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This exploits the ability of photoexcited palladium catalysts to activate C(sp3)\u2013bromides in concert with irreversible thermal reductive elimination to access substituted five-membered lactones under mild conditions, from available reagents, and where regioselectivity is defined by the substrate.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c02707","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T14:02:20Z","timestamp":1785852140000},"page":"10265-10270","source":"Crossref","is-referenced-by-count":0,"title":["Visible-Light-Driven\nPalladium-Catalyzed Cyclocarbonylative\nSynthesis of Aliphatic Lactones"],"prefix":"10.1021","volume":"28","author":[{"given":"Cuihan","family":"Zhou","sequence":"first","affiliation":[{"name":"McGill University , , 801 Sherbrooke Street West , , ,","place":["Montreal, Quebec, Canada, H3A 0B8"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-2600-9486","authenticated-orcid":true,"given":"Benjamin J.","family":"Ennifer","sequence":"additional","affiliation":[{"name":"McGill University , , 801 Sherbrooke Street West , , ,","place":["Montreal, Quebec, Canada, H3A 0B8"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4915-9261","authenticated-orcid":true,"given":"Bruce A.","family":"Arndtsen","sequence":"additional","affiliation":[{"name":"McGill University , , 801 Sherbrooke Street West , , ,","place":["Montreal, Quebec, Canada, H3A 0B8"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,30]]},"reference":[{"key":"2026081410093167700_cit1a","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-39016-6","volume-title":"Transition Metal Catalyzed\nCarbonylation Reactions: Carbonylative Activation of C\u2013X Bonds","author":"Beller","year":"2013"},{"key":"2026081410093167700_cit1b","doi-asserted-by":"publisher","first-page":"526","DOI":"10.1016\/j.chempr.2018.11.006","article-title":"The Chemistry of CO: Carbonylation","volume":"5","author":"Peng","year":"2019","journal-title":"Chem."},{"key":"2026081410093167700_cit2a","doi-asserted-by":"publisher","first-page":"3318","DOI":"10.1021\/jo00937a003","article-title":"Palladium-Catalyzed\nCarboalkoxylation of Aryl, Benzyl and Vinylic Halides","volume":"39","author":"Schoenberg","year":"1974","journal-title":"J. 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Chem."},{"key":"2026081410093167700_cit22a","doi-asserted-by":"publisher","first-page":"16841","DOI":"10.1021\/ja4098093","article-title":"A Palladium-Catalyzed\nCarbonylation Approach to Acid Chloride Synthesis","volume":"135","author":"Quesnel","year":"2013","journal-title":"J. Am. Chem. 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