{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T13:22:57Z","timestamp":1789046577673,"version":"build-2803163510"},"reference-count":57,"publisher":"American Chemical Society (ACS)","issue":"36","license":[{"start":{"date-parts":[[2026,8,28]],"date-time":"2026-08-28T00:00:00Z","timestamp":1787875200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003196","name":"Ministero della Salute","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100003196","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004731","name":"Natural Science Foundation of Zhejiang Province","doi-asserted-by":"publisher","award":["Z25C100007"],"award-info":[{"award-number":["Z25C100007"]}],"id":[{"id":"10.13039\/501100004731","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100017526","name":"International Cooperation Project of Ningbo City","doi-asserted-by":"publisher","award":["2024H006"],"award-info":[{"award-number":["2024H006"]}],"id":[{"id":"10.13039\/501100017526","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021856","name":"Ministero dell'Universit? e della Ricerca","doi-asserted-by":"publisher","award":["CUP J53C25000530001"],"award-info":[{"award-number":["CUP J53C25000530001"]}],"id":[{"id":"10.13039\/501100021856","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"Key Research and Development Program of Ningbo","doi-asserted-by":"publisher","award":["2024Z217"],"award-info":[{"award-number":["2024Z217"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"Italian Fund for Applied Sciences","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Perylene bisimides (PBIs) are prime building blocks for functional supramolecular architectures, yet mapping their salt-induced self-assembly kinetics under physiological conditions remains challenging, due to rapid aggregation and overwhelming fluorescence. Here, we combine fluorescence stopped-flow kinetics and stimulated Raman scattering (SRS) spectroscopy to decipher the electrolyte-controlled polymerization of a spermine-functionalized PBI. We found that self-assembly obeys an anticooperative K2\u2013K pathway, where nucleation yields rapid and salt-independent dimers. In contrast, polymer growth is strongly salt-dependent, with polymer dissociation rates decreasing as NaCl concentration increases. Crucially, chloride ions selectively stabilize the growing assemblies by drastically suppressing the monomer release, establishing a Michaelis\u2013Menten-type saturation profile. To link these kinetic trajectories with molecular-scale structural rearrangements, SRS is used to effectively suppress the fluorescence background, revealing that the relative intensity of low-frequency Raman modes, associated with high-mass displacement and structurally delocalized in nature, are drastically reduced upon aggregation. This vibrational suppression underscores the role of packing constraints and excitonic pressure within the cofacial H-aggregates. By directly bridging macroscale kinetic pathways with microscopic vibrational dynamics, this work offers a generalizable framework to rationally design and tune water-soluble supramolecular materials for biomedical and optoelectronic applications.<\/jats:p>","DOI":"10.1021\/acs.jpclett.6c02220","type":"journal-article","created":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T04:50:14Z","timestamp":1788324614000},"page":"10378-10387","source":"Crossref","is-referenced-by-count":0,"title":["Electrolyte-Controlled\nSelf-Assembly of Water-Soluble\nPerylene Bisimides: A Kinetic and Stimulated Raman Study"],"prefix":"10.1021","volume":"17","author":[{"given":"Miles","family":"Martinati","sequence":"first","affiliation":[{"name":"Sapienza University of Rome , , Piazzale Aldo Moro 5 , ,","place":["Rome, Italy, 00185"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6214-8604","authenticated-orcid":true,"given":"Giovanni","family":"Batignani","sequence":"additional","affiliation":[{"name":"Sapienza University of Rome , , Piazzale Aldo Moro 5 , ,","place":["Rome, Italy, 00185"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gaia","family":"De Maria","sequence":"additional","affiliation":[{"name":"Sapienza University of Rome , , Piazzale Aldo Moro 5 , ,","place":["Rome, Italy, 00185"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Giancarlo","family":"Fabrizi","sequence":"additional","affiliation":[{"name":"Sapienza University of Rome , , Piazzale Aldo Moro 5 , ,","place":["Rome, Italy, 00185"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuri","family":"Gazzilli","sequence":"additional","affiliation":[{"name":"Sapienza University of Rome , , Piazzale Aldo Moro 5 , ,","place":["Rome, Italy, 00185"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Valeria","family":"Pennacchietti","sequence":"additional","affiliation":[{"name":"Sapienza University of Rome , , Piazzale Aldo Moro 5 , ,","place":["Rome, Italy, 00185"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6966-9464","authenticated-orcid":true,"given":"Fang","family":"Yang","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences , , ,","place":["Ningbo, China, 315201"]},{"name":"Ningbo Cixi Institute of Biomedical Engineering , , ,","place":["Cixi, China, 315300"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alberto","family":"Boffi","sequence":"additional","affiliation":[{"name":"Sapienza University of Rome , , Piazzale Aldo Moro 5 , ,","place":["Rome, Italy, 00185"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7437-4262","authenticated-orcid":true,"given":"Tullio","family":"Scopigno","sequence":"additional","affiliation":[{"name":"Sapienza University of Rome , , Piazzale Aldo Moro 5 , ,","place":["Rome, Italy, 00185"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1381-9560","authenticated-orcid":true,"given":"Roberta","family":"Piacentini","sequence":"additional","affiliation":[{"name":"Sapienza University of Rome , , Piazzale Aldo Moro 5 , ,","place":["Rome, Italy, 00185"]},{"name":"D-Tails s.r.l. S.B. , Via Agrigento, 4A\/4B , ,","place":["Rome, Italy, 00161"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,28]]},"reference":[{"issue":"1","key":"2026091008094729000_cit1","doi-asserted-by":"publisher","first-page":"68","DOI":"10.1021\/bm049674i","article-title":"Water-Soluble Rylene Dyes as High-Performance\nColorants\nfor the Staining of Cells","volume":"6","author":"Weil","year":"2005","journal-title":"Biomacromolecules"},{"key":"2026091008094729000_cit2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cbpa.2021.102102","article-title":"Show Your\nTrue Color: Mammalian Cell Surface Staining\nfor Tracking Cellular Identity in Multiplexing and Beyond","volume":"66","author":"Hassdenteufel","year":"2022","journal-title":"Curr. Opin. Chem. Biol."},{"issue":"11","key":"2026091008094729000_cit3","doi-asserted-by":"publisher","first-page":"7612","DOI":"10.1039\/C7CP07778E","article-title":"Fluorescence\nQuantum Yields of Dye Aggregates: A Showcase Example Based on Self-Assembled\nPerylene Bisimide Dimers","volume":"20","author":"Fennel","year":"2018","journal-title":"Phys. Chem. Chem.\nPhys."},{"issue":"7","key":"2026091008094729000_cit4","doi-asserted-by":"publisher","first-page":"6308","DOI":"10.3390\/ijms24076308","article-title":"Recent Advances in Applications of Fluorescent Perylenediimide\nand Perylenemonoimide Dyes in Bioimaging, Photothermal and Photodynamic\nTherapy","volume":"24","author":"Krupka","year":"2023","journal-title":"Int. J. Mol. Sci."},{"issue":"9","key":"2026091008094729000_cit5","doi-asserted-by":"publisher","first-page":"1964","DOI":"10.3390\/molecules29091964","article-title":"Self-Assembly Behavior,\nAggregation Structure, and the Charge Carrier Transport Properties\nof S-Heterocyclic Annulated Perylene Diimide Derivatives","volume":"29","author":"Ben","year":"2024","journal-title":"Molecules"},{"issue":"5","key":"2026091008094729000_cit6","doi-asserted-by":"publisher","first-page":"1245","DOI":"10.1021\/acs.accounts.9b00064","article-title":"Semiconducting Perylene Diimide Nanostructure:\nMultifunctional Phototheranostic\nNanoplatform","volume":"52","author":"Yang","year":"2019","journal-title":"Acc. Chem. Res."},{"issue":"11","key":"2026091008094729000_cit7","doi-asserted-by":"publisher","first-page":"3372","DOI":"10.1002\/chem.200902839","article-title":"Spermine-Functionalized\nPerylene Bisimide Dyes\u2500Highly Fluorescent Bola-Amphiphiles\nin Water","volume":"16","author":"Rehm","year":"2010","journal-title":"Chem.\u2013Eur. J."},{"issue":"26","key":"2026091008094729000_cit8","doi-asserted-by":"publisher","first-page":"6328","DOI":"10.1002\/anie.201108690","article-title":"Molecular Assemblies of Perylene\nBisimide Dyes in Water","volume":"51","author":"Go\u0308rl","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"issue":"41","key":"2026091008094729000_cit9","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202501317","article-title":"Self-Assembly,\nAggregation Mechanisms, and Morphological Properties of Asymmetric\nPerylene Diimide-based Supramolecular Polymers","volume":"31","author":"Alharbi","year":"2025","journal-title":"Chem\u2013Eur. J."},{"issue":"7","key":"2026091008094729000_cit10","doi-asserted-by":"publisher","first-page":"1223","DOI":"10.3390\/nano12071223","article-title":"Supramolecular Nanostructures Based\non Perylene Diimide Bioconjugates: From Self-Assembly to Applications","volume":"12","author":"Kihal","year":"2022","journal-title":"Nanomaterials"},{"issue":"42","key":"2026091008094729000_cit11","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200990157","article-title":"Soluble Graphene: Soluble Graphene:\nGeneration of Aqueous Graphene Solutions Aided by a Perylenebisimide-Based\nBolaamphiphile (Adv. Mater. 42\/2009)","volume":"21","author":"Englert","year":"2009","journal-title":"Adv.\nMater."},{"issue":"1","key":"2026091008094729000_cit12","doi-asserted-by":"publisher","first-page":"31989","DOI":"10.1038\/s41598-024-83525-x","article-title":"Aggregation\nPathway Complexity in\na Simple Perylene Diimide","volume":"14","author":"Kim","year":"2024","journal-title":"Sci. Rep."},{"key":"2026091008094729000_cit13","doi-asserted-by":"publisher","DOI":"10.1016\/j.supmat.2023.100031","article-title":"Perylene Diimide\nSupramolecular Aggregates: Constructions and Sensing Applications","volume":"2","author":"Wu","year":"2023","journal-title":"Supramolecular Materials"},{"issue":"3","key":"2026091008094729000_cit14","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202103443","article-title":"Design and Control of Perylene Supramolecular Polymers through Imide\nSubstitutions","volume":"28","author":"Wilson-Kovacs","year":"2022","journal-title":"Chem.\u2013Eur. J."},{"issue":"15","key":"2026091008094729000_cit15","doi-asserted-by":"publisher","DOI":"10.1063\/1.3245403","article-title":"Multimode\nSimulation of Dimer Absorption Spectra from First Principles Calculations:\nApplication to the 3,4,9,10-Perylenetetracarboxylic Diimide Dimer","volume":"131","author":"Guthmuller","year":"2009","journal-title":"J. Chem. Phys."},{"issue":"24","key":"2026091008094729000_cit16","doi-asserted-by":"publisher","first-page":"7586","DOI":"10.1021\/ja0687724","article-title":"Beyond\nExciton Theory: A Time-Dependent DFT and Franck\u2013Condon\nStudy of Perylene Diimide and Its Chromophoric Dimer","volume":"129","author":"Clark","year":"2007","journal-title":"J. Am. Chem. Soc."},{"issue":"6","key":"2026091008094729000_cit17","doi-asserted-by":"publisher","first-page":"3718","DOI":"10.1021\/acs.jctc.2c00063","article-title":"How the Interplay among\nConformational Disorder, Solvation, Local, and Charge-Transfer Excitations\nAffects the Absorption Spectrum and Photoinduced Dynamics of Perylene\nDiimide Dimers: A Molecular Dynamics\/Quantum Vibronic Approach","volume":"18","author":"Segalina","year":"2022","journal-title":"J. Chem. Theory Comput."},{"issue":"15","key":"2026091008094729000_cit18","doi-asserted-by":"publisher","first-page":"7069","DOI":"10.1021\/acs.chemrev.7b00581","article-title":"Expanded Theory\nof H- and J-Molecular Aggregates: The\nEffects of Vibronic Coupling and Intermolecular Charge Transfer","volume":"118","author":"Hestand","year":"2018","journal-title":"Chem. Rev."},{"issue":"3","key":"2026091008094729000_cit19","doi-asserted-by":"publisher","first-page":"429","DOI":"10.1021\/ar900233v","article-title":"The Spectral\nSignatures of Frenkel Polarons in H- and J-Aggregates","volume":"43","author":"Spano","year":"2010","journal-title":"Acc. Chem. Res."},{"issue":"34","key":"2026091008094729000_cit20","doi-asserted-by":"publisher","first-page":"15917","DOI":"10.1039\/C9NR03898A","article-title":"Insight\ninto the Self-Assembly of Water-Soluble Perylene\nBisimide Derivatives through a Combined Computational and Experimental\nApproach","volume":"11","author":"Draper","year":"2019","journal-title":"Nanoscale"},{"issue":"40","key":"2026091008094729000_cit21","doi-asserted-by":"publisher","first-page":"17670","DOI":"10.1002\/ange.202005837","article-title":"N -Annulated Perylene Bisimides to\nBias the Differentiation of Metastable\nSupramolecular Assemblies into J- and H-Aggregates","volume":"132","author":"Greciano","year":"2020","journal-title":"Angew. Chem."},{"issue":"6","key":"2026091008094729000_cit22","doi-asserted-by":"publisher","first-page":"1513","DOI":"10.1039\/C5CS00754B","article-title":"Water-Soluble Perylenediimides: Design\nConcepts and Biological Applications","volume":"45","author":"Sun","year":"2016","journal-title":"Chem.\nSoc. Rev."},{"issue":"36","key":"2026091008094729000_cit23","doi-asserted-by":"publisher","first-page":"9900","DOI":"10.1039\/D3SC03372D","article-title":"Solvent-Dependent\nSelf-Assembly of N -Annulated Perylene Diimides.\nFrom Dimers to Supramolecular Polymers","volume":"14","author":"Naranjo","year":"2023","journal-title":"Chem.\nSci."},{"issue":"40","key":"2026091008094729000_cit24","doi-asserted-by":"publisher","first-page":"23626","DOI":"10.1039\/D5NR02723C","article-title":"Anticooperative Self-Assembly of\nPerylene Diimide Dyes in Water Unveiled by Advanced Molecular Dynamics\nSimulations","volume":"17","author":"Cantina","year":"2025","journal-title":"Nanoscale"},{"issue":"33","key":"2026091008094729000_cit25","doi-asserted-by":"publisher","first-page":"13281","DOI":"10.1021\/jacs.1c06125","article-title":"Distance Matters:\nBiasing Mechanism, Transfer of Asymmetry, and Stereomutation in N-Annulated\nPerylene Bisimide Supramolecular Polymers","volume":"143","author":"Marti\u0301nez","year":"2021","journal-title":"J.\nAm. Chem. Soc."},{"issue":"43","key":"2026091008094729000_cit26","doi-asserted-by":"publisher","first-page":"9670","DOI":"10.1021\/jp994190f","article-title":"Dynamics of\nFormation of 1,1\u2018-Diethyl-2,2\u2018-Cyanine Iodide J-Aggregates\nin Solution","volume":"104","author":"Struganova","year":"2000","journal-title":"J. Phys. Chem. A"},{"issue":"21","key":"2026091008094729000_cit27","doi-asserted-by":"publisher","first-page":"4758","DOI":"10.1021\/jp058014k","article-title":"Kinetics of Salt-Induced J-Aggregation\nof Cyanine Dyes","volume":"109","author":"Slavnova","year":"2005","journal-title":"J. Phys. Chem. A"},{"issue":"14","key":"2026091008094729000_cit28","doi-asserted-by":"publisher","first-page":"1622","DOI":"10.2174\/138955709791012274","article-title":"Water Soluble Cationic\nPerylene Derivatives as Possible Telomerase Inhibitors: The Search\nfor Selective G-Quadruplex Targeting","volume":"9","author":"Michelia","year":"2009","journal-title":"Mini-Rev.\nMed. Chem."},{"issue":"5","key":"2026091008094729000_cit29","doi-asserted-by":"publisher","first-page":"2292","DOI":"10.1016\/j.bmc.2007.11.065","article-title":"The Number\nand Distances of Positive Charges of Polyamine Side Chains in a Series\nof Perylene Diimides Significantly Influence Their Ability to Induce\nG-Quadruplex Structures and Inhibit Human Telomerase","volume":"16","author":"Franceschin","year":"2008","journal-title":"Bioorg. Med. Chem."},{"issue":"23","key":"2026091008094729000_cit30","doi-asserted-by":"publisher","first-page":"3395","DOI":"10.1016\/S0960-894X(02)00763-1","article-title":"The Aggregation\nand G-Quadruplex DNA Selectivity of\nCharged 3,4,9,10-Perylenetetracarboxylic Acid Diimides","volume":"12","author":"Kern","year":"2002","journal-title":"Bioorg. Med. Chem. Lett."},{"issue":"18","key":"2026091008094729000_cit31","doi-asserted-by":"publisher","first-page":"9784","DOI":"10.1021\/acsami.5b01665","article-title":"Molecular\nSize, Shape,\nand Electric Charges: Essential for Perylene Bisimide-Based DNA Intercalator\nto Localize in Cell Nuclei and Inhibit Cancer Cell Growth","volume":"7","author":"Xu","year":"2015","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"2026091008094729000_cit32","doi-asserted-by":"publisher","first-page":"454","DOI":"10.1016\/j.cplett.2017.03.056","article-title":"Structural and Optical\nProperties of a Perylene Bisimide in Aqueous Media","volume":"683","author":"Burian","year":"2017","journal-title":"Chem. Phys. Lett."},{"issue":"9","key":"2026091008094729000_cit33","doi-asserted-by":"publisher","first-page":"1103","DOI":"10.1039\/c6pp00221h","article-title":"Self-Assembly\nof Organic Dyes in Supramolecular Aggregates","volume":"15","author":"Heyne","year":"2016","journal-title":"Photochemical & Photobiological Sciences"},{"issue":"7","key":"2026091008094729000_cit34","doi-asserted-by":"publisher","first-page":"1223","DOI":"10.3390\/nano12071223","article-title":"Supramolecular\nNanostructures Based\non Perylene Diimide Bioconjugates: From Self-Assembly to Applications","volume":"12","author":"Kihal","year":"2022","journal-title":"Nanomaterials"},{"issue":"9","key":"2026091008094729000_cit35","doi-asserted-by":"publisher","first-page":"3300","DOI":"10.1021\/ja511952c","article-title":"Mechanism\nof Self-Assembly Process and Seeded Supramolecular Polymerization\nof Perylene Bisimide Organogelator","volume":"137","author":"Ogi","year":"2015","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026091008094729000_cit36","doi-asserted-by":"publisher","first-page":"54","DOI":"10.1016\/j.dyepig.2017.06.051","article-title":"Insights into\nthe Anion Effect on the Self Assembly of Perylene Bisimide Diimidazolium\nSalts","volume":"146","author":"Marullo","year":"2017","journal-title":"Dyes Pigm."},{"issue":"11","key":"2026091008094729000_cit37","doi-asserted-by":"publisher","first-page":"7541","DOI":"10.1021\/acs.joc.4c00183","article-title":"Self-Aggregation,\nEnhanced Guest-Binding\nBehavior, and Anion-Induced Agglutination of Cyclophane Dimers Linked\nwith Florescent Perylene Diimide","volume":"89","author":"Hayashida","year":"2024","journal-title":"J. Org. Chem."},{"issue":"31","key":"2026091008094729000_cit38","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202501270","article-title":"Core-Twisted,\nCationic Perylene Diimides; Homochiral Dimerization and Chiroptical\nAnion Sensing","volume":"31","author":"Hartmann","year":"2025","journal-title":"Chem.\u2013Eur. J."},{"issue":"11","key":"2026091008094729000_cit39","doi-asserted-by":"publisher","first-page":"6203","DOI":"10.1016\/S0021-9258(19)39311-1","article-title":"Anion-Linked\nPolymerization of the\nTetrameric Hemoglobin from Scapharca Inaequivalvis. Characterization\nand Functional Relevance","volume":"265","author":"Boffi","year":"1990","journal-title":"J. Biol. Chem."},{"issue":"4","key":"2026091008094729000_cit40","doi-asserted-by":"publisher","first-page":"2379","DOI":"10.1039\/C9CP06089H","article-title":"Calculation of Vibrationally Resolved Absorption and\nFluorescence Spectra of the Rylenes","volume":"22","author":"Greiner","year":"2020","journal-title":"Phys. Chem.\nChem. Phys."},{"key":"2026091008094729000_cit41","volume-title":"Coherent Raman Scattering\nMicroscopy","author":"Potma","year":"2013"},{"issue":"20","key":"2026091008094729000_cit42","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.133.206902","article-title":"Temperature\nDependence of Coherent versus Spontaneous Raman Scattering","volume":"133","author":"Batignani","year":"2024","journal-title":"Phys. Rev. Lett."},{"issue":"12","key":"2026091008094729000_cit43","doi-asserted-by":"publisher","DOI":"10.1063\/1.2356318","article-title":"Generation\nof Narrow-Bandwidth Picosecond Visible Pulses from Broadband Femtosecond\nPulses for Femtosecond Stimulated Raman","volume":"89","author":"Shim","year":"2006","journal-title":"Appl.\nPhys. Lett."},{"issue":"1","key":"2026091008094729000_cit44","doi-asserted-by":"publisher","first-page":"34","DOI":"10.1038\/s43586-024-00314-6","article-title":"Femtosecond Stimulated Raman Spectroscopy","volume":"4","author":"Batignani","year":"2024","journal-title":"Nature Reviews Methods Primers"},{"issue":"19","key":"2026091008094729000_cit45","doi-asserted-by":"publisher","first-page":"3660","DOI":"10.1021\/jp027394w","article-title":"Electronic\nAbsorption Spectra of Neutral Perylene (C20H12),\nTerrylene (C30H16), and Quaterrylene (C40H20) and Their Positive and\nNegative Ions: Ne Matrix-Isolation Spectroscopy and Time-Dependent\nDensity Functional Theory Calculations","volume":"107","author":"Halasinski","year":"2003","journal-title":"J. Phys.\nChem. A"},{"issue":"7","key":"2026091008094729000_cit46","doi-asserted-by":"publisher","DOI":"10.1063\/1.3549143","article-title":"Theoretical\nPredictions of Red and Near-Infrared Strongly Emitting X-Annulated\nRylenes","volume":"134","author":"Peng","year":"2011","journal-title":"J. Chem. Phys."},{"issue":"1\u20133","key":"2026091008094729000_cit47","doi-asserted-by":"publisher","first-page":"131","DOI":"10.1016\/S0166-1280(98)00266-8","article-title":"Theoretical\nStudies of the Infrared\nand Raman Spectra of Perylene","volume":"459","author":"Ong","year":"1999","journal-title":"Journal of Molecular\nStructure: THEOCHEM"},{"issue":"20","key":"2026091008094729000_cit48","doi-asserted-by":"publisher","first-page":"13659","DOI":"10.1103\/PhysRevB.61.13659","article-title":"Resonant Raman\nSpectroscopy of 3,4,9,10-Perylene-Tetracarboxylic-Dianhydride\nEpitaxial Films","volume":"61","author":"Scholz","year":"2000","journal-title":"Phys. Rev. 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