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Sulfur dioxide, delivered from the surrogate DABSO (DABCO-bis(sulfur dioxide)), acts as the initial electrophile and combines with the first organometallic reagent to generate a sulfinate intermediate. In situ conversion of the sulfinate to a sulfinate silyl ester, using TMS-Cl (trimethylsilyl chloride), generates a second electrophile, allowing addition of a second organometallic reagent. Organolithium or Grignard reagents can be employed, delivering sulfoxides in good to excellent yields.<\/jats:p>","DOI":"10.1021\/acs.orglett.6b00712","type":"journal-article","created":{"date-parts":[[2016,4,15]],"date-time":"2016-04-15T14:07:29Z","timestamp":1460729249000},"page":"2086-2089","source":"Crossref","is-referenced-by-count":90,"title":["One-Pot Sulfoxide Synthesis Exploiting a Sulfinyl-Dication\nEquivalent Generated from a DABSO\/Trimethylsilyl Chloride Sequence"],"prefix":"10.1021","volume":"18","author":[{"given":"Danny C.","family":"Lenstra","sequence":"first","affiliation":[{"name":"University of Oxford , , Chemistry Research Laboratory, Mansfield Road , , ,","place":["Oxford, United Kingdom, OX1 3TA"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vincent","family":"Vedovato","sequence":"additional","affiliation":[{"name":"University of Oxford , , Chemistry Research Laboratory, Mansfield Road , , ,","place":["Oxford, United Kingdom, OX1 3TA"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Emmanuel","family":"Ferrer Flegeau","sequence":"additional","affiliation":[{"name":"University of Oxford , , Chemistry Research Laboratory, Mansfield Road , , ,","place":["Oxford, United Kingdom, OX1 3TA"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jonathan","family":"Maydom","sequence":"additional","affiliation":[{"name":"University of Oxford , , Chemistry Research Laboratory, Mansfield Road , , ,","place":["Oxford, United Kingdom, OX1 3TA"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael C.","family":"Willis","sequence":"additional","affiliation":[{"name":"University of Oxford , , Chemistry Research Laboratory, Mansfield Road , , ,","place":["Oxford, United Kingdom, OX1 3TA"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2016,4,15]]},"reference":[{"key":"2026090222490078500_cit1a","doi-asserted-by":"publisher","first-page":"19","DOI":"10.1002\/adsc.200404206","volume":"347","author":"Legros","year":"2005","journal-title":"Adv.\nSynth. 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