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Upon Michael addition of selenols to ESF, the relatively inert sulfonyl group on ESF will become activated via intramolecular nonbonded Se\u00b7\u00b7\u00b7F interactions, which enables it to react with various O- and N-nucleophiles under mild conditions. In this reaction, the embedded selenium atom plays a dual role by promoting the latent alkyl SuFEx process through Se\u00b7\u00b7\u00b7F interaction and being retained as a valuable motif in the final products.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c02655","type":"journal-article","created":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T09:54:31Z","timestamp":1784282071000},"page":"9761-9766","source":"Crossref","is-referenced-by-count":0,"title":["Intramolecular\nNonbonded Se\u00b7\u00b7\u00b7F Interaction-Promoted\nSuFEx Click Chemistry for the Synthesis of \u03b2-Selenyl\nSulfonates and Sulfonamides"],"prefix":"10.1021","volume":"28","author":[{"given":"Lingxia","family":"Chen","sequence":"first","affiliation":[{"name":"China Agricultural University , , ,","place":["Beijing, China, 100193"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cuiping","family":"Wang","sequence":"additional","affiliation":[{"name":"China Agricultural University , , ,","place":["Beijing, China, 100193"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Siyu","family":"Huo","sequence":"additional","affiliation":[{"name":"China Agricultural University , , ,","place":["Beijing, China, 100193"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4239-6157","authenticated-orcid":true,"given":"Hainam","family":"Do","sequence":"additional","affiliation":[{"name":"University of Nottingham Ningbo China , , ,","place":["Ningbo, China, 315100"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-3189-7159","authenticated-orcid":true,"given":"Jiaman","family":"Hou","sequence":"additional","affiliation":[{"name":"China Agricultural University , , ,","place":["Beijing, China, 100193"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinshu","family":"Qin","sequence":"additional","affiliation":[{"name":"China Agricultural University , , ,","place":["Beijing, China, 100193"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minlong","family":"Wang","sequence":"additional","affiliation":[{"name":"China Agricultural University , , ,","place":["Beijing, China, 100193"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1521-009X","authenticated-orcid":true,"given":"Jie","family":"An","sequence":"additional","affiliation":[{"name":"China Agricultural University , , ,","place":["Beijing, China, 100193"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,17]]},"reference":[{"issue":"3","key":"2026073109274037100_cit1a","doi-asserted-by":"publisher","first-page":"409","DOI":"10.1016\/j.cell.2017.11.048","article-title":"Selenium Utilization\nby GPX4 Is Required to Prevent Hydroperoxide-Induced Ferroptosis","volume":"172","author":"Ingold","year":"2018","journal-title":"Cell"},{"issue":"2","key":"2026073109274037100_cit1b","doi-asserted-by":"publisher","first-page":"343","DOI":"10.1038\/s42255-024-00974-4","article-title":"Selenium Reduction\nof Ubiquinone via SQOR Suppresses Ferroptosis","volume":"6","author":"Lee","year":"2024","journal-title":"Nat. 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