{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:44:47Z","timestamp":1792784687664,"version":"4.5.0"},"reference-count":29,"publisher":"American Chemical Society (ACS)","issue":"41","license":[{"start":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T00:00:00Z","timestamp":1790812800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T00:00:00Z","timestamp":1790812800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T00:00:00Z","timestamp":1790812800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFA1207800"],"award-info":[{"award-number":["2024YFA1207800"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100018537","name":"National Science and Technology Major Project","doi-asserted-by":"publisher","award":["2025ZD0300500"],"award-info":[{"award-number":["2025ZD0300500"]}],"id":[{"id":"10.13039\/501100018537","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002367","name":"Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["XDB1710000"],"award-info":[{"award-number":["XDB1710000"]}],"id":[{"id":"10.13039\/501100002367","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002367","name":"Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["YSBR-003"],"award-info":[{"award-number":["YSBR-003"]}],"id":[{"id":"10.13039\/501100002367","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Beijing Municipal Natural Science Foundation","award":["Z230005"],"award-info":[{"award-number":["Z230005"]}]},{"name":"National Basic Research Program of China (973 Program)","award":["2022YFA1204100"],"award-info":[{"award-number":["2022YFA1204100"]}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["12174433"],"award-info":[{"award-number":["12174433"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["92476202"],"award-info":[{"award-number":["92476202"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Magnetic atoms on insulating films are promising candidates for information storage at the atomic scale, but practical operation requires their magnetic lifetimes and readout to be controllable. Here, we study holmium (Ho) single-atom magnets on MgO using electron spin resonance scanning tunneling microscopy. The two magnetic states of Ho are written by current-induced switching with a spin-polarized tip and read remotely through the ESR resonance frequency of a nearby Ti atom, which senses the Ho dipolar field. By atomic manipulation, we construct a two Ho\/one Ti structure in which the four Ho magnetic configurations are resolved as distinct Ti resonance frequencies and remain stable for up to 12 h. Rotating the external magnetic field changes the projection of the Ho dipolar fields onto the Ti-sensing axis, allowing the frequency separation between different magnetic configurations to be tuned. The same vector field control also modifies the Ho lifetime, while spatial mapping with the spin-polarized tip reveals a strong dependence of the switching dynamics on the local tip position. These results demonstrate vector field control of both the lifetime and frequency-resolved readout of surface-supported single-atom magnets.<\/jats:p>","DOI":"10.1021\/acs.jpclett.6c02503","type":"journal-article","created":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T01:01:37Z","timestamp":1790902897000},"page":"11731-11737","source":"Crossref","is-referenced-by-count":0,"title":["Tuning the Lifetime\nand Spectral Readout of Single-Atom\nMagnets with a Vector Magnetic Field"],"prefix":"10.1021","volume":"17","author":[{"given":"Zilong","family":"Wu","sequence":"first","affiliation":[{"name":"Chinese Academy of Sciences , , ,","place":["Beijing, China, 100190"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shijie","family":"Li","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences , , ,","place":["Beijing, China, 100190"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Chen","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences , , ,","place":["Beijing, China, 100190"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Wang","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences , , ,","place":["Beijing, China, 100190"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Fan","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences , , ,","place":["Beijing, China, 100190"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5863-3666","authenticated-orcid":true,"given":"Kai","family":"Yang","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences , , ,","place":["Beijing, China, 100190"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,1]]},"reference":[{"key":"2026101508221181800_cit1","doi-asserted-by":"publisher","first-page":"R199","DOI":"10.1088\/0022-3727\/38\/12\/R01","article-title":"Nanofabricated and self-assembled magnetic structures\nas data storage media","volume":"38","author":"Terris","year":"2005","journal-title":"J. Phys. D: Appl. Phys."},{"key":"2026101508221181800_cit2","doi-asserted-by":"publisher","first-page":"1989","DOI":"10.1126\/science.287.5460.1989","article-title":"Monodisperse\nFePt Nanoparticles and Ferromagnetic FePt Nanocrystal Superlattices","volume":"287","author":"Sun","year":"2000","journal-title":"Science"},{"key":"2026101508221181800_cit3","doi-asserted-by":"publisher","first-page":"179","DOI":"10.1038\/nmat2133","article-title":"Molecular\nspintronics using single-molecule magnets","volume":"7","author":"Bogani","year":"2008","journal-title":"Nat.\nMater."},{"key":"2026101508221181800_cit4","doi-asserted-by":"publisher","first-page":"109","DOI":"10.1146\/annurev-conmatphys-070909-104053","article-title":"Single-Molecule\nNanomagnets","volume":"1","author":"Friedman","year":"2010","journal-title":"Annu. Rev. Condens. Matter Phys."},{"key":"2026101508221181800_cit5","doi-asserted-by":"publisher","first-page":"141","DOI":"10.1038\/365141a0","article-title":"Magnetic bistability\nin a metal-ion cluster","volume":"365","author":"Sessoli","year":"1993","journal-title":"Nature"},{"key":"2026101508221181800_cit6","doi-asserted-by":"publisher","first-page":"196","DOI":"10.1126\/science.1214131","article-title":"Bistability\nin Atomic-Scale Antiferromagnets","volume":"335","author":"Loth","year":"2012","journal-title":"Science"},{"key":"2026101508221181800_cit7","doi-asserted-by":"publisher","first-page":"1628","DOI":"10.1126\/science.1191688","article-title":"Measurement\nof Fast Electron Spin Relaxation Times with Atomic Resolution","volume":"329","author":"Loth","year":"2010","journal-title":"Science"},{"key":"2026101508221181800_cit8","doi-asserted-by":"publisher","first-page":"318","DOI":"10.1126\/science.aad9898","article-title":"Magnetic remanence in\nsingle atoms","volume":"352","author":"Donati","year":"2016","journal-title":"Science"},{"key":"2026101508221181800_cit9","doi-asserted-by":"publisher","first-page":"226","DOI":"10.1038\/nature21371","article-title":"Reading and writing\nsingle-atom magnets","volume":"543","author":"Natterer","year":"2017","journal-title":"Nature"},{"key":"2026101508221181800_cit10","doi-asserted-by":"publisher","first-page":"027201","DOI":"10.1103\/PhysRevLett.121.027201","article-title":"Thermal and Magnetic-Field\nStability of Holmium Single-Atom Magnets","volume":"121","author":"Natterer","year":"2018","journal-title":"Phys.\nRev. Lett."},{"key":"2026101508221181800_cit11","doi-asserted-by":"publisher","first-page":"166703","DOI":"10.1103\/PhysRevLett.133.166703","article-title":"Long-Lived Magnetization in an Atomic\nSpin Chain Tuned to a Diabolic\nPoint","volume":"133","author":"Elbertse","year":"2024","journal-title":"Phys. Rev. Lett."},{"key":"2026101508221181800_cit12","doi-asserted-by":"publisher","first-page":"7785","DOI":"10.1038\/s41467-025-63232-5","article-title":"Single-shot readout\nof the nuclear spin of an on-surface atom","volume":"16","author":"Stolte","year":"2025","journal-title":"Nat.\nCommun."},{"key":"2026101508221181800_cit13","doi-asserted-by":"publisher","first-page":"10454","DOI":"10.1038\/ncomms10454","article-title":"Absence of a spin-signature from a single Ho adatom\nas probed by spin-sensitive tunneling","volume":"7","author":"Steinbrecher","year":"2016","journal-title":"Nat.\nCommun."},{"key":"2026101508221181800_cit14","doi-asserted-by":"publisher","first-page":"257202","DOI":"10.1103\/PhysRevLett.121.257202","article-title":"Spin Excitations\nin a 4f-3d Heterodimer\non MgO","volume":"121","author":"Singha","year":"2018","journal-title":"Phys. Rev. Lett."},{"key":"2026101508221181800_cit15","doi-asserted-by":"publisher","first-page":"242","DOI":"10.1038\/nature12759","article-title":"Stabilizing the magnetic\nmoment of single holmium atoms by symmetry","volume":"503","author":"Miyamachi","year":"2013","journal-title":"Nature"},{"key":"2026101508221181800_cit16","doi-asserted-by":"publisher","first-page":"237201","DOI":"10.1103\/PhysRevLett.113.237201","article-title":"Magnetism\nof Ho and Er Atoms on Close-Packed Metal Surfaces","volume":"113","author":"Donati","year":"2014","journal-title":"Phys. Rev. Lett."},{"key":"2026101508221181800_cit17","doi-asserted-by":"publisher","first-page":"180405","DOI":"10.1103\/PhysRevB.100.180405","article-title":"Quantum state manipulation of single\natom magnets using the hyperfine interaction","volume":"100","author":"Forrester","year":"2019","journal-title":"Phys. Rev. B"},{"key":"2026101508221181800_cit18","doi-asserted-by":"publisher","first-page":"2213951","DOI":"10.1002\/adfm.202213951","article-title":"The Impact of Lattice\nDistortions on the Magnetic Stability of Single Atoms: Dy and Ho on\nBaO(100)","volume":"33","author":"Sorokin","year":"2023","journal-title":"Adv. Funct. Materials"},{"key":"2026101508221181800_cit19","doi-asserted-by":"publisher","first-page":"077204","DOI":"10.1103\/PhysRevLett.124.077204","article-title":"Unconventional Spin\nRelaxation Involving Localized Vibrational Modes\nin Ho Single-Atom Magnets","volume":"124","author":"Donati","year":"2020","journal-title":"Phys. Rev. Lett."},{"key":"2026101508221181800_cit20","doi-asserted-by":"publisher","first-page":"4179","DOI":"10.1038\/s41467-021-24465-2","article-title":"Engineering atomic-scale\nmagnetic fields by dysprosium single atom magnets","volume":"12","author":"Singha","year":"2021","journal-title":"Nat. Commun."},{"key":"2026101508221181800_cit21","doi-asserted-by":"publisher","first-page":"1782","DOI":"10.1038\/s41565-024-01775-2","article-title":"Construction\nof topological quantum magnets from atomic spins on\nsurfaces","volume":"19","author":"Wang","year":"2024","journal-title":"Nat. Nanotechnol."},{"key":"2026101508221181800_cit22","doi-asserted-by":"publisher","first-page":"8988","DOI":"10.1038\/s41467-025-64022-9","article-title":"Electrically tunable quantum interference of atomic\nspins on surfaces","volume":"16","author":"Wang","year":"2025","journal-title":"Nat. Commun."},{"key":"2026101508221181800_cit23","doi-asserted-by":"publisher","first-page":"420","DOI":"10.1038\/nnano.2017.18","article-title":"Atomic-scale sensing of the magnetic\ndipolar field\nfrom single atoms","volume":"12","author":"Choi","year":"2017","journal-title":"Nature Nanotechnol"},{"key":"2026101508221181800_cit24","doi-asserted-by":"publisher","first-page":"227206","DOI":"10.1103\/PhysRevLett.119.227206","article-title":"Engineering the Eigenstates\nof Coupled Spin-1\/2 Atoms on a Surface","volume":"119","author":"Yang","year":"2017","journal-title":"Phys.\nRev. Lett."},{"key":"2026101508221181800_cit25","doi-asserted-by":"publisher","first-page":"045419","DOI":"10.1103\/PhysRevB.96.045419","article-title":"Adsorption\nsites of\nindividual metal atoms on ultrathin MgO(100) films","volume":"96","author":"Fernandes","year":"2017","journal-title":"Phys. Rev. B"},{"key":"2026101508221181800_cit26","doi-asserted-by":"publisher","first-page":"5927","DOI":"10.1038\/s41467-026-74922-z","article-title":"Force-based reading\nand writing of individual single-atom magnets","volume":"17","author":"Adachi","year":"2026","journal-title":"Nat. Commun."},{"key":"2026101508221181800_cit27","doi-asserted-by":"publisher","first-page":"509","DOI":"10.1126\/science.aay6779","article-title":"Coherent spin manipulation\nof individual atoms on a\nsurface","volume":"366","author":"Yang","year":"2019","journal-title":"Science"},{"key":"2026101508221181800_cit28","doi-asserted-by":"publisher","first-page":"5618","DOI":"10.1021\/acs.jpclett.0c01281","article-title":"Probing Magnetism in\nArtificial Metal\u2013Organic Complexes Using Electronic Spin Relaxometry","volume":"11","author":"Zhang","year":"2020","journal-title":"J. Phys. Chem. Lett."},{"key":"2026101508221181800_cit29","doi-asserted-by":"publisher","first-page":"1005","DOI":"10.1038\/s41567-019-0573-x","article-title":"Magnetic\nresonance imaging of single atoms on a surface","volume":"15","author":"Willke","year":"2019","journal-title":"Nat. Phys."}],"container-title":["The Journal of Physical\nChemistry Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpclett.6c02503","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jpclcd\/article-pdf\/17\/41\/11731\/68731145\/acs.jpclett.6c02503.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jpclcd\/article-pdf\/17\/41\/11731\/68731145\/acs.jpclett.6c02503.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T12:49:31Z","timestamp":1792068571000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jpclcd\/article\/17\/41\/11731\/5443636\/Tuning-the-Lifetime-and-Spectral-Readout-of-Single"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,1]]},"references-count":29,"journal-issue":{"issue":"41","published-online":{"date-parts":[[2026,10,1]]},"published-print":{"date-parts":[[2026,10,15]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.jpclett.6c02503","relation":{},"ISSN":["1948-7185"],"issn-type":[{"value":"1948-7185","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,1]]}}}