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Complete conversion and an 81.8% yield are attained, affording a yield rate higher than that of reported homogeneous catalysts. The synergy between the Ru\u2013Pt alloy and acid sites facilitates coplanar adsorption of the electron-rich phenol ring in 2-naphthol via dual hydrogen bonds. Meanwhile, the alloy promotes H2 adsorption and dissociation at bridge sites, directing hydrogenation preferentially to the lower-energy benzene ring in 2-naphthol.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c02730","type":"journal-article","created":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T06:01:45Z","timestamp":1786514505000},"page":"10714-10718","source":"Crossref","is-referenced-by-count":0,"title":["Unlocking Room-Temperature\nSelective Hydrogenation\nof 2-Naphthol: Coplanar Adsorption of the Substituted Ring\nGoverns Stepwise Addition of Active Hydrogen toward the Unsubstituted\nRing"],"prefix":"10.1021","volume":"28","author":[{"given":"Weixing","family":"Ming","sequence":"first","affiliation":[{"name":"Shenyang University of Technology , , ,","place":["Shenyang, P. R. China, 110870"]},{"name":"Shenyang University of Technology , , ,","place":["Shenyang, P. R. 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