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Bis(adamantyl)-1,2-dioxetane units incorporated as cross-linkers underwent mechanoluminescent scission, demonstrating that solvent ingress caused covalent bond scission. At higher cross-linking densities, the light emission took the form of hundreds of discrete bursts, widely varying in intensity, with each burst composed of 107\u2013109 photons. Camera imaging indicated a relatively slow propagation of bursts through the material and permitted analysis of the spatial correlation between the discrete bond-breaking events. The implications of these observations for the mechanism of sorption and fracture are discussed.<\/jats:p>","DOI":"10.1021\/acs.macromol.6b02540","type":"journal-article","created":{"date-parts":[[2017,3,2]],"date-time":"2017-03-02T13:19:20Z","timestamp":1488460760000},"page":"2043-2053","source":"Crossref","is-referenced-by-count":61,"title":["Mechanoluminescent Imaging of Osmotic Stress-Induced\nDamage in a Glassy Polymer Network"],"prefix":"10.1021","volume":"50","author":[{"given":"Jess M.","family":"Clough","sequence":"first","affiliation":[{"name":"Eindhoven University of Technology , , P.O. 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