{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T01:50:35Z","timestamp":1792806635710,"version":"4.5.0"},"reference-count":67,"publisher":"American Chemical Society (ACS)","issue":"42","license":[{"start":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T00:00:00Z","timestamp":1697414400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T00:00:00Z","timestamp":1697414400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T00:00:00Z","timestamp":1697414400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001412","name":"Council of Scientific and Industrial Research, India","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001412","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["CRG\/2022\/0003261"],"award-info":[{"award-number":["CRG\/2022\/0003261"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Org. Lett."],"published-print":{"date-parts":[[2023,10,27]]},"DOI":"10.1021\/acs.orglett.3c02721","type":"journal-article","created":{"date-parts":[[2023,10,16]],"date-time":"2023-10-16T11:47:35Z","timestamp":1697456855000},"page":"7606-7611","source":"Crossref","is-referenced-by-count":20,"title":["Chiral Transient Ligand Enabled Enantioselective Synthesis of Atropisomers Decorated with Unactivated Olefins via a Palladium-Catalyzed C\u2013H Olefination"],"prefix":"10.1021","volume":"25","author":[{"given":"Vadivel","family":"Arjun","sequence":"first","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, Tamil Nadu, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7835-3928","authenticated-orcid":true,"given":"Masilamani","family":"Jeganmohan","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, Tamil Nadu, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2023,10,16]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"publisher","DOI":"10.1039\/C4NP00121D"},{"key":"ref1\/cit1b","doi-asserted-by":"publisher","DOI":"10.1021\/cr100155e"},{"key":"ref1\/cit1c","doi-asserted-by":"publisher","DOI":"10.1039\/b821092f"},{"key":"ref1\/cit1d","volume-title":"Asymmetric Catalysis in Organic Synthesis","author":"Noyori R.","year":"1994"},{"key":"ref1\/cit1e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00136"},{"key":"ref1\/cit1f","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202104278"},{"key":"ref1\/cit1g","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c13013"},{"key":"ref1\/cit1h","doi-asserted-by":"publisher","DOI":"10.1055\/s-0030-1259731"},{"key":"ref1\/cit1i","doi-asserted-by":"publisher","DOI":"10.1021\/ja900200g"},{"key":"ref1\/cit1j","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202008437"},{"key":"ref1\/cit1k","doi-asserted-by":"publisher","DOI":"10.6023\/cjoc202003057"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1021\/cr078004a"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00239K"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201911268"},{"key":"ref2\/cit2d","doi-asserted-by":"publisher","DOI":"10.1021\/cr5001496"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1021\/ja2120184"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b01860"},{"key":"ref3\/cit3c","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2543"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(97)10301-5"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1039\/p19910002737"},{"key":"ref4\/cit4c","doi-asserted-by":"publisher","DOI":"10.1248\/cpb.41.2096"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200500394"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20021202)41:23<4532::AID-ANIE4532>3.0.CO;2-5"},{"key":"ref5\/cit5c","doi-asserted-by":"publisher","DOI":"10.1021\/ja027745k"},{"key":"ref5\/cit5d","doi-asserted-by":"publisher","DOI":"10.1002\/asia.200800378"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b06009"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201901058"},{"key":"ref6\/cit6c","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC05763K"},{"key":"ref6\/cit6d","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201608150"},{"key":"ref6\/cit6e","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201811177"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1021\/ja0319442"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1126\/science.1188403"},{"key":"ref7\/cit7c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201408805"},{"key":"ref7\/cit7d","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201407865"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1039\/b816707a"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1039\/c3ra46996d"},{"key":"ref8\/cit8c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201000799"},{"key":"ref8\/cit8d","doi-asserted-by":"publisher","DOI":"10.1021\/jo400159y"},{"key":"ref8\/cit8e","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915674"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1126\/science.aad7893"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-018-0048-1"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.2c01981"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201713106"},{"key":"ref10\/cit10c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201811256"},{"key":"ref10\/cit10d","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b04870"},{"key":"ref10\/cit10e","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC06131G"},{"key":"ref10\/cit10f","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201906700"},{"key":"ref11\/cit11a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201701849"},{"key":"ref11\/cit11b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.2c02303"},{"key":"ref11\/cit11c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b02243"},{"key":"ref11\/cit11d","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202101242"},{"key":"ref11\/cit11e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b01099"},{"key":"ref11\/cit11f","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.021.202000695"},{"key":"ref11\/cit11g","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915949"},{"key":"ref11\/cit11h","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202003826"},{"key":"ref11\/cit11i","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.12.011"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1021\/ja5082734"},{"key":"ref12\/cit12b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b10309"},{"key":"ref12\/cit12c","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC05330K"},{"key":"ref12\/cit12d","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC04835H"},{"key":"ref12\/cit12e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.2c01730"},{"key":"ref12\/cit12f","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.1c03905"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC04827K"},{"key":"ref13\/cit13b","doi-asserted-by":"publisher","DOI":"10.1021\/ol102890k"},{"key":"ref13\/cit13c","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201601253"},{"key":"ref13\/cit13d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c03981"},{"key":"ref13\/cit13e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.2c01588"}],"container-title":["Organic Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.orglett.3c02721","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.orglett.3c02721","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,27]],"date-time":"2023-10-27T08:32:49Z","timestamp":1698395569000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.3c02721"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,10,16]]},"references-count":67,"journal-issue":{"issue":"42","published-print":{"date-parts":[[2023,10,27]]}},"alternative-id":["10.1021\/acs.orglett.3c02721"],"URL":"https:\/\/doi.org\/10.1021\/acs.orglett.3c02721","relation":{},"ISSN":["1523-7060","1523-7052"],"issn-type":[{"value":"1523-7060","type":"print"},{"value":"1523-7052","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,10,16]]}}}