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Herein, we report an orthogonal strategy for the decyanative borylation of dicyanoarenes via radical\u2013radical coupling between amine-ligated boryl radicals and dicyanoarene-derived radical anions, enabled by an oxidative quenching photoredox cycle. Importantly, the resulting amine\u2013borane adducts readily engage in Suzuki\u2013Miyaura cross-couplings with aryl halides, including late-stage functionalization of bioactive compounds.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c02736","type":"journal-article","created":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T13:37:31Z","timestamp":1785159451000},"page":"10022-10027","source":"Crossref","is-referenced-by-count":1,"title":["Photocatalytic\nDecyanative Borylation of Dicyanoarenes\nEnabled by Radical\u2013Radical Coupling"],"prefix":"10.1021","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7994-0470","authenticated-orcid":true,"given":"Naoki","family":"Yasukawa","sequence":"first","affiliation":[{"name":"Nagoya Institute of Technology , , Gokiso, Showa-ku , , ,","place":["Nagoya, Aichi, Japan, 466-8555"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ryota","family":"Nomura","sequence":"additional","affiliation":[{"name":"Nagoya Institute of Technology , , Gokiso, Showa-ku , , ,","place":["Nagoya, Aichi, Japan, 466-8555"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Waka","family":"Okada","sequence":"additional","affiliation":[{"name":"Nagoya Institute of Technology , , Gokiso, Showa-ku , , ,","place":["Nagoya, Aichi, Japan, 466-8555"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kazutake","family":"Takada","sequence":"additional","affiliation":[{"name":"Nagoya Institute of Technology , , Gokiso, Showa-ku , , ,","place":["Nagoya, Aichi, Japan, 466-8555"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4113-7578","authenticated-orcid":true,"given":"Tsunayoshi","family":"Takehara","sequence":"additional","affiliation":[{"name":"Osaka University , , 8-1 Mihogaoka, Ibaraki-shi , ,","place":["Osaka, Japan, 567-0047"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2137-0276","authenticated-orcid":true,"given":"Takeyuki","family":"Suzuki","sequence":"additional","affiliation":[{"name":"Osaka University , , 8-1 Mihogaoka, Ibaraki-shi , ,","place":["Osaka, Japan, 567-0047"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7692-4504","authenticated-orcid":true,"given":"Daniele","family":"Leonori","sequence":"additional","affiliation":[{"name":"RWTH Aachen University , , Landoltweg 1 , ,","place":["Aachen, Germany, 52056"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5633-8367","authenticated-orcid":true,"given":"Shuichi","family":"Nakamura","sequence":"additional","affiliation":[{"name":"Nagoya Institute of Technology , , Gokiso, Showa-ku , , ,","place":["Nagoya, Aichi, Japan, 466-8555"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,27]]},"reference":[{"key":"2026080709074902900_cit1a","doi-asserted-by":"crossref","first-page":"355","DOI":"10.1002\/9783527805624.ch8","article-title":"Acetonitrile as Reagents in Organic Synthesis: Reactions and Applications","volume-title":"Solvents as Reagents in Organic Synthesis: Reactions\nand Applications","author":"Wang","year":"2017"},{"key":"2026080709074902900_cit1b","doi-asserted-by":"publisher","first-page":"13170","DOI":"10.1002\/anie.201502493","article-title":"Cyanoalkylation: Alkylnitriles in Catalytic C-C Bond-Forming\nReactions","volume":"54","author":"Lo\u0301pez","year":"2015","journal-title":"Angew. 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A"},{"key":"2026080709074902900_cit23","doi-asserted-by":"publisher","first-page":"13818","DOI":"10.1021\/acs.joc.3c00490","article-title":"Photoredox\nProduct Selectivity Controlled by Persistent Radical Stability","volume":"89","author":"Stevenson","year":"2024","journal-title":"J. Org. 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