{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T20:18:09Z","timestamp":1788466689702,"version":"build-2803163510"},"reference-count":28,"publisher":"American Chemical Society (ACS)","issue":"35","license":[{"start":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T00:00:00Z","timestamp":1787356800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T00:00:00Z","timestamp":1787356800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T00:00:00Z","timestamp":1787356800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/na","name":"Chemical Measurement and Imaging Program in the NSF Division of Chemistry","doi-asserted-by":"publisher","award":["CHE-2403964"],"award-info":[{"award-number":["CHE-2403964"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Gas bubble accumulation at electrode surfaces remains a major challenge in gas-evolving electrocatalytic reactions because it blocks active sites, hinders mass transport, and can ultimately shut down electrochemical turnover. Here, we show that introducing immiscible 1,2-dichloroethane (DCE) microdroplets at the electrode interface redirects electrogenerated N2 from hydrazine oxidation, preventing direct accumulation at the electrode|electrolyte boundary, without requiring complex surface redesign. This liquid microenvironment suppresses early bubble nucleation, interrupts lateral coalescence, delays transport-limited failure, and preserves long-term interfacial accessibility. The resulting stabilization arises from dynamic gas uptake, redistribution, and release through the organic phase. As a result, the modified interface remains electrochemically active during prolonged operation, whereas the unmodified system undergoes severe deactivation because of macroscopic bubble insulation. These findings establish immiscible microdroplet-based microenvironment engineering as an effective strategy for stabilizing gas-evolving electrocatalytic reactions.<\/jats:p>","DOI":"10.1021\/acs.jpclett.6c01795","type":"journal-article","created":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T22:19:32Z","timestamp":1787609972000},"page":"10219-10225","source":"Crossref","is-referenced-by-count":0,"title":["Taming N2 Bubbles with Immiscible Droplets\nfor Stable Hydrazine Electrooxidation"],"prefix":"10.1021","volume":"17","author":[{"given":"Taizhe","family":"Liu","sequence":"first","affiliation":[{"name":"Purdue University , , , ,","place":["West Lafayette, Indiana, United States, 47907"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-0262-2704","authenticated-orcid":true,"given":"Ashutosh","family":"Rana","sequence":"additional","affiliation":[{"name":"Purdue University , , , ,","place":["West Lafayette, Indiana, United States, 47907"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"James H.","family":"Nguyen","sequence":"additional","affiliation":[{"name":"Purdue University , , , ,","place":["West Lafayette, Indiana, United States, 47907"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4538-9705","authenticated-orcid":true,"given":"Jeffrey E.","family":"Dick","sequence":"additional","affiliation":[{"name":"Purdue University , , , ,","place":["West Lafayette, Indiana, United States, 47907"]},{"name":"Purdue University , , , ,","place":["West Lafayette, Indiana, United States, 47907"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,22]]},"reference":[{"issue":"8","key":"2026090315413993500_cit1","doi-asserted-by":"publisher","first-page":"100138","DOI":"10.1016\/j.xcrp.2020.100138","article-title":"Efficient Renewable-to-Hydrogen Conversion via Decoupled Electrochemical\nWater Splitting","volume":"1","author":"Huang","year":"2020","journal-title":"Cell Rep. 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