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Amines, N-heterocycles, amides, carbamates, ureas, lactams, and cyclic ureas were converted to the corresponding N\u2013H products at room temperature without palladium catalysts or H2. The protocol exhibits broad functional-group tolerance and chemoselectively cleaves benzylic C\u2013N bonds while preserving carbonyl frameworks, enabling late-stage deprotection of densely functionalized bioactive-molecule derivatives.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c02722","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T14:34:23Z","timestamp":1785854063000},"page":"10277-10282","source":"Crossref","is-referenced-by-count":0,"title":["Electroreductive\nN-Debenzylation of Amines\nand Amide Derivatives in an Undivided Cell"],"prefix":"10.1021","volume":"28","author":[{"given":"Tianyi","family":"Zhang","sequence":"first","affiliation":[{"name":"Beijing Institute of Technology , , ,","place":["Beijing, China, 100081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Wang","sequence":"additional","affiliation":[{"name":"Beijing Institute of Technology , , ,","place":["Beijing, China, 100081"]},{"name":"Qing Yang Chemical Industry Corporation , ,","place":["Liaoyang, China, 111001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Guo","sequence":"additional","affiliation":[{"name":"Beijing Institute of Technology , , ,","place":["Beijing, China, 100081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Li","sequence":"additional","affiliation":[{"name":"Beijing Institute of Technology , , ,","place":["Beijing, China, 100081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng","family":"Han","sequence":"additional","affiliation":[{"name":"Beijing Institute of Technology , , ,","place":["Beijing, China, 100081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zihan","family":"Zhang","sequence":"additional","affiliation":[{"name":"Beijing Institute of Technology , , ,","place":["Beijing, China, 100081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weixiao","family":"Ji","sequence":"additional","affiliation":[{"name":"Beijing Institute of Technology , , ,","place":["Beijing, China, 100081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-2831-2236","authenticated-orcid":true,"given":"He","family":"Huang","sequence":"additional","affiliation":[{"name":"Beijing Institute of Technology , , ,","place":["Beijing, China, 100081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4639-7114","authenticated-orcid":true,"given":"Chenghui","family":"Sun","sequence":"additional","affiliation":[{"name":"Beijing Institute of Technology , , ,","place":["Beijing, China, 100081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Siping","family":"Pang","sequence":"additional","affiliation":[{"name":"Beijing Institute of Technology , , ,","place":["Beijing, China, 100081"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,3]]},"reference":[{"key":"2026081410090057300_cit1","doi-asserted-by":"crossref","DOI":"10.1002\/9781118905074","volume-title":"Greene\u2019s\nProtective Groups in Organic Synthesis","author":"Wuts","year":"2014","edition":"5"},{"key":"2026081410090057300_cit2","doi-asserted-by":"publisher","first-page":"263","DOI":"10.1002\/0471264180.or007.05","article-title":"Hydrogenolysis of Benzyl Groups Attached to Oxygen,\nNitrogen, or Sulfur","volume":"7","author":"Hartung","year":"1953","journal-title":"Org. 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