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The 3D polymorphs show a clear trend: as symmetry increases from orthorhombic to tetragonal to pseudocubic, Eb decreases. At fixed dimensionality, restoring local metal-centered symmetry suppresses Rashba splitting. It reduces or preserves Eb, indicating that SOC affects excitons mainly through band-edge structure rather than direct strengthening of the electron\u2013hole Coulomb kernel. Low-dimensional compounds retain much larger Eb than 3D analogs, although quasi-1D is not monotonic with quasi-2D. Photoluminescence spectra place the lowest excitons at the optical gap, consistent with bright ground-state excitons.<\/jats:p>","DOI":"10.1021\/acs.jpclett.6c01964","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:17:01Z","timestamp":1785849421000},"page":"11039-11046","source":"Crossref","is-referenced-by-count":0,"title":["Correlating Rashba Suppression with Exciton Binding\nin Low-Dimensional Metal Halide Perovskites"],"prefix":"10.1021","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-7507-4794","authenticated-orcid":true,"given":"Marco","family":"Antonio de Andrade Queiroz","sequence":"first","affiliation":[{"name":"Federal University of Parana\u0301, CEP , ,","place":["Curitiba, Brazil, 81531-980"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6343-5560","authenticated-orcid":true,"given":"Danilo Neves","family":"Silveira","sequence":"additional","affiliation":[{"name":"Federal University of Parana\u0301, CEP , ,","place":["Curitiba, Brazil, 81531-980"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fernando P.","family":"Sabino","sequence":"additional","affiliation":[{"name":"University of Sa\u0303o Paulo, CEP , ,","place":["Sa\u0303o Carlos, Brazil, 13566-590"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carlos M. O.","family":"Bastos","sequence":"additional","affiliation":[{"name":"University of Brasi\u0301lia , , , ,","place":["Brasi\u0301lia, DF, Brazil, 70919-970"]},{"name":"University of Brasi\u0301lia , , ,","place":["Brasi\u0301lia, Brazil, 70910-900"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1861-2438","authenticated-orcid":true,"given":"Celso R. 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Opt.\nMater."},{"key":"2026100109081620000_cit44","doi-asserted-by":"publisher","first-page":"3384","DOI":"10.1107\/S0567740872007976","article-title":"The Classification\nof Tilted Octahedra in Perovskites","volume":"28","author":"Glazer","year":"1972","journal-title":"Acta Crystallogr.,\nSect. B: Struct. Crystallogr. Cryst. Chem."},{"key":"2026100109081620000_cit45","doi-asserted-by":"publisher","first-page":"16508","DOI":"10.1021\/acs.jpcc.9b02140","article-title":"Organic Molecule\nOrientations and\nRashba\u2013Dresselhaus Effect in \u03b1\u2013Formamidinium\nLead Iodide","volume":"123","author":"Sukmas","year":"2019","journal-title":"J. Phys. Chem. 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