{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T15:57:43Z","timestamp":1791475063295,"version":"4.3.4"},"reference-count":46,"publisher":"American Chemical Society (ACS)","issue":"40","license":[{"start":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T00:00:00Z","timestamp":1788912000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T00:00:00Z","timestamp":1788912000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T00:00:00Z","timestamp":1788912000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001502","name":"Department of Atomic Energy, Government of India","doi-asserted-by":"publisher","award":["RIN-4002"],"award-info":[{"award-number":["RIN-4002"]}],"id":[{"id":"10.13039\/501100001502","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["CRG\/2022\/001096"],"award-info":[{"award-number":["CRG\/2022\/001096"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Thiourea (TU) is a versatile functional scaffold in catalysis, sensing, and medicinal chemistry, owing to its strong electron-donating character. However, the photophysical parameters governing the efficiency of TU derivatives in photoinduced electron transfer (PET) remain poorly understood. Here, we systematically investigated TU-mediated PET by introducing controlled alkyl substitution at the nitrogen centers while preserving the thiocarbonyl framework. Using Rhodamine 6G (Rh6G) as a model fluorophore, we combined quantum chemical calculations with steady-state and time-resolved spectroscopic techniques to elucidate structure-PET relationships. Progressive alkyl substitution leads to a significant enhancement in fluorescence quenching efficiency (67 to \u223c90 %). While the free energy change (\u0394G) exhibits minor deviation, the donor\u2013acceptor energy gap (\u0394E) decreases systematically, identifying \u0394E as a key parameter governing PET efficiency in these systems. Time-resolved fluorescence and femtosecond transient absorption measurements reveal the emergence of intrinsic PET dynamics on the \u223c220\u2013360 ps time scale and confirm the formation of long-lived Rh6G radical species. Higher alkylated derivatives exhibit mixed static-dynamic quenching, driven by enhanced ground-state association. This behavior arises from a synergistic interplay of increased electron density and hydrophobic interactions, which collectively promote efficient PET. These findings establish a mechanistic framework for tuning electron transfer in thiocarbonyl systems and provide design principles for advanced fluorescent probes and sensing platforms.<\/jats:p>","DOI":"10.1021\/acs.jpclett.6c02379","type":"journal-article","created":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T21:02:09Z","timestamp":1788987729000},"page":"11469-11478","source":"Crossref","is-referenced-by-count":0,"title":["Thiourea-Mediated\nPhotoinduced Electron Transfer in\nWater"],"prefix":"10.1021","volume":"17","author":[{"given":"Laxmipriya","family":"Dash","sequence":"first","affiliation":[{"name":"National Institute of Science Education and Research (NISER) , , PO-Bhimpur-Padanpur, Via-Jatni, District-Khurda , PIN- ,","place":["Bhubaneswar, India, 752050"]},{"name":"Homi Bhabha National Institute , Training School Complex, Anushakti Nagar , ,","place":["Mumbai, India, 400094"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9474-821X","authenticated-orcid":true,"given":"Subhrakant","family":"Jena","sequence":"additional","affiliation":[{"name":"National Institute of Science Education and Research (NISER) , , PO-Bhimpur-Padanpur, Via-Jatni, District-Khurda , PIN- ,","place":["Bhubaneswar, India, 752050"]},{"name":"Homi Bhabha National Institute , Training School Complex, Anushakti Nagar , ,","place":["Mumbai, India, 400094"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rudhi Ranjan","family":"Sahoo","sequence":"additional","affiliation":[{"name":"National Institute of Science Education and Research (NISER) , , PO-Bhimpur-Padanpur, Via-Jatni, District-Khurda , PIN- ,","place":["Bhubaneswar, India, 752050"]},{"name":"Homi Bhabha National Institute , Training School Complex, Anushakti Nagar , ,","place":["Mumbai, India, 400094"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ipsita","family":"Parichha","sequence":"additional","affiliation":[{"name":"National Institute of Science Education and Research (NISER) , , PO-Bhimpur-Padanpur, Via-Jatni, District-Khurda , PIN- ,","place":["Bhubaneswar, India, 752050"]},{"name":"Homi Bhabha National Institute , Training School Complex, Anushakti Nagar , ,","place":["Mumbai, India, 400094"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Madhusmita","family":"Parida","sequence":"additional","affiliation":[{"name":"National Institute of Science Education and Research (NISER) , , PO-Bhimpur-Padanpur, Via-Jatni, District-Khurda , PIN- ,","place":["Bhubaneswar, India, 752050"]},{"name":"Homi Bhabha National Institute , Training School Complex, Anushakti Nagar , ,","place":["Mumbai, India, 400094"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1823-9744","authenticated-orcid":true,"given":"Hirendra N.","family":"Ghosh","sequence":"additional","affiliation":[{"name":"National Institute of Science Education and Research (NISER) , , PO-Bhimpur-Padanpur, Via-Jatni, District-Khurda , PIN- ,","place":["Bhubaneswar, India, 752050"]},{"name":"Homi Bhabha National Institute , Training School Complex, Anushakti Nagar , ,","place":["Mumbai, India, 400094"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0791-2259","authenticated-orcid":true,"given":"Himansu S.","family":"Biswal","sequence":"additional","affiliation":[{"name":"National Institute of Science Education and Research (NISER) , , PO-Bhimpur-Padanpur, Via-Jatni, District-Khurda , PIN- ,","place":["Bhubaneswar, India, 752050"]},{"name":"Homi Bhabha National Institute , Training School Complex, Anushakti Nagar , ,","place":["Mumbai, India, 400094"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,9]]},"reference":[{"issue":"15","key":"2026100811170113000_cit1","doi-asserted-by":"publisher","first-page":"4901","DOI":"10.3390\/molecules27154901","article-title":"Thiocoumarins: From\nthe Synthesis to the Biological Applications","volume":"27","author":"Matos","year":"2022","journal-title":"Molecules"},{"issue":"10","key":"2026100811170113000_cit2","doi-asserted-by":"publisher","first-page":"4215","DOI":"10.3390\/molecules28104215","article-title":"Thiocarbonyl Derivatives of Natural\nChlorins: Synthesis Using Lawesson\u2019s Reagent and a Study of\nTheir Properties","volume":"28","author":"Pogorilyy","year":"2023","journal-title":"Molecules"},{"key":"2026100811170113000_cit3","doi-asserted-by":"publisher","first-page":"23","DOI":"10.33263\/BRIAC152.023","article-title":"Functionalized Thioureas\nin Medicinal Chemistry: Binding Ability of Thiourea Derivatives to\nBiological Targets, Focused on Their Anticancer Activity","volume":"15","author":"Zborovskii","year":"2025","journal-title":"Biointerface Res. Appl. Chem."},{"issue":"1","key":"2026100811170113000_cit4","doi-asserted-by":"publisher","first-page":"4057","DOI":"10.1038\/s41467-018-06329-4","article-title":"An ultra-low thiourea catalyzed strain-release glycosylation\nand a multicatalytic diversification strategy","volume":"9","author":"Xu","year":"2018","journal-title":"Nat. Commun."},{"issue":"1","key":"2026100811170113000_cit5","doi-asserted-by":"publisher","first-page":"93","DOI":"10.1080\/10408347.2022.2063017","article-title":"Recent advances in thiourea based colorimetric and fluorescent chemosensors\nfor detection of anions and neutral analytes: a review","volume":"54","author":"Al-Saidi","year":"2024","journal-title":"Crit. Rev. Anal. Chem."},{"issue":"21","key":"2026100811170113000_cit6","doi-asserted-by":"publisher","first-page":"21795","DOI":"10.1021\/acsomega.5c01648","article-title":"Molecular\nModeling and In Vitro Evaluation of Thioureas and Arylthioureas as\nUrease Inhibitors","volume":"10","author":"Fabris","year":"2025","journal-title":"ACS omega"},{"issue":"3","key":"2026100811170113000_cit7","doi-asserted-by":"publisher","first-page":"435","DOI":"10.3390\/chemistry6030025","article-title":"Biological\napplications of thiourea derivatives: detailed review","volume":"6","author":"Agili","year":"2024","journal-title":"Chemistry"},{"issue":"26","key":"2026100811170113000_cit8","doi-asserted-by":"publisher","first-page":"6701","DOI":"10.1039\/D0SC02286A","article-title":"Single-atom\nreplacement as a general approach towards visible-light\/near-infrared\nheavy-atom-free photosensitizers for photodynamic therapy","volume":"11","author":"Tang","year":"2020","journal-title":"Chem. Sci."},{"issue":"2","key":"2026100811170113000_cit9","doi-asserted-by":"publisher","first-page":"171","DOI":"10.1080\/17415993.2010.550294","article-title":"Oxidation of thiourea\nand substituted thioureas: a review","volume":"32","author":"Sahu","year":"2011","journal-title":"J. Sulfur\nChem."},{"issue":"32","key":"2026100811170113000_cit10","doi-asserted-by":"publisher","first-page":"6083","DOI":"10.1021\/acs.jpcb.2c03489","article-title":"Thiolumazines\nas heavy-atom-free photosensitizers for applications in daylight photodynamic\ntherapy: Insights from ultrafast excited-state dynamics","volume":"126","author":"Jena","year":"2022","journal-title":"J. Phys. Chem. B"},{"issue":"13","key":"2026100811170113000_cit11","doi-asserted-by":"publisher","first-page":"4373","DOI":"10.1002\/chem.202004627","article-title":"Doubling\nfret efficiency in proteins with extrinsic thioamide probes: implications\nto thio modified nucleobases","volume":"27","author":"Jena","year":"2021","journal-title":"Chem.\u2500Eur.\nJ."},{"issue":"41","key":"2026100811170113000_cit12","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202207521","article-title":"Hydrogen bonding\ndirected reversal of 13C NMR chemical shielding","volume":"134","author":"Jena","year":"2022","journal-title":"Angew. Chem."},{"issue":"45","key":"2026100811170113000_cit13","doi-asserted-by":"publisher","first-page":"11445","DOI":"10.1021\/acs.jpclett.4c02791","article-title":"Probing Aromaticity\nwith Supersonic Jet Spectroscopy:\nA Case Study on Furan, Thiophene, and Selenophene","volume":"15","author":"Sahu","year":"2024","journal-title":"J. Phys. Chem. Lett."},{"issue":"8","key":"2026100811170113000_cit14","doi-asserted-by":"publisher","first-page":"1580","DOI":"10.1021\/acs.accounts.0c00289","article-title":"The prodigious\nhydrogen bonds with sulfur and selenium in molecular assemblies, structural\nbiology, and functional materials","volume":"53","author":"Chand","year":"2020","journal-title":"Acc. Chem.\nRes."},{"issue":"31","key":"2026100811170113000_cit15","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202200755","article-title":"How the Chalcogen Atom Size Dictates\nthe Hydrogen-Bond\nDonor Capability of Carboxamides, Thioamides, and Selenoamides","volume":"28","author":"Nieuwland","year":"2022","journal-title":"Chem.\u2500Eur. J."},{"issue":"9","key":"2026100811170113000_cit16","doi-asserted-by":"publisher","first-page":"2713","DOI":"10.3390\/molecules27092713","article-title":"Photoinduced electron\ntransfer in organized assemblies\u2500case\nstudies","volume":"27","author":"Santoro","year":"2022","journal-title":"Molecules"},{"issue":"4","key":"2026100811170113000_cit17","doi-asserted-by":"publisher","first-page":"1123","DOI":"10.1021\/acs.jpclett.1c04247","article-title":"Photoinduced charge\ntransfer and recombination dynamics in star nonfullerene\norganic solar cells","volume":"13","author":"Chen","year":"2022","journal-title":"J. Phys. Chem. Lett."},{"issue":"7","key":"2026100811170113000_cit18","doi-asserted-by":"publisher","first-page":"2322","DOI":"10.1039\/D1CS01097B","article-title":"Photoinduced\nelectron transfer (PeT)\nbased fluorescent probes for cellular imaging and disease therapy","volume":"52","author":"Niu","year":"2023","journal-title":"Chem. Soc. Rev."},{"issue":"49","key":"2026100811170113000_cit19","doi-asserted-by":"publisher","first-page":"18651","DOI":"10.1021\/ja409709x","article-title":"Thioamide\nquenching of fluorescent probes through photoinduced electron transfer:\nmechanistic studies and applications","volume":"135","author":"Goldberg","year":"2013","journal-title":"J. Am.\nChem. Soc."},{"issue":"17","key":"2026100811170113000_cit20","doi-asserted-by":"publisher","first-page":"6529","DOI":"10.1021\/ja4005943","article-title":"Labeling\nproteins with fluorophore\/thioamide Forster resonant energy transfer\npairs by combining unnatural amino acid mutagenesis and native chemical\nligation","volume":"135","author":"Wissner","year":"2013","journal-title":"J. Am. Chem. Soc."},{"issue":"10","key":"2026100811170113000_cit21","doi-asserted-by":"publisher","first-page":"3729","DOI":"10.1039\/b926160p","article-title":"Anion complexation\nand sensing using modified urea and thiourea-based receptors","volume":"39","author":"Li","year":"2010","journal-title":"Chem. Soc. Rev."},{"issue":"8","key":"2026100811170113000_cit22","doi-asserted-by":"publisher","first-page":"3980","DOI":"10.1021\/jo4003129","article-title":"Thioureas as reporting\nelements for metal-responsive\nfluorescent chemosensors","volume":"78","author":"Vonlanthen","year":"2013","journal-title":"J. Org. Chem."},{"issue":"3","key":"2026100811170113000_cit23","doi-asserted-by":"publisher","first-page":"287","DOI":"10.1007\/s10895-005-2627-y","article-title":"Fluorescent photoinduced\nelectron transfer (PET) sensors for anions; from design to potential\napplication","volume":"15","author":"Gunnlaugsson","year":"2005","journal-title":"J. Fluoresc."},{"issue":"26","key":"2026100811170113000_cit24","doi-asserted-by":"publisher","DOI":"10.1002\/slct.202400920","article-title":"A Deep Dive\ninto Thiourea-Based Sensors\nfor Cation Sensing","volume":"9","author":"Khan","year":"2024","journal-title":"ChemistrySelect"},{"issue":"11","key":"2026100811170113000_cit25","doi-asserted-by":"publisher","first-page":"1320","DOI":"10.1021\/acs.accounts.2c00701","article-title":"Urea-and thiourea-based receptors\nfor anion binding","volume":"56","author":"Kundu","year":"2023","journal-title":"Acc. Chem. Res."},{"issue":"48","key":"2026100811170113000_cit26","doi-asserted-by":"publisher","first-page":"14200","DOI":"10.1039\/D3SC04287A","article-title":"Critical assessment of selenourea as an efficient small\nmolecule fluorescence quenching probe to monitor protein dynamics","volume":"14","author":"Jena","year":"2023","journal-title":"Chem. Sci."},{"issue":"5","key":"2026100811170113000_cit27","first-page":"885","article-title":"Corrosion inhibition\nof thiourea\nand thiadiazole derivatives: a review","volume":"3","author":"Loto","year":"2012","journal-title":"J. Mater.\nEnviron. Sci."},{"key":"2026100811170113000_cit28","doi-asserted-by":"publisher","first-page":"139218","DOI":"10.1016\/j.molstruc.2024.139218","article-title":"Thiourea derivatives as efficient inhibitors for the corrosion of\ncold rolled steel in citric acid solution: experimental and computational\nstudies","volume":"1318","author":"Jiang","year":"2024","journal-title":"J. Mol. Struct."},{"issue":"7","key":"2026100811170113000_cit29","doi-asserted-by":"publisher","first-page":"907","DOI":"10.1515\/chempap-2016-0030","article-title":"ZnO-nanorods\nas economical catalyst for synthesis of 4-amino-2-iminodithiole derivatives\nusing tetramethyl thiourea in water","volume":"70","author":"Rostami-Charati","year":"2016","journal-title":"Chem. Pap."},{"issue":"5","key":"2026100811170113000_cit30","doi-asserted-by":"publisher","first-page":"966","DOI":"10.1063\/1.1742723","article-title":"On the\ntheory of oxidation-reduction reactions involving electron transfer.\nI","volume":"24","author":"Marcus","year":"1956","journal-title":"J. Chem. Phys."},{"key":"2026100811170113000_cit31","volume-title":"Marcus\nTheory with Gaussian and ADF\u2500A Tutorial","author":"Hedstro\u0308m","year":"2016"},{"issue":"2","key":"2026100811170113000_cit32","doi-asserted-by":"publisher","first-page":"259","DOI":"10.1002\/ijch.197000029","article-title":"Kinetics of fluorescence\nquenching by electron and\nH-atom transfer","volume":"8","author":"Rehm","year":"1970","journal-title":"Isr. J. Chem."},{"issue":"14","key":"2026100811170113000_cit33","doi-asserted-by":"publisher","first-page":"6777","DOI":"10.1021\/jacs.0c01473","article-title":"A general\ndescriptor \u0394 E enables the quantitative\ndevelopment of luminescent materials based on photoinduced electron\ntransfer","volume":"142","author":"Chi","year":"2020","journal-title":"J. Am. Chem. Soc."},{"issue":"39","key":"2026100811170113000_cit34","doi-asserted-by":"publisher","first-page":"11017","DOI":"10.1021\/acs.jpcb.1c05354","article-title":"Femtosecond Upconversion\nStudy of Interfacial Electron Transfer from Photoexcited CsPbBr3 Perovskite\nNanocrystal to Rhodamine 6G","volume":"125","author":"Mishra","year":"2021","journal-title":"J. Phys. Chem.\nB"},{"issue":"5","key":"2026100811170113000_cit35","doi-asserted-by":"publisher","first-page":"2026","DOI":"10.1021\/ja4118279","article-title":"Bimolecular photoinduced\nelectron\ntransfer beyond the diffusion limit: the Rehm\u2013Weller experiment\nrevisited with femtosecond time resolution","volume":"136","author":"Rosspeintner","year":"2014","journal-title":"J. Am. Chem. Soc."},{"issue":"24","key":"2026100811170113000_cit36","doi-asserted-by":"publisher","first-page":"8775","DOI":"10.1021\/ja0508976","article-title":"Fluorescence correlation\nspectroscopy, a tool to investigate\nsupramolecular dynamics: inclusion complexes of pyronines with cyclodextrin","volume":"127","author":"Al-Soufi","year":"2005","journal-title":"J. Am. Chem. Soc."},{"issue":"6","key":"2026100811170113000_cit37","doi-asserted-by":"publisher","first-page":"3046","DOI":"10.1021\/jp3094098","article-title":"Surface-enhanced\nhyper-Raman scattering elucidates the two-photon absorption spectrum\nof rhodamine 6G","volume":"117","author":"Milojevich","year":"2013","journal-title":"J. Phys. Chem. C"},{"issue":"18","key":"2026100811170113000_cit38","doi-asserted-by":"publisher","first-page":"4182","DOI":"10.1002\/cctc.201800971","article-title":"Rhodamine\n6G radical: a spectro (fluoro) electrochemical\nand transient spectroscopic study","volume":"10","author":"Slanina","year":"2018","journal-title":"ChemCatChem."},{"issue":"11","key":"2026100811170113000_cit39","doi-asserted-by":"publisher","DOI":"10.1002\/cptc.202500117","article-title":"Ultrafast Studies of Different Oxidation and Protonation\nStates of Rhodamine 6G and Implications for Photocatalysis","volume":"9","author":"Bergwinkl","year":"2025","journal-title":"ChemPhotoChem."},{"issue":"30","key":"2026100811170113000_cit40","doi-asserted-by":"publisher","first-page":"8550","DOI":"10.1021\/acs.jpcb.1c04536","article-title":"Electron\ntransfer quenching of Rhodamine 6G by N-methylpyrrole\nis an unproductive process in the photocatalytic heterobiaryl cross-coupling\nreaction","volume":"125","author":"Tan","year":"2021","journal-title":"J. Phys. Chem. B"},{"issue":"19","key":"2026100811170113000_cit41","doi-asserted-by":"publisher","first-page":"5184","DOI":"10.1021\/jp502058e","article-title":"Excited-state\ndynamics of rhodamine\n6G in aqueous solution and at the dodecane\/water interface","volume":"118","author":"Fedoseeva","year":"2014","journal-title":"J. Phys. Chem. B"},{"issue":"17","key":"2026100811170113000_cit42","doi-asserted-by":"publisher","first-page":"5903","DOI":"10.1021\/ja00225a054","article-title":"The relative\nease of removing a proton,\na hydrogen atom, or an electron from carboxamides versus thiocarboxamides","volume":"110","author":"Bordwell","year":"1988","journal-title":"J. Am. Chem. Soc."},{"issue":"30","key":"2026100811170113000_cit43","doi-asserted-by":"publisher","first-page":"21168","DOI":"10.1021\/jacs.4c07515","article-title":"Thiourea as a \u201cpolar\nhydrophobic\u201d\nhydrogen-bonding motif: application to highly durable all-underwater\nadhesion","volume":"146","author":"Kikkawa","year":"2024","journal-title":"J. Am. Chem. Soc."},{"issue":"44","key":"2026100811170113000_cit44","doi-asserted-by":"publisher","first-page":"15671","DOI":"10.1021\/ja106273w","article-title":"Influence\nof concentration and temperature on the dynamics of water in the hydrophobic\nhydration shell of tetramethylurea","volume":"132","author":"Tielrooij","year":"2010","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026100811170113000_cit45","first-page":"102","article-title":"Structure-activity\nrelationship of thiourea derivatives: influence of substituents on\nantibacterial activity","volume":"14","author":"Zborovskii","year":"2025","journal-title":"Lett. Appl. NanoBioScience."},{"issue":"6","key":"2026100811170113000_cit46","doi-asserted-by":"publisher","first-page":"2165","DOI":"10.1007\/s10895-011-0918-z","article-title":"Photophysical studies on the interaction\nof formamide\nand alkyl substituted amides with photoinduced electron transfer (PET)\nbased acridinedione dyes in water","volume":"21","author":"Kumaran","year":"2011","journal-title":"J. Fluoresc."}],"container-title":["The Journal of Physical\nChemistry Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpclett.6c02379","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jpclcd\/article-pdf\/17\/40\/11469\/68465255\/acs.jpclett.6c02379.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jpclcd\/article-pdf\/17\/40\/11469\/68465255\/acs.jpclett.6c02379.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T15:29:15Z","timestamp":1791473355000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jpclcd\/article\/17\/40\/11469\/5427310\/Thiourea-Mediated-Photoinduced-Electron-Transfer"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,9]]},"references-count":46,"journal-issue":{"issue":"40","published-online":{"date-parts":[[2026,9,9]]},"published-print":{"date-parts":[[2026,10,8]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.jpclett.6c02379","relation":{},"ISSN":["1948-7185"],"issn-type":[{"value":"1948-7185","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,9]]}}}