{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T02:33:19Z","timestamp":1791685999544,"version":"4.3.4"},"reference-count":61,"publisher":"American Chemical Society (ACS)","issue":"20","license":[{"start":{"date-parts":[[2025,5,12]],"date-time":"2025-05-12T00:00:00Z","timestamp":1747008000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,5,12]],"date-time":"2025-05-12T00:00:00Z","timestamp":1747008000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,5,12]],"date-time":"2025-05-12T00:00:00Z","timestamp":1747008000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100002980","name":"Dalian University of Technology","doi-asserted-by":"publisher","award":["DUT2022TB10"],"award-info":[{"award-number":["DUT2022TB10"]}],"id":[{"id":"10.13039\/501100002980","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22071014"],"award-info":[{"award-number":["22071014"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22271040"],"award-info":[{"award-number":["22271040"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Org. Lett."],"published-print":{"date-parts":[[2025,5,23]]},"DOI":"10.1021\/acs.orglett.5c01454","type":"journal-article","created":{"date-parts":[[2025,5,12]],"date-time":"2025-05-12T12:56:03Z","timestamp":1747054563000},"page":"5247-5252","source":"Crossref","is-referenced-by-count":4,"title":["Copper-Catalyzed Defluorinative C(sp<sup>3<\/sup>)\u2013C(sp<sup>2<\/sup>) Cross-Coupling of Polyfluoroarenes with <i>gem<\/i>-Diborylalkanes"],"prefix":"10.1021","volume":"27","author":[{"given":"Xin-Li","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Chemistry","place":["Dalian, P. R. China"]},{"name":"Dalian University of Technology","place":["Dalian, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bing-Xia","family":"Yan","sequence":"additional","affiliation":[{"name":"School of Chemistry","place":["Dalian, P. R. China"]},{"name":"Dalian University of Technology","place":["Dalian, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8379-5328","authenticated-orcid":true,"given":"Zhi-Shi","family":"Ye","sequence":"additional","affiliation":[{"name":"School of Chemistry","place":["Dalian, P. R. China"]},{"name":"Dalian University of Technology","place":["Dalian, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2025,5,12]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"crossref","DOI":"10.1007\/978-3-662-04164-2","volume-title":"Organofluorine Compounds, Chemistry and Applications","author":"Hiyama T.","year":"2000"},{"key":"ref1\/cit1b","doi-asserted-by":"publisher","DOI":"10.1039\/B610213C"},{"key":"ref1\/cit1c","doi-asserted-by":"publisher","DOI":"10.1126\/science.1131943"},{"key":"ref1\/cit1d","doi-asserted-by":"publisher","DOI":"10.1039\/c0cs00221f"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1016\/S0960-894X(99)00317-0"},{"key":"ref3\/cit3","unstructured":"Cocito Armanino, N.; Charpentier, J.; Chen, C.; Ding, C.; Emter, R.; Natsch, A.; Wang, C.; Zhou, L. Preparation of Methylpiperazine, Morpholine and Related Heterocyclic Derivatives as TRMP8 Antagonists Useful as Medicaments and Agents Providing Cooling Sensation. WO 2021175971 A1, 2021."},{"key":"ref4\/cit4","unstructured":"Macielag, M. J.; Zhang, Y.M.; Decorte, B. L.; Greco, M. N.; Ludovici, D. W.; Parker, M. H. Cinnoline Derivatives Useful as CB-1 Receptor Inverse Agonists. WO 2016115013 A1, 2016."},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1021\/cr00026a005"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201206566"},{"key":"ref5\/cit5c","doi-asserted-by":"publisher","DOI":"10.1039\/C4QO00020J"},{"key":"ref5\/cit5d","doi-asserted-by":"publisher","DOI":"10.1021\/cr500366b"},{"key":"ref5\/cit5e","doi-asserted-by":"publisher","DOI":"10.1021\/cr500706a"},{"key":"ref5\/cit5f","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-016-0399-5"},{"key":"ref5\/cit5g","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201814457"},{"key":"ref5\/cit5h","doi-asserted-by":"publisher","DOI":"10.1021\/ja908434e"},{"key":"ref5\/cit5i","doi-asserted-by":"publisher","DOI":"10.1021\/ja106046p"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1021\/cr800388c"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.1039\/c0dt00540a"},{"key":"ref6\/cit6c","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2014.06.004"},{"key":"ref6\/cit6d","doi-asserted-by":"publisher","DOI":"10.1021\/cr500257c"},{"key":"ref6\/cit6e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b00692"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1021\/ja064068b"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.6b01041"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201201405"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201303451"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1021\/jo2023262"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1021\/ol303567t"},{"key":"ref9\/cit9c","doi-asserted-by":"publisher","DOI":"10.1021\/ol502499q"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202010492"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.3c00671"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC06472C"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1021\/ja105176v"},{"key":"ref12\/cit12b","doi-asserted-by":"publisher","DOI":"10.1021\/ol201115k"},{"key":"ref12\/cit12d","doi-asserted-by":"publisher","DOI":"10.1021\/ja500029w"},{"key":"ref12\/cit12e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.5b00991"},{"key":"ref12\/cit12f","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.5b01100"},{"key":"ref12\/cit12g","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201406680"},{"key":"ref12\/cit12h","doi-asserted-by":"publisher","DOI":"10.1039\/C6RA09959A"},{"key":"ref12\/cit12i","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b03979"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1039\/C7OB02978K"},{"key":"ref13\/cit13b","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201701390"},{"key":"ref13\/cit13c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00455"},{"key":"ref13\/cit13d","doi-asserted-by":"publisher","DOI":"10.1039\/D1QO01300A"},{"key":"ref13\/cit13e","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC06165E"},{"key":"ref13\/cit13f","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b03477"},{"key":"ref13\/cit13g","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201603465"},{"key":"ref13\/cit13h","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.1c04380"},{"key":"ref13\/cit13i","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b00376"},{"key":"ref13\/cit13j","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201705829"},{"key":"ref13\/cit13k","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b02931"},{"key":"ref13\/cit13l","doi-asserted-by":"publisher","DOI":"10.1021\/acs.oprd.9b00179"},{"key":"ref13\/cit13m","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201909712"},{"key":"ref13\/cit13n","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC06543A"},{"key":"ref13\/cit13o","doi-asserted-by":"publisher","DOI":"10.1039\/D1QO00632K"},{"key":"ref13\/cit13p","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.202201241"},{"key":"ref13\/cit13q","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201509840"},{"key":"ref13\/cit13r","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC00129K"},{"key":"ref13\/cit13s","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b02947"},{"key":"ref13\/cit13t","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c11750"},{"key":"ref13\/cit13u","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c14150"},{"key":"ref14\/cit14","unstructured":"Nosal, R. A.; Stealey, M. A.; Weier, R. M. N,N-Dialkyl(phenoxy)benzamide Derivatives. WO 9310077 A1, 1993."}],"container-title":["Organic Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.orglett.5c01454","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.orglett.5c01454","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,5,23]],"date-time":"2025-05-23T08:14:37Z","timestamp":1747988077000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.5c01454"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,5,12]]},"references-count":61,"journal-issue":{"issue":"20","published-print":{"date-parts":[[2025,5,23]]}},"alternative-id":["10.1021\/acs.orglett.5c01454"],"URL":"https:\/\/doi.org\/10.1021\/acs.orglett.5c01454","relation":{},"ISSN":["1523-7060","1523-7052"],"issn-type":[{"value":"1523-7060","type":"print"},{"value":"1523-7052","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,5,12]]}}}