{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:44:48Z","timestamp":1792784688306,"version":"4.5.0"},"reference-count":44,"publisher":"American Chemical Society (ACS)","issue":"41","license":[{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100002663","name":"Northwestern Polytechnical University","doi-asserted-by":"publisher","award":["ZX2026068"],"award-info":[{"award-number":["ZX2026068"]}],"id":[{"id":"10.13039\/501100002663","id-type":"DOI","asserted-by":"publisher"}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["22379121"],"award-info":[{"award-number":["22379121"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["22579139"],"award-info":[{"award-number":["22579139"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Low-temperature-induced rigid and cage-like lithium polysulfide clusters impede the kinetics of sulfur (S) conversion. Electronic analysis reveals a charge density contrast within these structures, in which terminal S with high charge density serves as a \u201chard base\u201d to tightly bind with Li+, while the bridging S featuring low charge density acts as a \u201csoft base\u201d. This soft base would be the ideal site for lithiation-incurred bond cleavage due to low bond energy. How to further loosen the bridging S\u2013S bond and facilitate Li attack in these sites has not been studied. Guided by hard\u2013soft-acid\u2013base (HSAB) principles, this work proposes large-radius Cs+ as a \u201csoft Lewis acid\u201d (with respect to Li+) to selectively target soft bridging S sites, aiming at disrupting LiPS cluster symmetry and reducing the Mulliken bond order of bridging S\u2013S, effectively lowering the rate-determining lithiation barrier. This work highlights large-cation-mediated structural disruption as a unique strategy to regulate specific S bond cleavage for expediting lithium\u2013sulfur battery conversion kinetics at low temperature.<\/jats:p>","DOI":"10.1021\/acs.jpclett.6c03037","type":"journal-article","created":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T11:02:29Z","timestamp":1791198149000},"page":"11981-11987","source":"Crossref","is-referenced-by-count":0,"title":["Attacking Bridging\nSulfur by a Soft Cation to Disrupt\nLithium Polysulfide Clusters for Low-Temperature Lithium\u2013Sulfur\nBatteries"],"prefix":"10.1021","volume":"17","author":[{"given":"Jin-Hao","family":"Zhang","sequence":"first","affiliation":[{"name":"Northwestern Polytechnical University , , ,","place":["Xi\u2019an, China, 710129"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao-Zhong","family":"Fan","sequence":"additional","affiliation":[{"name":"Northwestern Polytechnical University , , ,","place":["Xi\u2019an, China, 710129"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Zhang","sequence":"additional","affiliation":[{"name":"Northwestern Polytechnical University , , ,","place":["Xi\u2019an, China, 710129"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao-He","family":"Zhou","sequence":"additional","affiliation":[{"name":"Northwestern Polytechnical University , , ,","place":["Xi\u2019an, China, 710129"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu-Kun","family":"Wang","sequence":"additional","affiliation":[{"name":"Northwestern Polytechnical University , , ,","place":["Xi\u2019an, China, 710129"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Na","family":"Du","sequence":"additional","affiliation":[{"name":"Northwestern Polytechnical University , , ,","place":["Xi\u2019an, China, 710129"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chen-Hao","family":"Yu","sequence":"additional","affiliation":[{"name":"Northwestern Polytechnical University , , ,","place":["Xi\u2019an, China, 710129"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5949-4637","authenticated-orcid":true,"given":"Wen-Long","family":"Cai","sequence":"additional","affiliation":[{"name":"Sichuan University , , ,","place":["Chengdu, China, 610065"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6284-9478","authenticated-orcid":true,"given":"Long","family":"Kong","sequence":"additional","affiliation":[{"name":"Northwestern Polytechnical University , , ,","place":["Xi\u2019an, China, 710129"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,5]]},"reference":[{"issue":"4","key":"2026101508213095000_cit1","doi-asserted-by":"publisher","first-page":"1330","DOI":"10.1039\/D3EE04183B","article-title":"Interface engineering\ntoward stable lithium\u2013sulfur batteries","volume":"17","author":"Guo","year":"2024","journal-title":"Energy Environ. 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