{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,28]],"date-time":"2026-05-28T09:04:18Z","timestamp":1779959058335,"version":"3.53.1"},"reference-count":60,"publisher":"American Chemical Society (ACS)","issue":"21","license":[{"start":{"date-parts":[[2026,5,16]],"date-time":"2026-05-16T00:00:00Z","timestamp":1778889600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,5,16]],"date-time":"2026-05-16T00:00:00Z","timestamp":1778889600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,5,16]],"date-time":"2026-05-16T00:00:00Z","timestamp":1778889600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22373033"],"award-info":[{"award-number":["22373033"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Phys. Chem. Lett."],"published-print":{"date-parts":[[2026,5,28]]},"DOI":"10.1021\/acs.jpclett.6c01072","type":"journal-article","created":{"date-parts":[[2026,5,16]],"date-time":"2026-05-16T14:04:02Z","timestamp":1778940242000},"page":"6111-6119","source":"Crossref","is-referenced-by-count":0,"title":["Tuning Out-of-Plane Charge Transport via Spacer-Cation Positional Isomerism in 2D Layered Perovskites"],"prefix":"10.1021","volume":"17","author":[{"given":"Jiayi","family":"Ma","sequence":"first","affiliation":[{"name":"School of Chemistry and Materials Science","place":["Changsha, P. R. China"]},{"name":"Hunan Agricultural University","place":["Changsha, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanhong","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science","place":["Changsha, P. R. China"]},{"name":"Hunan Agricultural University","place":["Changsha, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangrui","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science","place":["Changsha, P. R. China"]},{"name":"Hunan Agricultural University","place":["Changsha, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6085-9333","authenticated-orcid":true,"given":"Pingzhi","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science","place":["Changsha, P. R. China"]},{"name":"Hunan Agricultural University","place":["Changsha, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1387-7077","authenticated-orcid":true,"given":"Wei","family":"Wei","sequence":"additional","affiliation":[{"name":"Institute of Theoretical Chemistry, College of Chemistry","place":["Changchun, P. R. China"]},{"name":"Jilin University","place":["Changchun, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9999-5081","authenticated-orcid":true,"given":"Wei","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science","place":["Changsha, P. R. China"]},{"name":"Hunan Agricultural University","place":["Changsha, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,5,16]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adt9952"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.5c01073"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-020-00811-1"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.1c00295"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.0c00359"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-021-01010-2"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-19331-6"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE01695D"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-51345-2"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-024-08158-6"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-58164-z"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b03659"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b06398"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-019-0354-2"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1016\/j.nantod.2022.101394"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.1c02603"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA01447A"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c01006"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-19330-7"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c05621"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1126\/science.abj2637"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c05974"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA01518J"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1039\/D2TC03985K"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.9b01564"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.1c01505"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201901673"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.1c00620"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.9b01068"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-20555-9"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00972"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c21715"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c17876"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1002\/solr.202000107"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c01754"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1039\/D4CP04357J"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.2c00146"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202303255"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c03726"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202402243"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1039\/D5TC03431K"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-08980-x"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jctc.3c00904"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jctc.5c01479"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.67.155108"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.69.195113"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.22885"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1039\/D1CP02805G"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889811038970"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1016\/0263-7855(96)00018-5"},{"key":"ref52\/cit52","unstructured":"Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, J. A., Jr.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, J. M.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, \u00d6.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J.\n                      Gaussian 09\n                      , rev. E.01; Gaussian, Inc.: Wallingford, CT, 2009."},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202001647"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1021\/ja100936w"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1039\/D2QI01482C"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1039\/D4QI00833B"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.6c00437"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c14416"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1039\/C9CP06568G"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.2c00454"}],"container-title":["The Journal of Physical Chemistry Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpclett.6c01072","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpclett.6c01072","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,5,28]],"date-time":"2026-05-28T08:12:14Z","timestamp":1779955934000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.jpclett.6c01072"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,5,16]]},"references-count":60,"journal-issue":{"issue":"21","published-print":{"date-parts":[[2026,5,28]]}},"alternative-id":["10.1021\/acs.jpclett.6c01072"],"URL":"https:\/\/doi.org\/10.1021\/acs.jpclett.6c01072","relation":{},"ISSN":["1948-7185","1948-7185"],"issn-type":[{"value":"1948-7185","type":"print"},{"value":"1948-7185","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,5,16]]}}}