{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:44:47Z","timestamp":1792784687921,"version":"4.5.0"},"reference-count":44,"publisher":"American Chemical Society (ACS)","issue":"41","license":[{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100011280","name":"State Key Laboratory of Engines","doi-asserted-by":"publisher","award":["K2025-10"],"award-info":[{"award-number":["K2025-10"]}],"id":[{"id":"10.13039\/501100011280","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Natural Science Foundation of Chongqing","award":["CSTB2024NSCQ-MSX0915"],"award-info":[{"award-number":["CSTB2024NSCQ-MSX0915"]}]},{"name":"National Basic Research Program of China (973 Program)","award":["2025YFE0206900"],"award-info":[{"award-number":["2025YFE0206900"]}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["52394202"],"award-info":[{"award-number":["52394202"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["52476056"],"award-info":[{"award-number":["52476056"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["525B2088"],"award-info":[{"award-number":["525B2088"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Electrochemical CO2 reduction (ECR) is highly sensitive to the electrode-electrolyte interfacial microenvironment (EEIM). However, how the hydration structures of alkali-metal cations reorganize EEIM and thereby influence the energetics of ECR and hydrogen evolution reaction (HER) related elementary steps remains unclear. Here, explicit-solvent ab initio molecular dynamics simulations were used to elucidate the cation-dependent restructuring of interfacial water. Specifically, cation-specific hydration governs the spatial distribution, hydrogen-bond connectivity, and orientation of interfacial water. Strongly hydrated Li+ maintains a highly connected hydrogen-bond network, lowers the activation barrier for Volmer water activation, and facilitates the removal of the generated OH\u2013 from the interface. In contrast, weakly hydrated K+ creates a broader water-depletion region near the electrode, disrupts hydrogen-bond connectivity, and promotes a more pronounced H-down orientation of interfacial water. This reconstructed interface increases the accessibility of water hydrogen atoms to adsorbed *CO2, thereby creating an EEIM that favors ECR. Moreover, weakly hydrogen-bonded, K+ coordinated water provides a more energetically favorable proton-donation environment than water embedded in a strongly connected hydrogen-bond network, thereby lowering the activation barrier for *COOH formation. These findings establish a molecular-level link among cation hydration strength, interfacial water restructuring, and reaction selectivity, providing a mechanistic basis for tuning electrochemical interfacial microenvironments through cation engineering.<\/jats:p>","DOI":"10.1021\/acs.jpclett.6c02653","type":"journal-article","created":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T10:04:39Z","timestamp":1790589879000},"page":"11947-11954","source":"Crossref","is-referenced-by-count":0,"title":["Interfacial\nCations Modulate CO2 Reduction\nSelectivity by Shaping Hydrogen-Bond Networks and Water Orientation"],"prefix":"10.1021","volume":"17","author":[{"given":"Hang","family":"Wang","sequence":"first","affiliation":[{"name":"Chongqing University, Ministry of Education , , ,","place":["Chongqing, China, 400044"]},{"name":"Chongqing University , , ,","place":["Chongqing, China, 400044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan","family":"Liang","sequence":"additional","affiliation":[{"name":"Chongqing University, Ministry of Education , , ,","place":["Chongqing, China, 400044"]},{"name":"Chongqing University , , ,","place":["Chongqing, China, 400044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuanjun","family":"Wang","sequence":"additional","affiliation":[{"name":"Chongqing University, Ministry of Education , , ,","place":["Chongqing, China, 400044"]},{"name":"Chongqing University , , ,","place":["Chongqing, China, 400044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haomiao","family":"Cao","sequence":"additional","affiliation":[{"name":"Chongqing University, Ministry of Education , , ,","place":["Chongqing, China, 400044"]},{"name":"Chongqing University , , ,","place":["Chongqing, China, 400044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9651-1160","authenticated-orcid":true,"given":"Qiang","family":"Liao","sequence":"additional","affiliation":[{"name":"Chongqing University, Ministry of Education , , ,","place":["Chongqing, China, 400044"]},{"name":"Chongqing University , , ,","place":["Chongqing, China, 400044"]},{"name":"National Innovation Center for Industry-Education Integration of Energy Storage Technology , ,","place":["Chongqing, China, 400044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1180-7403","authenticated-orcid":true,"given":"Yang","family":"Wang","sequence":"additional","affiliation":[{"name":"Chongqing University, Ministry of Education , , ,","place":["Chongqing, China, 400044"]},{"name":"Chongqing University , , ,","place":["Chongqing, China, 400044"]},{"name":"National Innovation Center for Industry-Education Integration of Energy Storage Technology , ,","place":["Chongqing, China, 400044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7537-3069","authenticated-orcid":true,"given":"Qian","family":"Fu","sequence":"additional","affiliation":[{"name":"Chongqing University, Ministry of Education , , ,","place":["Chongqing, China, 400044"]},{"name":"Chongqing University , , ,","place":["Chongqing, China, 400044"]},{"name":"National Innovation Center for Industry-Education Integration of Energy Storage Technology , ,","place":["Chongqing, China, 400044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3923-5977","authenticated-orcid":true,"given":"Xun","family":"Zhu","sequence":"additional","affiliation":[{"name":"Chongqing University, Ministry of Education , , ,","place":["Chongqing, China, 400044"]},{"name":"Chongqing University , , ,","place":["Chongqing, China, 400044"]},{"name":"National Innovation Center for Industry-Education Integration of Energy Storage Technology , ,","place":["Chongqing, China, 400044"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,28]]},"reference":[{"issue":"51","key":"2026101508222017900_cit1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202306288","article-title":"Stability Issues in\nElectrochemical CO2 Reduction: Recent Advances in Fundamental\nUnderstanding and Design Strategies","volume":"35","author":"Lai","year":"2023","journal-title":"Advanced\nMaterials"},{"issue":"7","key":"2026101508222017900_cit2","doi-asserted-by":"publisher","first-page":"6560","DOI":"10.1021\/acscatal.8b01340","article-title":"Standards and Protocols for Data Acquisition and Reporting\nfor Studies of the Electrochemical Reduction of Carbon Dioxide","volume":"8","author":"Clark","year":"2018","journal-title":"ACS Catal."},{"key":"2026101508222017900_cit3","doi-asserted-by":"publisher","DOI":"10.1016\/j.decarb.2025.100112","article-title":"Synthesis, Characterizations, and\nStructure-Activity Relationship of Dual-Atom Catalysts for CO2 electroreduction","volume":"9","author":"Li","year":"2025","journal-title":"DeCarbon"},{"key":"2026101508222017900_cit4","doi-asserted-by":"publisher","DOI":"10.1016\/j.decarb.2025.100132","article-title":"A Review on\nNano-Micro Structure Design of Fuel Cells for Efficient Heat and Mass\nTransport","volume":"10","author":"Xu","year":"2025","journal-title":"DeCarbon"},{"issue":"4","key":"2026101508222017900_cit5","doi-asserted-by":"publisher","first-page":"495","DOI":"10.1021\/acs.accounts.1c00679","article-title":"Theories for\nElectrolyte Effects in CO2 Electroreduction","volume":"55","author":"Xu","year":"2022","journal-title":"Acc. Chem. Res."},{"issue":"10","key":"2026101508222017900_cit6","doi-asserted-by":"publisher","first-page":"3001","DOI":"10.1039\/C9EE01341E","article-title":"Understanding\nCation Effects in Electrochemical\nCO2 Reduction","volume":"12","author":"Ringe","year":"2019","journal-title":"Energy Environ. Sci."},{"issue":"1","key":"2026101508222017900_cit7","doi-asserted-by":"publisher","first-page":"7607","DOI":"10.1038\/s41467-023-43300-4","article-title":"Cation-Induced Changes\nin the Inner- and Outer-Sphere Mechanisms of Electrocatalytic CO2 Reduction","volume":"14","author":"Qin","year":"2023","journal-title":"Nat. Commun."},{"issue":"17","key":"2026101508222017900_cit8","doi-asserted-by":"publisher","first-page":"14588","DOI":"10.1021\/acscatal.5c03725","article-title":"Revealing the Role\nof the Electrical Double Layer in Electrochemical CO2 Reduction","volume":"15","author":"King","year":"2025","journal-title":"ACS Catal."},{"issue":"10","key":"2026101508222017900_cit9","doi-asserted-by":"publisher","first-page":"7133","DOI":"10.1021\/acscatal.6b02299","article-title":"Electric\nField Effects in Electrochemical CO2 Reduction","volume":"6","author":"Chen","year":"2016","journal-title":"ACS Catal."},{"issue":"11","key":"2026101508222017900_cit10","doi-asserted-by":"publisher","first-page":"8168","DOI":"10.1021\/acscatal.4c00639","article-title":"Modulating\nActivity and Selectivity\nof CO2 Electroreductions at Au\u2013Water Interfaces\nvia Engineering Local Cation Condition","volume":"14","author":"Qin","year":"2024","journal-title":"ACS\nCatal."},{"issue":"24","key":"2026101508222017900_cit11","doi-asserted-by":"publisher","first-page":"14871","DOI":"10.1021\/acscatal.0c03553","article-title":"Cation Effect on Interfacial\nCO2 Concentration in the Electrochemical CO2 Reduction\nReaction","volume":"10","author":"Malkani","year":"2020","journal-title":"ACS Catal."},{"issue":"36","key":"2026101508222017900_cit12","doi-asserted-by":"publisher","first-page":"25282","DOI":"10.1021\/jacs.4c09512","article-title":"Electrochemical\nCO2 Reduction in Acidic Electrolytes: Spectroscopic Evidence\nfor Local pH Gradients","volume":"146","author":"Hicks","year":"2024","journal-title":"J. Am. Chem. Soc."},{"issue":"9","key":"2026101508222017900_cit13","doi-asserted-by":"publisher","first-page":"905","DOI":"10.1038\/s41929-025-01399-2","article-title":"Microenvironment Effects in Electrochemical\nCO2 Reduction from First-Principles Multiscale Modelling","volume":"8","author":"Lorenzutti","year":"2025","journal-title":"Nat. Catal"},{"issue":"6","key":"2026101508222017900_cit14","doi-asserted-by":"publisher","first-page":"1267","DOI":"10.1016\/j.checat.2022.03.012","article-title":"Understanding and Leveraging the\nEffect of Cations in the Electrical Double Layer for Electrochemical\nCO2 Reduction","volume":"2","author":"Pan","year":"2022","journal-title":"Chem. Catalysis"},{"issue":"1","key":"2026101508222017900_cit15","doi-asserted-by":"publisher","first-page":"15","DOI":"10.1016\/0927-0256(96)00008-0","article-title":"Efficiency of Ab-Initio Total Energy Calculations for\nMetals and Semiconductors Using a Plane-Wave Basis Set","volume":"6","author":"Kresse","year":"1996","journal-title":"Computational Materials Science"},{"issue":"16","key":"2026101508222017900_cit16","doi-asserted-by":"publisher","first-page":"11169","DOI":"10.1103\/PhysRevB.54.11169","article-title":"Efficient\nIterative Schemes for Ab Initio Total-Energy Calculations\nUsing a Plane-Wave Basis Set","volume":"54","author":"Kresse","year":"1996","journal-title":"Phys. Rev. B"},{"issue":"1","key":"2026101508222017900_cit17","doi-asserted-by":"publisher","first-page":"558","DOI":"10.1103\/PhysRevB.47.558","article-title":"Ab Initio Molecular Dynamics for Liquid\nMetals","volume":"47","author":"Kresse","year":"1993","journal-title":"Phys. Rev. B"},{"issue":"20","key":"2026101508222017900_cit18","doi-asserted-by":"publisher","first-page":"14251","DOI":"10.1103\/PhysRevB.49.14251","article-title":"Ab Initio Molecular-Dynamics Simulation\nof the Liquid-Metal\u2013Amorphous-Semiconductor Transition in Germanium","volume":"49","author":"Kresse","year":"1994","journal-title":"Phys. Rev. B"},{"issue":"3","key":"2026101508222017900_cit19","doi-asserted-by":"publisher","first-page":"598","DOI":"10.1016\/j.scib.2025.12.048","article-title":"Multiscale Insights of Interfacial\nTransport and Kinetics in Acidic\nCO2 Electroreduction","volume":"71","author":"Wang","year":"2026","journal-title":"Science Bulletin"},{"issue":"43","key":"2026101508222017900_cit20","doi-asserted-by":"publisher","first-page":"20908","DOI":"10.1021\/acs.energyfuels.5c03026","article-title":"Continuum\nModeling of the Electrical Double Layer at the Acidic CO2 Electroreduction Reaction Interface","volume":"39","author":"Wang","year":"2025","journal-title":"Energy\nFuels"},{"issue":"15","key":"2026101508222017900_cit21","doi-asserted-by":"publisher","first-page":"13507","DOI":"10.1021\/acscatal.5c03215","article-title":"Mechanism\nof Potential-Dependent CO2 Reduction and H2 Evolution during\nElectrocatalytic CO2 Process","volume":"15","author":"Fu","year":"2025","journal-title":"ACS\nCatal."},{"issue":"5","key":"2026101508222017900_cit22","doi-asserted-by":"publisher","first-page":"3596","DOI":"10.1021\/acscatal.3c05812","article-title":"Coverage-Induced\nCation Dehydration\nand Migration for Enhanced CO\u2013CO Coupling on Cu Electrocatalysts","volume":"14","author":"Yan","year":"2024","journal-title":"ACS Catal."},{"issue":"3","key":"2026101508222017900_cit23","doi-asserted-by":"publisher","first-page":"473","DOI":"10.1038\/s41557-025-01977-8","article-title":"Carbonate Anions\nand Radicals Induce\nInterfacial Water Ordering in CO2 Electroreduction on Gold","volume":"18","author":"Zhou","year":"2026","journal-title":"Nat. Chem."},{"issue":"10","key":"2026101508222017900_cit24","doi-asserted-by":"publisher","first-page":"900","DOI":"10.1038\/s41929-022-00846-8","article-title":"Hydrogen Bond Network Connectivity in the Electric\nDouble Layer Dominates the Kinetic pH Effect in Hydrogen Electrocatalysis\non Pt","volume":"5","author":"Li","year":"2022","journal-title":"Nat. Catal"},{"issue":"28","key":"2026101508222017900_cit25","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202505022","article-title":"Mechanistic Insights\ninto Cation Effects in Electrolytes for Electrocatalysis","volume":"64","author":"Wu","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"issue":"1","key":"2026101508222017900_cit26","doi-asserted-by":"publisher","first-page":"1844","DOI":"10.1038\/s41467-025-56966-9","article-title":"Kinetic Cation\nEffect in Alkaline Hydrogen Electrocatalysis and Double Layer Proton\nTransfer","volume":"16","author":"Li","year":"2025","journal-title":"Nat. Commun."},{"issue":"7","key":"2026101508222017900_cit27","doi-asserted-by":"publisher","first-page":"807","DOI":"10.1038\/s41929-024-01179-4","article-title":"Probing\nElectrolyte Effects on Cation-Enhanced CO2 Reduction on\nCopper in Acidic Media","volume":"7","author":"Zhang","year":"2024","journal-title":"Nat. Catal"},{"issue":"4","key":"2026101508222017900_cit28","doi-asserted-by":"publisher","first-page":"268","DOI":"10.1038\/s41929-022-00761-y","article-title":"Modulating Electric Field Distribution\nby Alkali Cations for CO2 Electroreduction in Strongly\nAcidic Medium","volume":"5","author":"Gu","year":"2022","journal-title":"Nat. Catal"},{"issue":"23","key":"2026101508222017900_cit29","doi-asserted-by":"publisher","first-page":"20332","DOI":"10.1021\/acscatal.5c06490","article-title":"Surface-Hydrogen Modulated\nHydrogen Bond Network Steering Two-Electron Pathways in CO2 Electroreduction on Cu Surface","volume":"15","author":"Zhang","year":"2025","journal-title":"ACS Catal."},{"issue":"48","key":"2026101508222017900_cit30","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202516799","article-title":"Tuning Microscopic\nWater Orientation in Nickel Single-Atom Catalyst for Commercial-Scale\nCO2 Electrolysis to CO","volume":"64","author":"Wen","year":"2025","journal-title":"Angew. Chem.,\nInt. Ed."},{"issue":"16","key":"2026101508222017900_cit31","doi-asserted-by":"publisher","first-page":"15962","DOI":"10.1021\/acscatal.6c03511","article-title":"Potential-Driven\nDual Effects of Cations Regulate CO2 Reduction: The Interplay\nbetween Kinetic Promotion and Steric Effects","volume":"16","author":"Wang","year":"2026","journal-title":"ACS Catal."},{"issue":"41","key":"2026101508222017900_cit32","doi-asserted-by":"publisher","first-page":"37328","DOI":"10.1021\/jacs.5c10984","article-title":"Unraveling the Molecular\nPathways\nfor Structure \u201cMaking\u201d and \u201cBreaking\u201d\nby Ions in Water","volume":"147","author":"Flor","year":"2025","journal-title":"J. Am. Chem. Soc."},{"issue":"16","key":"2026101508222017900_cit33","doi-asserted-by":"publisher","DOI":"10.1063\/1.5124878","article-title":"How Cations Affect\nthe Electric Double Layer and the Rates and Selectivity of Electrocatalytic\nProcesses","volume":"151","author":"Waegele","year":"2019","journal-title":"J. Chem. Phys."},{"issue":"33","key":"2026101508222017900_cit34","doi-asserted-by":"publisher","first-page":"30230","DOI":"10.1021\/jacs.5c08922","article-title":"In Situ\nRaman Spectroscopy Reveals\nthe Multifunctional Role of Interfacial Water in CO2-to-C2\nElectroreduction on Cu(Hkl) Surfaces","volume":"147","author":"Zhao","year":"2025","journal-title":"J. Am.\nChem. Soc."},{"issue":"8","key":"2026101508222017900_cit35","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2025.102461","article-title":"Strong Cation Concentration Effect\nof Ni\u2013N\u2013C Electrocatalysts in Accelerating Acidic CO2 Reduction Reaction","volume":"11","author":"Yun","year":"2025","journal-title":"Chem."},{"issue":"5","key":"2026101508222017900_cit36","doi-asserted-by":"publisher","first-page":"3457","DOI":"10.1021\/acscatal.3c05880","article-title":"Strong Hydrogen-Bonded\nInterfacial Water Inhibiting Hydrogen Evolution Kinetics to Promote\nElectrochemical CO2 Reduction to C2+","volume":"14","author":"Wang","year":"2024","journal-title":"ACS Catal."},{"issue":"4","key":"2026101508222017900_cit37","doi-asserted-by":"publisher","first-page":"2426","DOI":"10.1021\/jacs.3c09128","article-title":"Cation Modifies\nInterfacial Water\nStructures on Platinum during Alkaline Hydrogen Electrocatalysis","volume":"146","author":"Xu","year":"2024","journal-title":"J. Am. Chem. Soc."},{"issue":"9","key":"2026101508222017900_cit38","doi-asserted-by":"publisher","first-page":"8113","DOI":"10.1021\/acscatal.5c09283","article-title":"Geometry-Enabled\nHydrogen Bonding Alignment Dictates CO2 Electroreduction\nKinetics on Gold Facets","volume":"16","author":"Shi","year":"2026","journal-title":"ACS Catal."},{"issue":"45","key":"2026101508222017900_cit39","doi-asserted-by":"publisher","first-page":"10550","DOI":"10.1021\/acs.jpclett.2c02907","article-title":"Platinum\u2013Water Interaction Induced Interfacial Water Orientation\nThat Governs the pH-Dependent Hydrogen Oxidation Reaction","volume":"13","author":"Li","year":"2022","journal-title":"J. Phys. Chem. Lett."},{"issue":"16","key":"2026101508222017900_cit40","doi-asserted-by":"publisher","DOI":"10.1063\/5.0201751","article-title":"Cation Effects in Hydrogen Evolution\nand CO2-to-CO Conversion: A Critical Perspective","volume":"160","author":"Hsu","year":"2024","journal-title":"J. Chem. Phys."},{"issue":"18","key":"2026101508222017900_cit41","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202425590","article-title":"Water in Electrocatalysis","volume":"64","author":"Yuan","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"issue":"1","key":"2026101508222017900_cit42","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-65630-1","article-title":"Electrochemical\nPotential-Driven Water Dynamics Control\nCO2 Electroreduction at the Ag\/H2O Interface","volume":"16","author":"Tian","year":"2025","journal-title":"Nat. Commun."},{"issue":"11","key":"2026101508222017900_cit43","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202520546","article-title":"Steering Ethylene Electrosynthesis\nby Controlling Interfacial Water Orientation","volume":"65","author":"Song","year":"2026","journal-title":"Angew. Chem., Int. Ed."},{"issue":"10","key":"2026101508222017900_cit44","doi-asserted-by":"publisher","first-page":"1674","DOI":"10.1021\/jacsau.1c00281","article-title":"Cation- and pH-Dependent Hydrogen\nEvolution and Oxidation\nReaction Kinetics","volume":"1","author":"Huang","year":"2021","journal-title":"JACS Au"}],"container-title":["The Journal of Physical\nChemistry Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.jpclett.6c02653","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jpclcd\/article-pdf\/17\/41\/11947\/68672913\/acs.jpclett.6c02653.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jpclcd\/article-pdf\/17\/41\/11947\/68672913\/acs.jpclett.6c02653.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T12:30:50Z","timestamp":1792067450000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jpclcd\/article\/17\/41\/11947\/5439726\/Interfacial-Cations-Modulate-CO2-Reduction"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,28]]},"references-count":44,"journal-issue":{"issue":"41","published-online":{"date-parts":[[2026,9,28]]},"published-print":{"date-parts":[[2026,10,15]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.jpclett.6c02653","relation":{},"ISSN":["1948-7185"],"issn-type":[{"value":"1948-7185","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,28]]}}}