{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T14:10:50Z","timestamp":1785507050274,"version":"3.56.0"},"reference-count":35,"publisher":"American Chemical Society (ACS)","issue":"30","license":[{"start":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T00:00:00Z","timestamp":1784246400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T00:00:00Z","timestamp":1784246400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T00:00:00Z","timestamp":1784246400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21761132021"],"award-info":[{"award-number":["21761132021"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,7,31]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>An electrochemical carbene radical cation-initiated dialkoxylation reaction of diazo compounds has been developed, which affords ketals as products in up to a 98% yield. The use of chloride salts enables the generation of a chlorinated intermediate that serves as the key catalytically active species in this process. Mechanistic data reveal that the reaction proceeds via anodic oxidation of diazo, coupling with chloride anion, coupling with alcohol, and substitution by alcohol to form the target ketals. Furthermore, broad substrate, mild reaction conditions, and scalability demonstrate that this process has easy access to ketals.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c02710","type":"journal-article","created":{"date-parts":[[2026,7,18]],"date-time":"2026-07-18T03:52:41Z","timestamp":1784346761000},"page":"9794-9799","source":"Crossref","is-referenced-by-count":0,"title":["Electrochemically\nChloride Anion-Mediated Dialkoxylation\nof Diazo Compounds with Alcohols Enabling Synthesis of Ketals"],"prefix":"10.1021","volume":"28","author":[{"given":"Qian","family":"Wang","sequence":"first","affiliation":[{"name":"Nanjing Forestry University , , ,","place":["Nanjing, China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jierui","family":"Deng","sequence":"additional","affiliation":[{"name":"Nanjing Forestry University , , ,","place":["Nanjing, China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2857-1935","authenticated-orcid":true,"given":"Haibo","family":"Mei","sequence":"additional","affiliation":[{"name":"Nanjing Forestry University , , ,","place":["Nanjing, China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1291-4312","authenticated-orcid":true,"given":"Ata","family":"Makarem","sequence":"additional","affiliation":[{"name":"University of Hamburg , , ,","place":["Hamburg, Germany, 22761"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3817-0764","authenticated-orcid":true,"given":"Jianlin","family":"Han","sequence":"additional","affiliation":[{"name":"Nanjing Forestry University , , ,","place":["Nanjing, China, 210037"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,17]]},"reference":[{"key":"2026073109275155300_cit1","doi-asserted-by":"publisher","first-page":"2056","DOI":"10.1002\/anie.199620561","article-title":"Protecting Group Strategies in Organic Synthesis","volume":"35","author":"Schelhaas","year":"1996","journal-title":"Angew. 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