      ; Scientific Instrument Services Inc., 2012."},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.1c00288"},{"key":"ref61\/cit61","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abg9080"},{"key":"ref62\/cit62","doi-asserted-by":"publisher","DOI":"10.1063\/5.0244970"},{"key":"ref63\/cit63","doi-asserted-by":"publisher","DOI":"10.1063\/1.1700424"},{"key":"ref64\/cit64","volume-title":"Theory of Unimolecular and Recombination Reactions","author":"Gilbert R. G.","year":"1990"},{"key":"ref65\/cit65","doi-asserted-by":"publisher","DOI":"10.1088\/1742-6596\/2380\/1\/012003"},{"key":"ref66\/cit66","doi-asserted-by":"publisher","DOI":"10.1107\/S0909049598000430"},{"key":"ref67\/cit67","unstructured":"Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Petersson, G. A.; Nakatsuji, H.; Li, X.; Caricato, M.; Marenich, A. V.; Bloino, J.; Janesko, B. G.; Gomperts, R.; Mennucci, B.; Hratchian, H. P.; Ortiz, J. V.; Izmaylov, A. F.; Sonnenberg, J. L.; Williams-Young, D.; Ding, F.; Lipparini, F.; Egidi, F.; Goings, J.; Peng, B.; Petrone, A.; Henderson, T.; Ranasinghe, D.; Zakrzewski, V. G.; Gao, J.; Rega, N.; Zheng, G.; Liang, W.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Throssell, K.; Montgomery, J. A., Jr.; Peralta, J. E.; Ogliaro, F.; Bearpark, M. J.; Heyd, J. J.; Brothers, E. N.; Kudin, K. N.; Staroverov, V. N.; Keith, T. A.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A. P.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Millam, J. M.; Klene, M.; Adamo, C.; Cammi, R.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Farkas, O.; Foresman, J. B.; Fox, D. J.\n                      Gaussian16\n                      , Revision C.01; Gaussian, Inc.: Wallingford, CT, 2016."},{"key":"ref68\/cit68","doi-asserted-by":"publisher","DOI":"10.1063\/1.1416876"},{"key":"ref69\/cit69","doi-asserted-by":"publisher","DOI":"10.1063\/1.1372182"},{"key":"ref70\/cit70","doi-asserted-by":"publisher","DOI":"10.1063\/1.1514582"},{"key":"ref71\/cit71","doi-asserted-by":"publisher","DOI":"10.1139\/p80-159"},{"key":"ref72\/cit72","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"ref73\/cit73","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"ref74\/cit74","doi-asserted-by":"publisher","DOI":"10.1021\/j100096a001"},{"key":"ref75\/cit75","doi-asserted-by":"publisher","DOI":"10.1063\/1.1677527"},{"key":"ref76\/cit76","doi-asserted-by":"publisher","DOI":"10.1007\/BF00533485"},{"key":"ref77\/cit77","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRev.46.618"},{"key":"ref78\/cit78","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(88)85250-3"},{"key":"ref79\/cit79","doi-asserted-by":"publisher","DOI":"10.1063\/1.456153"},{"key":"ref80\/cit80","doi-asserted-by":"publisher","DOI":"10.1002\/qua.560140504"},{"key":"ref81\/cit81","doi-asserted-by":"publisher","DOI":"10.1063\/1.443164"},{"key":"ref82\/cit82","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17653-z"},{"key":"ref83\/cit83","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.0c01344"},{"key":"ref84\/cit84","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.1c01788"},{"key":"ref85\/cit85","doi-asserted-by":"publisher","DOI":"10.1038\/s42004-022-00629-z"},{"key":"ref86\/cit86","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218770"}],"container-title":["The Journal of Physical Chemistry Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpclett.6c00416","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpclett.6c00416","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,18]],"date-time":"2026-06-18T08:14:11Z","timestamp":1781770451000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.jpclett.6c00416"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,5,19]]},"references-count":86,"journal-issue":{"issue":"24","published-print":{"date-parts":[[2026,6,18]]}},"alternative-id":["10.1021\/acs.jpclett.6c00416"],"URL":"https:\/\/doi.org\/10.1021\/acs.jpclett.6c00416","relation":{},"ISSN":["1948-7185","1948-7185"],"issn-type":[{"value":"1948-7185","type":"print"},{"value":"1948-7185","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,5,19]]}}}