{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T14:09:08Z","timestamp":1785506948889,"version":"3.56.0"},"reference-count":47,"publisher":"American Chemical Society (ACS)","issue":"30","license":[{"start":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T00:00:00Z","timestamp":1784678400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T00:00:00Z","timestamp":1784678400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T00:00:00Z","timestamp":1784678400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100013365","name":"West China Hospital, Sichuan University","doi-asserted-by":"publisher","award":["HXQMX0092"],"award-info":[{"award-number":["HXQMX0092"]}],"id":[{"id":"10.13039\/501100013365","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,7,31]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>We report a visible-light photocatalytic, transition-metal-free methylsulfonylation\/distal (benzo)thiazolyl migration cascade of unactivated alkenes using DMSO or DMSO-d6 as methylsulfonyl or trideuteromethylsulfonyl sources. The corresponding sulfonyl radicals add selectively to the terminal alkene carbon and trigger distal migration. Mechanistic studies support hydroxyl-radical generation through a photo-Fenton-like process involving water and oxygen, without externally added hydrogen peroxide, thereby avoiding metal leaching and catalyst deactivation.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c02449","type":"journal-article","created":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T12:54:38Z","timestamp":1784724878000},"page":"9696-9701","source":"Crossref","is-referenced-by-count":0,"title":["Photo-Fenton-Like\n(Trideutero)methylsulfonylation\/Remote\n(Benzo)thiazolyl Migration Cascade of Unactivated Alkenes with DMSO(-\n                    <i>d<\/i>\n                    6)"],"prefix":"10.1021","volume":"28","author":[{"given":"Qing","family":"Liu","sequence":"first","affiliation":[{"name":"Sichuan University , , , ,","place":["Chengdu, Sichuan, P. R. 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