{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T14:01:52Z","timestamp":1785333712053,"version":"3.55.0"},"reference-count":59,"publisher":"American Chemical Society (ACS)","issue":"29","license":[{"start":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T00:00:00Z","timestamp":1784073600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100000089","name":"Office of International Science and Engineering","doi-asserted-by":"publisher","award":["2230706"],"award-info":[{"award-number":["2230706"]}],"id":[{"id":"10.13039\/100000089","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,7,29]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Understanding the relationship between the structural and optical properties of lead halide perovskite quantum dots (QDs) requires precise control over their composition, size, surface passivation, and morphology. Although significant progress has been made in tuning the composition and size of perovskite QDs, less attention has been given to controlling their surface morphology, especially when the QDs are size-confined. Here, we present a synthesis of monodisperse, quantum-confined CsPbBr3 QDs with carefully controlled surface morphology. The exposure of surface facets is regulated by annealing the QDs with facet-selective dicationic ligands, which are designed to match the spacing of Cs+ vacancies on specific facets. Our QDs remain morphologically stable during purification and can self-assemble via drop-casting. By monitoring the circularity indices of QDs, we reveal that the evolution of surface facet exposure during annealing is driven thermodynamically. Our straightforward synthesis approach offers an additional degree of tuning freedom for perovskite QDs.<\/jats:p>","DOI":"10.1021\/acs.nanolett.6c01367","type":"journal-article","created":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T08:39:48Z","timestamp":1784104788000},"page":"9418-9426","source":"Crossref","is-referenced-by-count":0,"title":["Controlling\nthe Surface Morphology of Strongly Confined\nCsPbBr3 Perovskite Quantum Dots"],"prefix":"10.1021","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-3199-4751","authenticated-orcid":true,"given":"Matthew L.","family":"Atteberry","sequence":"first","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chance","family":"Lander","sequence":"additional","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carly","family":"Wickizer","sequence":"additional","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-9897-968X","authenticated-orcid":true,"given":"Amila","family":"Wanasinghe","sequence":"additional","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2169-864X","authenticated-orcid":true,"given":"Chenjia","family":"Mi","sequence":"additional","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Novruz G.","family":"Akhmedov","sequence":"additional","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sisi","family":"Xiang","sequence":"additional","affiliation":[{"name":"Texas A&M University , , , ,","place":["College Station, Texas, United States, 77843"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gavin C.","family":"Gee","sequence":"additional","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Heath","family":"Hadley","sequence":"additional","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Parker H.","family":"Bryan","sequence":"additional","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9117-9568","authenticated-orcid":true,"given":"John W.","family":"Peters","sequence":"additional","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9007-5492","authenticated-orcid":true,"given":"Madalina","family":"Furis","sequence":"additional","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]},{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]},{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yihan","family":"Shao","sequence":"additional","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7069-3725","authenticated-orcid":true,"given":"Yitong","family":"Dong","sequence":"additional","affiliation":[{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]},{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]},{"name":"The University of Oklahoma , , , ,","place":["Norman, Oklahoma, United States, 73019"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,15]]},"reference":[{"issue":"6364","key":"2026072909075631900_cit1","doi-asserted-by":"publisher","first-page":"745","DOI":"10.1126\/science.aam7093","article-title":"Properties and potential optoelectronic\napplications of lead halide perovskite 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Soc. Rev."},{"issue":"4","key":"2026072909075631900_cit4","doi-asserted-by":"publisher","first-page":"203","DOI":"10.1038\/s41928-022-00745-7","article-title":"Perovskite light-emitting diodes","volume":"5","author":"Fakharuddin","year":"2022","journal-title":"Nat. Electron."},{"issue":"28","key":"2026072909075631900_cit5","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adq9002","article-title":"Ultrastable\nlasing from perovskite colloidal nanocrystals","volume":"11","author":"Li","year":"2025","journal-title":"Sci. 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Lett."},{"issue":"40","key":"2026072909075631900_cit25","doi-asserted-by":"publisher","first-page":"18629","DOI":"10.1021\/jacs.2c08639","article-title":"Facets-Directed\nEpitaxially Grown Lead Halide Perovskite-Sulfobromide Nanocrystal\nHeterostructures and Their Improved Photocatalytic Activity","volume":"144","author":"Das","year":"2022","journal-title":"J. Am. Chem. Soc."},{"issue":"2","key":"2026072909075631900_cit26","doi-asserted-by":"publisher","first-page":"278","DOI":"10.1021\/acsaom.5c00607","article-title":"Synthesis, Properties,\nand Applications of Morphology-Controlled Perovskite Quantum Dots","volume":"4","author":"Atteberry","year":"2026","journal-title":"ACS Appl. Opt. 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Abb. und ISBN 0\u20137506\u20133759\u20135","volume":"70","author":"Lacmann","year":"1998","journal-title":"Chem. Ing. Tech"},{"issue":"7","key":"2026072909075631900_cit35","doi-asserted-by":"publisher","first-page":"743","DOI":"10.1038\/nmat4889","article-title":"An intrinsic\ngrowth instability in isotropic materials leads to quasi-two-dimensional\nnanoplatelets","volume":"16","author":"Riedinger","year":"2017","journal-title":"Nat. Mater."},{"issue":"45","key":"2026072909075631900_cit36","doi-asserted-by":"publisher","first-page":"16423","DOI":"10.1021\/ja903633d","article-title":"Shape Control\nof CdSe Nanocrystals\nwith Zinc Blende Structure","volume":"131","author":"Liu","year":"2009","journal-title":"J. Am. Chem. Soc."},{"issue":"21","key":"2026072909075631900_cit37","doi-asserted-by":"publisher","first-page":"8356","DOI":"10.1039\/D2TC01144A","article-title":"Bidentate aliphatic\nquaternary ammonium ligand-stabilized CsPbBr3 perovskite nanocrystals\nwith high PLQY (92.3%) and superior stability","volume":"10","author":"Li","year":"2022","journal-title":"J. Mater. Chem. C"},{"issue":"4","key":"2026072909075631900_cit38","doi-asserted-by":"publisher","first-page":"1128","DOI":"10.1021\/acs.nanolett.2c03354","article-title":"Lead Halide Perovskite Nanocrystals with Low Inhomogeneous\nBroadening\nand High Coherent Fraction through Dicationic Ligand Engineering","volume":"23","author":"Ginterseder","year":"2023","journal-title":"Nano Lett."},{"issue":"1","key":"2026072909075631900_cit39","doi-asserted-by":"publisher","first-page":"92","DOI":"10.1021\/acsenergylett.0c02099","article-title":"Why Do Perovskite\nNanocrystals Form Nanocubes and How Can Their Facets Be Tuned? A Perspective\nfrom Synthetic Prospects","volume":"6","author":"Pradhan","year":"2021","journal-title":"ACS Energy Lett."},{"issue":"1","key":"2026072909075631900_cit40","doi-asserted-by":"publisher","first-page":"63","DOI":"10.1021\/acsenergylett.8b01669","article-title":"Rationalizing and Controlling the Surface Structure and Electronic\nPassivation of Cesium Lead Halide Nanocrystals","volume":"4","author":"Bodnarchuk","year":"2019","journal-title":"ACS Energy Lett."},{"issue":"3","key":"2026072909075631900_cit41","doi-asserted-by":"publisher","first-page":"2089","DOI":"10.1021\/acsnano.2c07677","article-title":"Strongly Confined CsPbBr3 Quantum Dots as Quantum Emitters\nand Building Blocks for\nRhombic Superlattices","volume":"17","author":"Boehme","year":"2023","journal-title":"ACS Nano"},{"issue":"22","key":"2026072909075631900_cit42","doi-asserted-by":"publisher","first-page":"8810","DOI":"10.1021\/acs.nanolett.2c02223","article-title":"Confined Excitons in Spherical-Like\nHalide Perovskite Quantum Dots","volume":"22","author":"Barfu\u0308\u00dfer","year":"2022","journal-title":"Nano Lett."},{"issue":"7","key":"2026072909075631900_cit43","doi-asserted-by":"publisher","first-page":"7359","DOI":"10.1021\/acsnano.9b05157","article-title":"Tutorial on Powder X-ray Diffraction for Characterizing\nNanoscale Materials","volume":"13","author":"Holder","year":"2019","journal-title":"ACS Nano"},{"issue":"1","key":"2026072909075631900_cit44","doi-asserted-by":"publisher","first-page":"66","DOI":"10.1021\/acs.accounts.2c00613","article-title":"Collective\nDiffraction Effects in Perovskite Nanocrystal Superlattices","volume":"56","author":"Toso","year":"2023","journal-title":"Acc. Chem. Res."},{"issue":"2","key":"2026072909075631900_cit45","doi-asserted-by":"publisher","first-page":"272","DOI":"10.1021\/acsmaterialslett.9b00217","article-title":"Wide-Angle\nX-ray Diffraction Evidence of Structural Coherence in CsPbBr3 Nanocrystal Superlattices","volume":"1","author":"Toso","year":"2019","journal-title":"ACS Matt. Lett."},{"issue":"4","key":"2026072909075631900_cit46","doi-asserted-by":"publisher","first-page":"6243","DOI":"10.1021\/acsnano.0c08929","article-title":"Multilayer Diffraction\nReveals That Colloidal Superlattices Approach the Structural Perfection\nof Single Crystals","volume":"15","author":"Toso","year":"2021","journal-title":"ACS Nano"},{"issue":"45","key":"2026072909075631900_cit47","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.add1559","article-title":"Printable assemblies of perovskite\nnanocubes on meter-scale panel","volume":"8","author":"Li","year":"2022","journal-title":"Sci. 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