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Here, bench-stable \u03b2-sulfonyl sulfoxides are introduced as readily accessible sulfenate precursors that release sulfenates under mild conditions. This platform enables copper-catalyzed three-component 1,2-alkylsulfinylation and 1,2-aminosulfinylation of styrenes with a broad scope, late-stage applicability, and mechanistic evidence for radical\u2013anion crossover.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c02531","type":"journal-article","created":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T05:12:40Z","timestamp":1785129160000},"page":"9996-10002","source":"Crossref","is-referenced-by-count":0,"title":["Copper-Catalyzed\nRadical Alkyl- and Aminosulfinylation\nof Styrenes Enabled by \u03b2-Sulfonyl Sulfoxides as Sulfenate\nAnion Precursors"],"prefix":"10.1021","volume":"28","author":[{"given":"Yuxuan","family":"He","sequence":"first","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, China, 211816"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenlin","family":"Wang","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, China, 211816"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zibing","family":"Zheng","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, China, 211816"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junyu","family":"Chen","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, China, 211816"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1732-3709","authenticated-orcid":true,"given":"Yang","family":"Yang","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, China, 211816"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiyong","family":"Wang","sequence":"additional","affiliation":[{"name":"Chongqing University , , ,","place":["Chongqing, China, 401331"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4712-0088","authenticated-orcid":true,"given":"Danqing","family":"Zheng","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, China, 211816"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,25]]},"reference":[{"key":"2026080709062848800_cit1a","doi-asserted-by":"publisher","first-page":"3431","DOI":"10.6023\/cjoc202103046","article-title":"Progress on\nBiological\nActivityStudy and Enantioselective Synthesis of Sulfoxides","volume":"41","author":"Zhu","year":"2021","journal-title":"Chin. 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