{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,27]],"date-time":"2026-06-27T10:19:45Z","timestamp":1782555585800,"version":"3.54.5"},"reference-count":60,"publisher":"American Chemical Society (ACS)","issue":"23","license":[{"start":{"date-parts":[[2023,6,1]],"date-time":"2023-06-01T00:00:00Z","timestamp":1685577600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2023,6,1]],"date-time":"2023-06-01T00:00:00Z","timestamp":1685577600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2023,6,1]],"date-time":"2023-06-01T00:00:00Z","timestamp":1685577600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100018594","name":"Central University Basic Research Fund of China","doi-asserted-by":"publisher","award":["xtr072022003"],"award-info":[{"award-number":["xtr072022003"]}],"id":[{"id":"10.13039\/501100018594","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100017596","name":"Natural Science Basic Research Program of Shaanxi Province","doi-asserted-by":"publisher","award":["2021JM-003"],"award-info":[{"award-number":["2021JM-003"]}],"id":[{"id":"10.13039\/501100017596","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100017596","name":"Natural Science Basic Research Program of Shaanxi Province","doi-asserted-by":"publisher","award":["2022JQ-130"],"award-info":[{"award-number":["2022JQ-130"]}],"id":[{"id":"10.13039\/501100017596","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21971201"],"award-info":[{"award-number":["21971201"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22171220"],"award-info":[{"award-number":["22171220"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Org. Lett."],"published-print":{"date-parts":[[2023,6,16]]},"DOI":"10.1021\/acs.orglett.3c01427","type":"journal-article","created":{"date-parts":[[2023,6,1]],"date-time":"2023-06-01T20:16:11Z","timestamp":1685650571000},"page":"4329-4334","source":"Crossref","is-referenced-by-count":18,"title":["Iron-Catalyzed Alkoxyl Radical-Induced C\u2013C Bond Cleavage\/<i>gem<\/i>-Difluoroalkylation Cascade"],"prefix":"10.1021","volume":"25","author":[{"given":"Tian-Yu","family":"Zhang","sequence":"first","affiliation":[{"name":"Department of Chemistry, School of Chemistry, Xi\u2019an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi\u2019an Jiaotong University, Xi\u2019an 710049, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Chemistry, Xi\u2019an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi\u2019an Jiaotong University, Xi\u2019an 710049, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuai","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Chemistry, Xi\u2019an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi\u2019an Jiaotong University, Xi\u2019an 710049, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing-Qi","family":"Tao","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Chemistry, Xi\u2019an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi\u2019an Jiaotong University, Xi\u2019an 710049, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xu","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Electrical Engineering, Xi\u2019an Jiaotong University, Xi\u2019an 710049, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xue-Qi","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Chemistry, Xi\u2019an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi\u2019an Jiaotong University, Xi\u2019an 710049, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1527-5934","authenticated-orcid":true,"given":"Xin-Hua","family":"Duan","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Chemistry, Xi\u2019an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi\u2019an Jiaotong University, Xi\u2019an 710049, P. R. China"},{"name":"School of Electrical Engineering, Xi\u2019an Jiaotong University, Xi\u2019an 710049, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9789-6952","authenticated-orcid":true,"given":"Li-Na","family":"Guo","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Chemistry, Xi\u2019an Key Laboratory of Sustainable Energy Material Chemistry and Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi\u2019an Jiaotong University, Xi\u2019an 710049, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2023,6,1]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460441"},{"key":"ref1\/cit1b","doi-asserted-by":"publisher","DOI":"10.1126\/science.1131943"},{"key":"ref1\/cit1c","doi-asserted-by":"publisher","DOI":"10.1039\/B610213C"},{"key":"ref1\/cit1d","doi-asserted-by":"publisher","DOI":"10.1021\/cr4002879"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201200131"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.9b01877"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.1002\/slct.202202870"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201600509"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00079"},{"key":"ref3\/cit3c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00230"},{"key":"ref3\/cit3d","doi-asserted-by":"publisher","DOI":"10.1039\/D0QO00567C"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1039\/D2QO00613H"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1039\/a903681d"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-1139(01)00535-8"},{"key":"ref5\/cit5c","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC07677H"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b03213"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900745"},{"key":"ref6\/cit6c","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC00244E"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201611625"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.09.012"},{"key":"ref7\/cit7c","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202101388"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC00177G"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC05725H"},{"key":"ref8\/cit8c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c02997"},{"key":"ref8\/cit8d","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2021.07.030"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00253C"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1002\/tcr.201700090"},{"key":"ref9\/cit9c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201905218"},{"key":"ref9\/cit9d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00030"},{"key":"ref9\/cit9e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00256"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1021\/ja905110c"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b06517"},{"key":"ref10\/cit10c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b08781"},{"key":"ref10\/cit10d","doi-asserted-by":"publisher","DOI":"10.1055\/a-1545-6874"},{"key":"ref11\/cit11a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00539a041"},{"key":"ref11\/cit11b","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)89231-X"},{"key":"ref11\/cit11c","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)82245-5"},{"key":"ref11\/cit11d","doi-asserted-by":"publisher","DOI":"10.1021\/ol051854x"},{"key":"ref11\/cit11e","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202012720"},{"key":"ref11\/cit11f","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202200192"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1039\/C9QO00472F"},{"key":"ref12\/cit12b","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC04439C"},{"key":"ref12\/cit12c","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC03013B"},{"key":"ref12\/cit12d","doi-asserted-by":"publisher","DOI":"10.1039\/D1GC03230E"},{"key":"ref12\/cit12e","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC04399K"},{"key":"ref12\/cit12f","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.2c02663"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1039\/C8NP00094H"},{"key":"ref13\/cit13b","doi-asserted-by":"publisher","DOI":"10.1039\/D1CY01438B"},{"key":"ref13\/cit13c","doi-asserted-by":"publisher","DOI":"10.1039\/D0NP00087F"},{"key":"ref14\/cit14a","doi-asserted-by":"publisher","DOI":"10.1039\/D0QO01629B"},{"key":"ref14\/cit14b","doi-asserted-by":"publisher","DOI":"10.1021\/jo502501v"},{"key":"ref14\/cit0c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b00240"},{"key":"ref14\/cit0d","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c03927"},{"key":"ref15\/cit15a","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfluchem.2004.11.015"},{"key":"ref15\/cit15b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201507790"},{"key":"ref15\/cit15c","doi-asserted-by":"publisher","DOI":"10.1039\/C6OB00221H"},{"key":"ref15\/cit15d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.7b01279"},{"key":"ref15\/cit15e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b02069"},{"key":"ref15\/cit15f","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC00100J"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC06157K"}],"container-title":["Organic Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.orglett.3c01427","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.orglett.3c01427","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,6,16]],"date-time":"2023-06-16T08:42:57Z","timestamp":1686904977000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.3c01427"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,6,1]]},"references-count":60,"journal-issue":{"issue":"23","published-print":{"date-parts":[[2023,6,16]]}},"alternative-id":["10.1021\/acs.orglett.3c01427"],"URL":"https:\/\/doi.org\/10.1021\/acs.orglett.3c01427","relation":{},"ISSN":["1523-7060","1523-7052"],"issn-type":[{"value":"1523-7060","type":"print"},{"value":"1523-7052","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,6,1]]}}}