{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T15:38:58Z","timestamp":1786117138456,"version":"build-2736575974"},"reference-count":70,"publisher":"American Chemical Society (ACS)","issue":"31","license":[{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CNS-2320735"],"award-info":[{"award-number":["CNS-2320735"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["506711657"],"award-info":[{"award-number":["506711657"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["DFG 960\/27-1"],"award-info":[{"award-number":["DFG 960\/27-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["EXC 2033 - 390677874\/2 - RESOLV"],"award-info":[{"award-number":["EXC 2033 - 390677874\/2 - RESOLV"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["GRK2376 \/ 331085229"],"award-info":[{"award-number":["GRK2376 \/ 331085229"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Pure methanol desorbs from pristine Ag(111) surfaces under ultrahigh vacuum conditions at 160 K, limiting its availability in catalysis on this surface. To combat this, we devise how to adsorb methanol at room temperature without additives. The methanol adsorption near ambient pressures yields monosized trimers. We use low-temperature scanning tunneling microscopy and single-molecule manipulation to investigate the binding pattern of these clusters and compare them to hexamers formed at low pressure below the methanol desorption temperature. Supported by density functional theory, we unravel that the low-temperature, low-pressure clusters are hydrogen bonded cyclic hexamers, while the room temperature, high-pressure clusters are stabilized by stronger hydrogen bonds of three methanol molecules to a central chemisorbed oxygen atom. Our study shows that trace amounts of oxygen adatoms formed from methanol at high pressure on the Ag(111) surface may aid heterogeneous methanol chemistry under ambient conditions by increasing the residence time on a catalyst surface.<\/jats:p>","DOI":"10.1021\/acs.jpclett.6c01559","type":"journal-article","created":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T13:05:01Z","timestamp":1784811901000},"page":"8993-9000","source":"Crossref","is-referenced-by-count":0,"title":["Stabilization\nof Methanol at Near-Ambient Conditions\non a Noble Metal Surface"],"prefix":"10.1021","volume":"17","author":[{"given":"Ivan","family":"Soldo","sequence":"first","affiliation":[{"name":"Ruhr-University of Bochum , Universita\u0308tsstr. 150 , ,","place":["Bochum, Germany, D-44801"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4407-5931","authenticated-orcid":true,"given":"Paul","family":"Schweer","sequence":"additional","affiliation":[{"name":"Ruhr-University of Bochum , Universita\u0308tsstr. 150 , ,","place":["Bochum, Germany, D-44801"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ameer","family":"Carvan","sequence":"additional","affiliation":[{"name":"Hofstra University , , , ,","place":["Hempstead, New York, United States, 11549"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1507-2667","authenticated-orcid":true,"given":"Daniel P.","family":"Miller","sequence":"additional","affiliation":[{"name":"Hofstra University , , , ,","place":["Hempstead, New York, United States, 11549"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6660-5286","authenticated-orcid":true,"given":"Karina","family":"Morgenstern","sequence":"additional","affiliation":[{"name":"Ruhr-University of Bochum , Universita\u0308tsstr. 150 , ,","place":["Bochum, Germany, D-44801"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,23]]},"reference":[{"key":"2026080609083235500_cit1","doi-asserted-by":"publisher","first-page":"2636","DOI":"10.1002\/anie.200462121","article-title":"Beyond\nOil and Gas: the Methanol Economy","volume":"44","author":"Olah","year":"2005","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026080609083235500_cit2","doi-asserted-by":"publisher","first-page":"439","DOI":"10.1016\/j.renene.2022.05.089","article-title":"Direct Power Generation\nfrom Methanol by Solid Oxide Fuel Cells with a Cu-Ceria based Catalyst\nLayer","volume":"194","author":"Zhang","year":"2022","journal-title":"Renew. Energy"},{"key":"2026080609083235500_cit3","doi-asserted-by":"publisher","first-page":"137","DOI":"10.1021\/acsnano.2c05512","article-title":"Graphene as\nThinnest Coating on Copper Electrodes in Microbial Methanol Fuel Cells","volume":"17","author":"Islam","year":"2023","journal-title":"ACS Nano"},{"key":"2026080609083235500_cit4","doi-asserted-by":"publisher","first-page":"905","DOI":"10.1021\/jacs.2c09437","article-title":"The Nature\nof Interfacial Catalysis over Pt\/NiAl2O4 for\nHydrogen Production from Methanol Reforming Reaction","volume":"145","author":"Wang","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"2026080609083235500_cit5","doi-asserted-by":"publisher","first-page":"7709","DOI":"10.1021\/acscatal.1c05933","article-title":"Methanol Decomposition\non Copper Surfaces under Ambient Conditions: Mechanism, Surface Kinetics,\nand Structure Sensitivity","volume":"12","author":"Ben David","year":"2022","journal-title":"ACS Catal."},{"key":"2026080609083235500_cit6","doi-asserted-by":"publisher","first-page":"12908","DOI":"10.1021\/jp025772r","article-title":"Direct\nObservation\nof Two-Dimensional Electron Solvation at Alcohol\/Ag(111) Interfaces","volume":"106","author":"Liu","year":"2002","journal-title":"J. Phys. Chem. B"},{"key":"2026080609083235500_cit7","doi-asserted-by":"publisher","first-page":"351","DOI":"10.1016\/0378-5963(83)90079-X","article-title":"The Adsorption of Methanol on Ag(111) and its Reaction with Preadsorbed\nOxygen","volume":"16","author":"Felter","year":"1983","journal-title":"Appl. Surf. Sci."},{"key":"2026080609083235500_cit8","doi-asserted-by":"publisher","first-page":"2818","DOI":"10.1063\/1.447955","article-title":"The Interaction\nof Methanol with\nRu(0001)","volume":"81","author":"Hrbek","year":"1984","journal-title":"J. Chem. Phys."},{"key":"2026080609083235500_cit9","doi-asserted-by":"publisher","first-page":"7193","DOI":"10.1021\/ja017818k","article-title":"A First-Principles\nStudy of Methanol Decomposition\non Pt(111)","volume":"124","author":"Greeley","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"2026080609083235500_cit10","doi-asserted-by":"publisher","first-page":"17791","DOI":"10.1021\/jp053855c","article-title":"In Situ Studies\nof Methanol Decomposition and Oxidation on Pd(111) by PM-IRAS and\nXPS Spectroscopy","volume":"109","author":"Borasio","year":"2005","journal-title":"J. Phys. Chem. B"},{"key":"2026080609083235500_cit11","doi-asserted-by":"publisher","first-page":"1636","DOI":"10.1021\/jp0775653","article-title":"Methanol Adsorption\non Clean and Oxygen-Predosed V(100) Single-Crystal\nSurfaces","volume":"112","author":"Shen","year":"2008","journal-title":"J. Phys. Chem. C"},{"key":"2026080609083235500_cit12","doi-asserted-by":"publisher","first-page":"20388","DOI":"10.1021\/ja307465u","article-title":"Energetics of Adsorbed\nMethanol and Methoxy on Pt(111) by Microcalorimetry","volume":"134","author":"Karp","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"2026080609083235500_cit13","doi-asserted-by":"publisher","first-page":"420","DOI":"10.1016\/j.susc.2011.11.001","article-title":"In Situ\nXPS and MS Study of Methanol Decomposition and Oxidation on Pd(111)\nunder Millibar Pressure Range","volume":"606","author":"Kaichev","year":"2012","journal-title":"Surf. Sci."},{"key":"2026080609083235500_cit14","doi-asserted-by":"publisher","first-page":"1298","DOI":"10.1016\/j.susc.2012.04.012","article-title":"Does Methanol Produce\na Stable Methoxy Species on Ru(0001) at Low Temperatures?","volume":"606","author":"Duncan","year":"2012","journal-title":"Surf. Sci."},{"key":"2026080609083235500_cit15","doi-asserted-by":"publisher","first-page":"509","DOI":"10.1134\/S0023158414040065","article-title":"Decomposition\nand Oxidation of Methanol\non Platinum: a Study by in Situ X-Ray Photoelectron Spectroscopy and\nMass Spectrometry","volume":"55","author":"Kaichev","year":"2014","journal-title":"Kinet. Catal."},{"key":"2026080609083235500_cit16","doi-asserted-by":"publisher","first-page":"25402","DOI":"10.1021\/acs.jpcc.7b09598","article-title":"Systematic Study of\nAdsorption and the Reaction of\nMethanol on Three Model Catalysts: Cu(111), Zn-Cu(111), and Oxidized\nZn-Cu(111)","volume":"121","author":"Koitaya","year":"2017","journal-title":"J. Phys. Chem. C"},{"key":"2026080609083235500_cit17","doi-asserted-by":"publisher","first-page":"4559","DOI":"10.1021\/acs.jpcc.4c00049","article-title":"Effect of the Chemical\nStates of Copper on Methanol Decomposition\nand Oxidation","volume":"128","author":"Wang","year":"2024","journal-title":"J. Phys. Chem. C"},{"key":"2026080609083235500_cit18","doi-asserted-by":"publisher","first-page":"6209","DOI":"10.1021\/acs.jpclett.4c01134","article-title":"The Surface Chemistry of Methanol\non Pd(111) and H-Pd(111) Surfaces: C-O Bond Cleavage and the Effects\nof Metal Hydride Formation","volume":"15","author":"Kim","year":"2024","journal-title":"J. Phys. Chem. Lett."},{"key":"2026080609083235500_cit19","doi-asserted-by":"publisher","first-page":"2467","DOI":"10.1021\/acs.jpcc.4c07648","article-title":"The Surface Chemistry of Methanol on Cu3Pd(111): Effects of Metal Alloying and Reaction with Hydrogen","volume":"129","author":"Prabhakar Reddy","year":"2025","journal-title":"J. Phys. Chem. C"},{"key":"2026080609083235500_cit20","doi-asserted-by":"publisher","first-page":"91","DOI":"10.1016\/0039-6028(86)90165-2","article-title":"Conversion of Methanol, Formaldehyde\nand Formic Acid\non the Polar Faces of Zinc Oxide","volume":"176","author":"Vohs","year":"1986","journal-title":"Surf. Sci."},{"key":"2026080609083235500_cit21","doi-asserted-by":"publisher","first-page":"5501","DOI":"10.1021\/jp0763735","article-title":"Surface\nChemistry of Methanol on Clean and Atomic Oxygen Pre-Covered Au(111)","volume":"112","author":"Gong","year":"2008","journal-title":"J. Phys. Chem. C"},{"key":"2026080609083235500_cit22","doi-asserted-by":"publisher","first-page":"14356","DOI":"10.1021\/jp9022597","article-title":"STM Study\nof Surface Species Formed by Methanol Adsorption on Stoichiometric\nand Reduced ZnO(1010) Surface","volume":"113","author":"Shao","year":"2009","journal-title":"J. Phys. Chem.\nC"},{"key":"2026080609083235500_cit23","doi-asserted-by":"publisher","first-page":"669","DOI":"10.1007\/s11244-011-9685-y","article-title":"Methanol Adsorption on V2O3(0001)","volume":"54","author":"Romanyshyn","year":"2011","journal-title":"Top. Catal."},{"key":"2026080609083235500_cit24","doi-asserted-by":"publisher","first-page":"7180","DOI":"10.1021\/jp200146v","article-title":"Combined Theoretical\nand Experimental Study on the Adsorption of Methanol on the ZnO(10\n1\u03050) Surface","volume":"115","author":"Kiss","year":"2011","journal-title":"J. Phys. Chem. A"},{"key":"2026080609083235500_cit25","doi-asserted-by":"publisher","first-page":"28617","DOI":"10.1021\/acs.jpcc.6b09908","article-title":"Methanol\nAdsorption and Oxidation\non Reduced and Oxidized TbOx(111) Surfaces","volume":"120","author":"Scha\u0308fer","year":"2016","journal-title":"J. Phys. Chem. C"},{"key":"2026080609083235500_cit26","doi-asserted-by":"publisher","first-page":"420","DOI":"10.1007\/s11244-016-0713-9","article-title":"The Role\nof Surface Defects in the\nAdsorption of Methanol on Fe3O4(001)","volume":"60","author":"Gamba","year":"2017","journal-title":"Top. Catal."},{"key":"2026080609083235500_cit27","doi-asserted-by":"publisher","first-page":"499","DOI":"10.1007\/s11244-017-0867-0","article-title":"Methanol Oxidation\nto Formaldehyde\nPromoted at the Step Sites of Ultrathin ZnO","volume":"61","author":"Deng","year":"2018","journal-title":"Top. Catal."},{"key":"2026080609083235500_cit28","doi-asserted-by":"publisher","first-page":"064703","DOI":"10.1063\/1.5139418","article-title":"Adsorption and Reaction\nof Methanol on Fe3O4(001)","volume":"152","author":"Marcinkowski","year":"2020","journal-title":"J. Chem. Phys."},{"key":"2026080609083235500_cit29","doi-asserted-by":"publisher","first-page":"35","DOI":"10.1016\/0039-6028(85)90350-4","article-title":"Reaction of\nMethanol on Si(111)-7\n\u00d7 7","volume":"154","author":"Stroscio","year":"1985","journal-title":"Surf. Sci."},{"key":"2026080609083235500_cit30","doi-asserted-by":"publisher","first-page":"8424","DOI":"10.1021\/jp021942o","article-title":"Adsorption\nand Thermal Decomposition\nChemistry of 1-Propanol and Other Primary Alcohols on the Si(100)\nSurface","volume":"107","author":"Zhang","year":"2003","journal-title":"J. Phys. Chem. B"},{"key":"2026080609083235500_cit31","doi-asserted-by":"publisher","first-page":"1289","DOI":"10.1088\/0953-8984\/17\/8\/007","article-title":"Methanol Adsorption\non the Si(100)-2 \u00d7 1 Surface:\nA first-Principles Calculation","volume":"17","author":"Carbone","year":"2005","journal-title":"J. Phys.: Condens.\nMatter"},{"key":"2026080609083235500_cit32","doi-asserted-by":"publisher","first-page":"1491","DOI":"10.1039\/C5RA22759C","article-title":"A Novel\nTheoretical Study of Thermally-Induced Reaction\nand Vibration Dynamics of Methanol Dissociative Adsorption onto a\nSi(001) Surface","volume":"6","author":"Lee","year":"2016","journal-title":"RSC Adv."},{"key":"2026080609083235500_cit33","doi-asserted-by":"publisher","first-page":"10911","DOI":"10.1021\/acs.jpcc.5c02278","article-title":"Adsorption of Methanol on Si(001)\nRevisited: Alternative\nReaction Pathways at Increased Surface Temperature","volume":"129","author":"Go\u0308bel","year":"2025","journal-title":"J. Phys. Chem. C"},{"key":"2026080609083235500_cit34","doi-asserted-by":"publisher","first-page":"3541","DOI":"10.1039\/B700365J","article-title":"Adsorption and Reaction of Methanol\non Supported Palladium Catalysts: Microscopic-Level Studies from Ultrahigh\nVacuum or Ambient Pressure Conditions","volume":"9","author":"Ba\u0308umer","year":"2007","journal-title":"Phys.\nChem. Chem. Phys."},{"key":"2026080609083235500_cit35","doi-asserted-by":"publisher","first-page":"13524","DOI":"10.1021\/jp073607b","article-title":"Enhanced Methanol Dissociation on Nanostructured 2D Al Overlayers","volume":"111","author":"Zhang","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"2026080609083235500_cit36","doi-asserted-by":"publisher","first-page":"1087","DOI":"10.1016\/j.susc.2009.02.010","article-title":"Methanol Adsorption on a CeO2\/111)\/Cu(111) Thin Film Model\nCatalyst","volume":"603","author":"Matolin","year":"2009","journal-title":"Surf. Sci."},{"key":"2026080609083235500_cit37","doi-asserted-by":"publisher","first-page":"1233","DOI":"10.1016\/j.susc.2012.04.002","article-title":"Enhanced Activity for Supported Au\nClusters: Methanol\nOxidation on Au\/TiO2(110)","volume":"606","author":"Tenney","year":"2012","journal-title":"Surf.\nSci."},{"key":"2026080609083235500_cit38","doi-asserted-by":"publisher","first-page":"26998","DOI":"10.1021\/jp409618j","article-title":"Methanol Reaction on Pt-Au Clusters\non TiO2(110): Methoxy-Induced Diffusion of Pt","volume":"117","author":"Tenney","year":"2013","journal-title":"J. Phys. Chem. C"},{"key":"2026080609083235500_cit39","doi-asserted-by":"publisher","first-page":"2947","DOI":"10.1021\/acs.langmuir.5b04455","article-title":"Low-Temperature Adsorption and Diffusion of Methanol in ZIF-8 Nanoparticle\nFilms","volume":"32","author":"Mosier","year":"2016","journal-title":"Langmuir"},{"key":"2026080609083235500_cit40","doi-asserted-by":"publisher","first-page":"74","DOI":"10.1016\/j.cattod.2017.08.041","article-title":"Methanol Steam Reforming over Ni-CeO2 Model\nand Powder Catalysts: Pathways to High Stability and Selectivity for\nH2\/CO2 Production","volume":"311","author":"Liu","year":"2018","journal-title":"Catal.\nToday"},{"key":"2026080609083235500_cit41","doi-asserted-by":"publisher","first-page":"4080","DOI":"10.1021\/acscatal.0c00260","article-title":"Surface Species in Photocatalytic Methanol Reforming on Pt\/TiO2(110): Learning from Surface Science Experiments for Catalytically\nRelevant Conditions","volume":"10","author":"Walenta","year":"2020","journal-title":"ACS Catal."},{"key":"2026080609083235500_cit42","doi-asserted-by":"publisher","first-page":"6673","DOI":"10.1021\/acs.jpcc.1c00392","article-title":"Understanding\nMethanol Synthesis\non Inverse ZnO\/CuOx\/Cu Catalysts: Stability\nof CH3O Species and Dynamic Nature of the Surface","volume":"125","author":"Orozco","year":"2021","journal-title":"J. Phys. Chem. C"},{"key":"2026080609083235500_cit43","doi-asserted-by":"publisher","first-page":"12494","DOI":"10.1021\/jp960045f","article-title":"Polarization Modulation\nInfrared Reflection Absorption Spectroscopy of CO Adsorption on Co(0001)\nunder a High-Pressure Regime","volume":"100","author":"Beitel","year":"1996","journal-title":"J. Phys. Chem."},{"key":"2026080609083235500_cit44","doi-asserted-by":"publisher","first-page":"169","DOI":"10.1016\/j.surfrep.2008.01.001","article-title":"Ambient Pressure\nPhotoelectron Spectroscopy: A New\nTool for Surface Science and Nanotechnology","volume":"63","author":"Salmeron","year":"2008","journal-title":"Surf. Sci. Rep."},{"key":"2026080609083235500_cit45","doi-asserted-by":"publisher","first-page":"3537","DOI":"10.1063\/1.1389497","article-title":"A High-Pressure Scanning Tunneling\nMicroscope","volume":"72","author":"Laegsgaard","year":"2001","journal-title":"Rev. Sci. Instrum."},{"key":"2026080609083235500_cit46","doi-asserted-by":"publisher","first-page":"448","DOI":"10.1007\/s11244-015-0519-1","article-title":"Recent Approaches\nfor Bridging the Pressure Gap in Photoelectron Microspectroscopy","volume":"59","author":"Kolmakov","year":"2016","journal-title":"Top. Catal."},{"key":"2026080609083235500_cit47","doi-asserted-by":"publisher","first-page":"531","DOI":"10.1016\/0039-6028(78)90113-9","article-title":"The Oxidation of Methanol on a Silver\n(100) Catalyst","volume":"76","author":"Wachs","year":"1978","journal-title":"Surf. Sci."},{"key":"2026080609083235500_cit48","doi-asserted-by":"publisher","first-page":"10414","DOI":"10.1021\/jp972136y","article-title":"Electron-Induced\nChemistry of Methanol on Ag(111)","volume":"101","author":"Schwaner","year":"1997","journal-title":"J. Phys. Chem.\nB"},{"key":"2026080609083235500_cit49","doi-asserted-by":"publisher","first-page":"256101","DOI":"10.1103\/PhysRevLett.107.256101","article-title":"Vizualization\nof Hydrogen Boding and Associated Chirality\nin Methanol Hexamers","volume":"107","author":"Lawton","year":"2011","journal-title":"Phys. Rev. Lett."},{"key":"2026080609083235500_cit50","doi-asserted-by":"publisher","first-page":"9157","DOI":"10.1021\/jp201465d","article-title":"Hydrogen-Bonded\nNetworks in Surface-Bound\nMethanol","volume":"115","author":"Baber","year":"2011","journal-title":"J. Phys. Chem. C"},{"key":"2026080609083235500_cit51","doi-asserted-by":"publisher","first-page":"11846","DOI":"10.1039\/c2cp41875d","article-title":"Hydrogen-Bonded Assembly of Methanol\non Cu(111)","volume":"14","author":"Lawton","year":"2012","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026080609083235500_cit52","doi-asserted-by":"publisher","first-page":"014701","DOI":"10.1063\/1.4882863","article-title":"Structure and\nEnergetics of Hydrogen-Bonded Networks of Methanol on Close Packed\nTransition Metal Surfaces","volume":"141","author":"Murphy","year":"2014","journal-title":"J. Chem. Phys."},{"key":"2026080609083235500_cit53","doi-asserted-by":"publisher","first-page":"5164","DOI":"10.1021\/acs.jpcc.4c07837","article-title":"Effect of Temperature\nand Surface Properties on the Growth of Crystalline\nMultilayers of Methanol on Copper","volume":"129","author":"Akerman","year":"2025","journal-title":"J. Phys.\nChem. C"},{"key":"2026080609083235500_cit54","doi-asserted-by":"publisher","first-page":"516","DOI":"10.1016\/0039-6028(85)91077-5","article-title":"Reaction of Methanol with Cu(111)\nand Cu(111)","volume":"163","author":"Russell","year":"1985","journal-title":"O(Ads). Surf. Sci."},{"key":"2026080609083235500_cit55","doi-asserted-by":"publisher","first-page":"79","DOI":"10.1007\/BF00813523","article-title":"Oxidation\nof Methanol at Copper Surfaces","volume":"37","author":"Carley","year":"1996","journal-title":"Catal. Lett."},{"key":"2026080609083235500_cit56","doi-asserted-by":"publisher","first-page":"3823","DOI":"10.1021\/jp003611m","article-title":"The Formation of Methoxy\nfrom Methanol on an Oxygen\nCovered Cu(100) Surface at Temperatures of 90 - 200 K","volume":"105","author":"Mudalige","year":"2001","journal-title":"J. Phys. Chem. B"},{"key":"2026080609083235500_cit57","doi-asserted-by":"publisher","first-page":"19","DOI":"10.1016\/S0039-6028(02)02675-4","article-title":"An Infrared Vibrational Spectroscopic Study of the\nInteraction of Methanol with Oxygen-Covered Cu(111)","volume":"526","author":"Efstathiou","year":"2003","journal-title":"Surf. Sci."},{"key":"2026080609083235500_cit58","doi-asserted-by":"publisher","first-page":"14034","DOI":"10.1021\/jp802488n","article-title":"DFT and RAIRS Investigations of Methanol\nof Cu(110)\nand on Oxygen Modified Cu(110)","volume":"112","author":"Singnurkar","year":"2008","journal-title":"J. Phys. Chem.\nC"},{"key":"2026080609083235500_cit59","doi-asserted-by":"publisher","first-page":"2684","DOI":"10.1002\/cctc.201200810","article-title":"An Atomic Scale\nView of Methanol Reactivity at the Cu(111)\/CuOx Interfaces","volume":"5","author":"Lawton","year":"2013","journal-title":"ChemCatChem."},{"key":"2026080609083235500_cit60","doi-asserted-by":"publisher","first-page":"3621","DOI":"10.1002\/cctc.201601053","article-title":"Methanol Partial Oxidation on Ag(111)\nfrom First Principles","volume":"8","author":"Aljama","year":"2016","journal-title":"ChemCatChem."},{"key":"2026080609083235500_cit61","doi-asserted-by":"publisher","first-page":"7816","DOI":"10.1039\/D5CP00009B","article-title":"Modeling the Subsurface\nAdsorption of Atomic Oxygen in Silver form High Vacuum to High Pressure","volume":"27","author":"Mize","year":"2025","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026080609083235500_cit62","doi-asserted-by":"publisher","first-page":"7551","DOI":"10.1021\/acs.jpcc.7b11629","article-title":"Atomic and\nMolecular Adsorption on Ag(111)","volume":"123","author":"Chen","year":"2019","journal-title":"J. Phys. Chem.\nC"},{"key":"2026080609083235500_cit63","doi-asserted-by":"publisher","first-page":"104205","DOI":"10.1103\/PhysRevB.71.104205","article-title":"Chemical and Electronic Structures\nof Liquid Methanol from X-Ray Emission Spectroscopy and Density Functional\nTheory","volume":"71","author":"Kashtanov","year":"2005","journal-title":"Phys. Rev. B"},{"key":"2026080609083235500_cit64","doi-asserted-by":"publisher","first-page":"066102","DOI":"10.1103\/PhysRevLett.88.066102","article-title":"Intermolecular Bond Length of Ice\non Ag(111)","volume":"88","author":"Morgenstern","year":"2002","journal-title":"Phys. Rev. Lett."},{"key":"2026080609083235500_cit65","doi-asserted-by":"publisher","first-page":"165421","DOI":"10.1103\/PhysRevB.66.165421","article-title":"Contrast Changes\nin STM Images and Relations Between Different Tunneling Models","volume":"66","author":"Nieminen","year":"2002","journal-title":"Phys. Rev. B"},{"key":"2026080609083235500_cit66","doi-asserted-by":"publisher","first-page":"250","DOI":"10.1016\/S0009-2614(02)00593-6","article-title":"Dissociation of Water Molecules with the Scanning Tunnelling\nMicroscope","volume":"358","author":"Morgenstern","year":"2002","journal-title":"Chem. Phys. Lett."},{"key":"2026080609083235500_cit67","doi-asserted-by":"publisher","first-page":"597","DOI":"10.1038\/nmat1940","article-title":"Ice Nanoclusters\nat Hydrophobic Metal Surfaces","volume":"6","author":"Michaelides","year":"2007","journal-title":"Nat. Mater."},{"key":"2026080609083235500_cit68","unstructured":"Pu\u0308tz, F.\n          \n          Pra\u0308paration\norganischer Schichten aus der Flu\u0308ssigphase, Diploma thesis; Technical University of Kaiserslautern, 2022."},{"key":"2026080609083235500_cit69","doi-asserted-by":"publisher","first-page":"4206","DOI":"10.1063\/1.1346687","article-title":"Far-Ranged\nTransient Motion of \u201dHot\u201d Oxygen Atoms upon Dissociation","volume":"114","author":"Schintke","year":"2001","journal-title":"J. Chem. Phys."},{"key":"2026080609083235500_cit70","doi-asserted-by":"publisher","first-page":"617","DOI":"10.1002\/ange.200502229","article-title":"Reversible\ncis-trans Isomerization of a Single Azobenzene Molecule","volume":"118","author":"Henzl","year":"2006","journal-title":"Angew. Chem."}],"container-title":["The Journal of Physical\nChemistry Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpclett.6c01559","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jpclcd\/article-pdf\/17\/31\/8993\/66233535\/acs.jpclett.6c01559.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jpclcd\/article-pdf\/17\/31\/8993\/66233535\/acs.jpclett.6c01559.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,6]],"date-time":"2026-08-06T13:11:58Z","timestamp":1786021918000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jpclcd\/article\/17\/31\/8993\/5231006\/Stabilization-of-Methanol-at-Near-Ambient"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,23]]},"references-count":70,"journal-issue":{"issue":"31","published-online":{"date-parts":[[2026,7,23]]},"published-print":{"date-parts":[[2026,8,6]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.jpclett.6c01559","relation":{},"ISSN":["1948-7185"],"issn-type":[{"value":"1948-7185","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,23]]}}}