{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T14:28:13Z","timestamp":1788532093120,"version":"build-2803163510"},"reference-count":57,"publisher":"American Chemical Society (ACS)","issue":"35","license":[{"start":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T00:00:00Z","timestamp":1787529600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T00:00:00Z","timestamp":1787529600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T00:00:00Z","timestamp":1787529600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22078153"],"award-info":[{"award-number":["22078153"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"State Key Laboratory of Fine Chemicals, Dalian University of Technology","award":["KF2210"],"award-info":[{"award-number":["KF2210"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,4]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The \u03b1-alkylation of ketones with bio-based 2,5-furandimethanol via a hydrogen autotransfer process has been realized. In the presence of [Cp*Ir(2,2\u2032-bpyO)(OH2)] (0.5 mol %) and Cs2CO3 (0.2 equiv), a range of products were obtained with excellent selectivity. Functional groups in the bpy ligand play a crucial role in the catalytic activity of iridium complexes. DFT calculations and mechanistic expriements were performed. Furthermore, the synthesis of an aromatic compound from bio-based 2,5-furandimethanol and the \u03b1-alkylation of ketones with bio-based furfuryl alcohols were successfully accomplished.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c02882","type":"journal-article","created":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T21:16:18Z","timestamp":1788210978000},"page":"10942-10948","source":"Crossref","is-referenced-by-count":0,"title":["\u03b1-Alkylation\nof Ketones with Bio-Based\n2,5-Furandimethanol via a Hydrogen Autotransfer Process Catalyzed\nby a Metal\u2013Ligand Bifunctional Iridium Catalyst"],"prefix":"10.1021","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-5013-4730","authenticated-orcid":true,"given":"Beixuan","family":"Dong","sequence":"first","affiliation":[{"name":"Nanjing University of Science & Technology , , ,","place":["Nanjing, P. R. China, 210094"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiqian","family":"He","sequence":"additional","affiliation":[{"name":"Nanjing University of Science & Technology , , ,","place":["Nanjing, P. R. China, 210094"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinci","family":"Liang","sequence":"additional","affiliation":[{"name":"Nanjing University of Science & Technology , , ,","place":["Nanjing, P. R. China, 210094"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Wu","sequence":"additional","affiliation":[{"name":"Nanjing University of Science & Technology , , ,","place":["Nanjing, P. R. China, 210094"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liangshun","family":"Guo","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, P. R. China, 211816"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4924-831X","authenticated-orcid":true,"given":"Qixun","family":"Shi","sequence":"additional","affiliation":[{"name":"Nanjing Tech University , , ,","place":["Nanjing, P. R. China, 211816"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3288-4069","authenticated-orcid":true,"given":"Feng","family":"Li","sequence":"additional","affiliation":[{"name":"Nanjing University of Science & Technology , , ,","place":["Nanjing, P. R. China, 210094"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,24]]},"reference":[{"key":"2026090409092841100_cit1a","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1002\/9781118596784.ssd007","article-title":"Asymmetric \u03b1-Alkylation of Aldehydes, Ketones, and Carboxylic\nAcids","volume-title":"Stereoselective Synthesis of Drugs\nand Natural Products","author":"Kohler","year":"2013"},{"key":"2026090409092841100_cit1b","doi-asserted-by":"publisher","first-page":"9196","DOI":"10.1021\/acs.chemrev.0c00564","article-title":"Catalytic Enantioselective Alkylation\nof Prochiral Enolates","volume":"121","author":"Wright","year":"2021","journal-title":"Chem. Rev."},{"key":"2026090409092841100_cit2","doi-asserted-by":"crossref","DOI":"10.1002\/9783527613267","volume-title":"Modern Carbonyl\nChemistry","author":"Otera","year":"2000"},{"key":"2026090409092841100_cit3a","doi-asserted-by":"publisher","first-page":"681","DOI":"10.1021\/cr900202j","article-title":"Dehydrogenation as a Substrate-Activating Strategy\nin Homogeneous Transition-Metal Catalysis","volume":"110","author":"Dobereiner","year":"2010","journal-title":"Chem.\nRev."},{"key":"2026090409092841100_cit3b","doi-asserted-by":"publisher","first-page":"1611","DOI":"10.1021\/cr9002159","article-title":"Hydrogen Autotransfer\nin the N-Alkylation of Amines and Related Compounds Using Alcohols\nand Amines as Electrophiles","volume":"110","author":"Guillena","year":"2010","journal-title":"Chem. Rev."},{"key":"2026090409092841100_cit3c","doi-asserted-by":"publisher","first-page":"1410","DOI":"10.1021\/acs.chemrev.7b00340","article-title":"Advances in One-Pot\nSynthesis through Borrowing Hydrogen Catalysis","volume":"118","author":"Corma","year":"2018","journal-title":"Chem. Rev."},{"key":"2026090409092841100_cit3d","doi-asserted-by":"publisher","first-page":"2524","DOI":"10.1021\/acs.chemrev.8b00306","article-title":"3d-Metal Catalyzed\nN- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer","volume":"119","author":"Irrgang","year":"2019","journal-title":"Chem. Rev."},{"key":"2026090409092841100_cit4a","doi-asserted-by":"publisher","first-page":"4703","DOI":"10.1021\/ol302145a","article-title":"RuHCl(CO)(PPh3)3-Catalyzed \u03b1-Alkylation of Ketones with Primary\nAlcohols","volume":"14","author":"Kuwahara","year":"2012","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit4b","doi-asserted-by":"publisher","first-page":"4184","DOI":"10.1021\/acscatal.6b01351","article-title":"Ruthenium-NHC Catalyzed \u03b1-Alkylation of Methylene Ketones Provides Branched\nProducts through Borrowing Hydrogen Strategy","volume":"6","author":"Schlepphorst","year":"2016","journal-title":"ACS Catal."},{"key":"2026090409092841100_cit4c","doi-asserted-by":"publisher","first-page":"7879","DOI":"10.1021\/acs.orglett.0c02787","article-title":"Ruthenium-Catalyzed a-Alkylation of Ketones Using Secondary Alcohols to \u03b2-Disubstituted Ketones","volume":"22","author":"Thiyagarajan","year":"2020","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit5a","doi-asserted-by":"publisher","first-page":"72","DOI":"10.1021\/ja037552c","article-title":"An Efficient Direct \u03b1-Alkylation of Ketones\nwith Primary Alcohols Catalyzed by [Ir(cod)Cl]2\/PPh3\/KOH System without Solvent","volume":"126","author":"Taguchi","year":"2004","journal-title":"J. Am.\nChem. Soc."},{"key":"2026090409092841100_cit5b","doi-asserted-by":"publisher","first-page":"3819","DOI":"10.1002\/anie.200600677","article-title":"Ir- and Ru-Catalyzed Sequential Reactions: Asymmetric \u03b1-Alkylative Reduction of Ketones with Alcohols","volume":"45","author":"Onodera","year":"2006","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090409092841100_cit5c","doi-asserted-by":"publisher","first-page":"10447","DOI":"10.1021\/jo502051d","article-title":"\u03b1-Alkylation of Ketones with\nPrimary Alcohols Catalyzed by a Cp*Ir Complex Bearing a Functional\nBipyridonate Ligand","volume":"79","author":"Li","year":"2014","journal-title":"J. Org. Chem."},{"key":"2026090409092841100_cit5d","doi-asserted-by":"publisher","first-page":"2875","DOI":"10.1021\/acs.joc.8b00043","article-title":"Iridium(I)-Catalyzed Alkylation Reactions\nto Form \u03b1-Alkylated Ketones","volume":"83","author":"Genc","year":"2018","journal-title":"J. Org. Chem."},{"key":"2026090409092841100_cit6a","doi-asserted-by":"publisher","first-page":"6913","DOI":"10.1002\/anie.200502422","article-title":"Recyclable Palladium Catalyst for Highly Selective a Alkylation of\nKetones with Alcohols","volume":"44","author":"Kwon","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090409092841100_cit6b","doi-asserted-by":"publisher","first-page":"1375","DOI":"10.1021\/ol060166q","article-title":"Solid-Phase Self-Organized Catalyst\nof Nanopalladium with Main-Chain Viologen Polymers: \u03b1-Alkylation of Ketones with Primary Alcohols","volume":"8","author":"Yamada","year":"2006","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit6c","doi-asserted-by":"publisher","first-page":"9683","DOI":"10.1021\/acssuschemeng.7b00789","article-title":"Supported Palladium Nanoparticle Catalyzed \u03b1-Alkylation of Ketones Using Alcohols as Alkylating Agents","volume":"5","author":"Reddy","year":"2017","journal-title":"ACS Sustainable Chem. Eng."},{"key":"2026090409092841100_cit7a","doi-asserted-by":"publisher","first-page":"10786","DOI":"10.1021\/jacs.6b06448","article-title":"General and Mild Cobalt-Catalyzed\nC-Alkylation of Unactivated Amides\nand Esters with Alcohols","volume":"138","author":"Deibl","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"2026090409092841100_cit7b","doi-asserted-by":"publisher","first-page":"1080","DOI":"10.1021\/acs.orglett.7b00106","article-title":"Cobalt-Catalyzed \u03b1-Alkylation\nof Ketones with Primary Alcohols","volume":"19","author":"Zhang","year":"2017","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit8a","doi-asserted-by":"publisher","first-page":"14483","DOI":"10.1002\/anie.201506698","article-title":"Iron-Catalyzed \u03b1-Alkylation of Ketones with Alcohols","volume":"54","author":"Elangovan","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090409092841100_cit8b","doi-asserted-by":"publisher","first-page":"11676","DOI":"10.1021\/acs.joc.9b01600","article-title":"Iron-Catalyzed Ligand Free \u03b1-Alkylation of Methylene Ketones and \u03b2-Alkylation of Secondary Alcohols Using Primary Alcohols","volume":"84","author":"Alanthadka","year":"2019","journal-title":"J. Org. Chem."},{"key":"2026090409092841100_cit8c","doi-asserted-by":"publisher","first-page":"2064","DOI":"10.1021\/acs.orglett.0c00549","article-title":"Iron-Catalyzed \u03b1-Alkylation of Ketones with Secondary Alcohols: Access to \u03b2-Disubstituted Carbonyl Compounds","volume":"22","author":"Bettoni","year":"2020","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit9","doi-asserted-by":"publisher","first-page":"2072","DOI":"10.1021\/cs4005375","article-title":"Osmium Catalyst for the Borrowing\nHydrogen Methodology: \u03b1-Alkylation of Arylacetonitriles\nand Methyl Ketones","volume":"3","author":"Buil","year":"2013","journal-title":"ACS Catal."},{"key":"2026090409092841100_cit10a","doi-asserted-by":"publisher","first-page":"5587","DOI":"10.1021\/acs.orglett.8b02256","article-title":"Nickel-Catalyzed Hydrogen-Borrowing\nStrategy for \u03b1-Alkylation of Ketones with Alcohols:\nA New Route to Branched gem-Bis(alkyl) Ketones","volume":"20","author":"Das","year":"2018","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit10b","doi-asserted-by":"publisher","first-page":"769","DOI":"10.1021\/acs.joc.8b02609","article-title":"Nickel-Catalyzed Alkylation of Ketone Enolates: Synthesis\nof Monoselective Linear Ketones","volume":"84","author":"Das","year":"2019","journal-title":"J. Org. Chem."},{"key":"2026090409092841100_cit11a","doi-asserted-by":"publisher","first-page":"14967","DOI":"10.1002\/anie.201607072","article-title":"Manganese-Catalyzed Hydrogen-Autotransfer\nC-C Bond Formation: \u03b1-Alkylation of Ketones\nwith Primary Alcohols","volume":"55","author":"Pena-Lopez","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090409092841100_cit11b","doi-asserted-by":"publisher","first-page":"10300","DOI":"10.1021\/acscatal.8b03720","article-title":"Manganese-Catalyzed \u03b1-Alkylation\nof Ketones, Esters, and Amides Using Alcohols","volume":"8","author":"Chakraborty","year":"2018","journal-title":"ACS Catal."},{"key":"2026090409092841100_cit11c","doi-asserted-by":"publisher","first-page":"8065","DOI":"10.1021\/acs.orglett.9b03030","article-title":"Nonbifunctional Outer-Sphere Strategy\nAchieved Highly Active \u03b1-Alkylation of Ketones\nwith Alcohols by N-Heterocyclic Carbene Manganese (NHC-Mn)","volume":"21","author":"Lan","year":"2019","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit12a","doi-asserted-by":"publisher","first-page":"505","DOI":"10.1021\/acs.chemrev.7b00395","article-title":"Catalytic\nConversion of Carbohydrates to Initial Platform Chemicals: Chemistry\nand Sustainability","volume":"118","author":"Mika","year":"2018","journal-title":"Chem. Rev."},{"key":"2026090409092841100_cit12b","doi-asserted-by":"publisher","first-page":"7219","DOI":"10.1021\/acs.chemrev.9b00846","article-title":"Continuous Flow Upgrading of Selected\nC2-C6 Platform Chemicals Derived from Biomass","volume":"120","author":"Ge\u0301rardy","year":"2020","journal-title":"Chem. Rev."},{"key":"2026090409092841100_cit12c","doi-asserted-by":"publisher","first-page":"2889","DOI":"10.1021\/acs.chemrev.2c00756","article-title":"Production of Renewable\nHydrocarbon Biofuels with Lignocellulose and Its Derivatives over\nHeterogeneous Catalysts","volume":"124","author":"Li","year":"2024","journal-title":"Chem. Rev."},{"key":"2026090409092841100_cit13a","doi-asserted-by":"publisher","first-page":"1499","DOI":"10.1021\/cr300182k","article-title":"Hydroxymethylfurfural,\na Versatile\nPlatform Chemical Made from Renewable Resources","volume":"113","author":"van Putten","year":"2013","journal-title":"Chem. Rev."},{"key":"2026090409092841100_cit13b","doi-asserted-by":"publisher","first-page":"11023","DOI":"10.1021\/acs.chemrev.8b00134","article-title":"How Catalysts and Experimental\nConditions Determine the Selective Hydroconversion of Furfural and\n5-Hydroxymethylfurfural","volume":"118","author":"Chen","year":"2018","journal-title":"Chem. Rev."},{"key":"2026090409092841100_cit14a","doi-asserted-by":"publisher","first-page":"3643","DOI":"10.1021\/ja210857z","article-title":"Dehydrogenative\nOxidation of Alcohols in Aqueous Media Using Water-Soluble and Reusable\nCp*Ir Catalysts Bearing a Functional Bipyridine Ligand","volume":"134","author":"Kawahara","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"2026090409092841100_cit14b","doi-asserted-by":"publisher","first-page":"12790","DOI":"10.1002\/anie.201206987","article-title":"Cooperative Catalysis by Iridium\nComplexes with a Bipyridonate Ligand: Versatile Dehydrogenative Oxidation\nof Alcohols and Reversible Dehydrogenation\u2013Hydrogenation between\n2-Propanol and Acetone","volume":"51","author":"Kawahara","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090409092841100_cit14c","doi-asserted-by":"publisher","first-page":"10886","DOI":"10.1002\/anie.201705452","article-title":"Reversible\nInterconversion between 2,5-Dimethylpyrazine and 2,5-Dimethylpiperazine\nby Iridium-Catalyzed Hydrogenation\/Dehydrogenation for Efficient Hydrogen\nStorage","volume":"56","author":"Fujita","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090409092841100_cit15a","doi-asserted-by":"publisher","first-page":"9057","DOI":"10.1002\/anie.201502194","article-title":"Hydrogen Production from a Methanol\u2013Water Solution\nCatalyzed by an Anionic Iridium Complex Bearing a Functional Bipyridonate\nLigand under Weakly Basic Conditions","volume":"54","author":"Fujita","year":"2015","journal-title":"Angew.\nChem., Int. Ed."},{"key":"2026090409092841100_cit15b","doi-asserted-by":"publisher","first-page":"3820","DOI":"10.1002\/cssc.202001052","article-title":"Synthesis of Dicarboxylic Acids from\nAqueous Solutions of Diols with Hydrogen Evolution Catalyzed by an\nIridium Complex","volume":"13","author":"Toyooka","year":"2020","journal-title":"ChemSusChem"},{"key":"2026090409092841100_cit16a","doi-asserted-by":"publisher","first-page":"447","DOI":"10.1002\/adsc.201300711","article-title":"The N-Alkylation of Sulfonamides with Alcohols in Water Catalyzed\nby the Water-Soluble Iridium Complex {Cp*Ir[6,6\u2019-(OH)2bpy](H2O)}[OTf]2","volume":"356","author":"Qu","year":"2014","journal-title":"Adv.\nSynth. Catal."},{"key":"2026090409092841100_cit16b","doi-asserted-by":"publisher","first-page":"9081","DOI":"10.1021\/acs.orglett.2c03719","article-title":"Autotandem Catalyst: from Acylhydrazones to N\u2019,N\u2019-Methylaliphatic\nAcylhydrazides via Transfer Hydrogenation\/N-Methylation\nwith Methanol Catalyzed by a Cp* Iridium Complex Bearing a Functional\nLigand","volume":"24","author":"Luo","year":"2022","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit16c","doi-asserted-by":"publisher","first-page":"6291","DOI":"10.1021\/acs.orglett.5c01338","article-title":"Direct Synthesis of \u03b1-Methylated\nArylacetamides from Arylacetonitriles via Ir-Catalyzed\nCascade \u03b1-Methylation and Selective Hydration","volume":"27","author":"Liu","year":"2025","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit17a","doi-asserted-by":"publisher","first-page":"2580","DOI":"10.1021\/acs.orglett.6b00925","article-title":"Acceptorless\nDehydrogenative Coupling of o-Aminobenzamides with\nthe Activation of Methanol as a C1 Source for the Construction of\nQuinazolinones","volume":"18","author":"Li","year":"2016","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit17b","doi-asserted-by":"publisher","first-page":"3558","DOI":"10.1021\/acs.orglett.6b01518","article-title":"Acceptorless\nDehydrogenative Cyclization of o-Aminobenzyl Alcohols\nwith Ketones to Quinolines in Water Catalyzed by Water-Soluble Metal\u2013Ligand\nBifunctional Catalyst [Cp*(6,6\u2019-(OH)2bpy)(H2O)][OTf]2","volume":"18","author":"Wang","year":"2016","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit18a","doi-asserted-by":"publisher","first-page":"1857","DOI":"10.1021\/acs.orglett.4c00064","article-title":"Hydrogenation of Quinones to Hydroquinones\nunder Atmospheric Pressure Catalyzed by a Metal\u2013Ligand Bifunctional\nIridium Catalyst","volume":"26","author":"Zhang","year":"2024","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit18b","doi-asserted-by":"publisher","first-page":"948","DOI":"10.1021\/acs.orglett.5c04893","article-title":"Hydrogenation of Fluoroalkyl Ketones\non Water under Atmospheric Pressure Catalyzed by a Water-Soluble Metal\u2013Ligand\nBifunctional Iridium Catalyst","volume":"28","author":"Wang","year":"2026","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit18c","doi-asserted-by":"publisher","first-page":"5706","DOI":"10.1021\/acs.inorgchem.5c06007","article-title":"Chemoselective Hydrogenation of Nitroalkenes\nto Nitroalkanes on Water under Atmospheric Pressure Catalyzed by a\nWater-Soluble Metal\u2013Ligand Bifunctional Iridium Catalyst","volume":"65","author":"Liang","year":"2026","journal-title":"Inorg. Chem."},{"key":"2026090409092841100_cit19a","doi-asserted-by":"publisher","first-page":"5790","DOI":"10.1021\/acs.orglett.7b02723","article-title":"N-Methylation of Amines with Methanol Catalyzed by\na Cp*Ir Complex Bearing a Functional 2,2\u2019-Bibenzimidazole Ligand","volume":"19","author":"Liang","year":"2017","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit19b","doi-asserted-by":"publisher","first-page":"15072","DOI":"10.1021\/acs.inorgchem.4c02053","article-title":"Poly(2,2\u2019-Bibenzimidazole)-Supported\nIridium Complex: A Recyclable Metal\u2013Polymer Ligand Bifunctional\nCatalyst for the N-Methylation of Amines with Methanol","volume":"63","author":"Dong","year":"2024","journal-title":"Inorg. Chem."},{"key":"2026090409092841100_cit19c","doi-asserted-by":"publisher","first-page":"7020","DOI":"10.1021\/acs.orglett.5c01929","article-title":"Hyper-Cross-Linked Polymer Bearing Functional Ligands\u2013Supported\nIridium Complex: A Recyclable Metal\u2013Polymer Ligand Bifunctional\nCatalyst for the N-Trideuteromethylation of Amines\nwith Deuterated Methanol","volume":"27","author":"Chen","year":"2025","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit20a","doi-asserted-by":"publisher","first-page":"725","DOI":"10.1021\/acssuschemeng.4c08606","article-title":"Reductive Amination of 2,5-Furandicarbaldehyde\nto N,N\u2019-Disubstituted 2,5-Bis(aminomethyl)furan under Atmospheric\nPressure of Hydrogen Gas Catalyzed by a Metal\u2013Ligand Bifunctional\nIridium Catalyst","volume":"13","author":"You","year":"2025","journal-title":"ACS Sustainable Chem. Eng."},{"key":"2026090409092841100_cit20b","doi-asserted-by":"publisher","first-page":"15129","DOI":"10.1021\/acs.inorgchem.5c02121","article-title":"N-Alkylation of Amines\nwith 2,5-Furandimethanol to N,N\u2019-Disubstituted 2,5-Bis(aminomethyl)furans\nCatalyzed by a Metal\u2013Ligand Bifunctional Iridium Catalyst","volume":"64","author":"Dong","year":"2025","journal-title":"Inorg. Chem."},{"key":"2026090409092841100_cit20c","doi-asserted-by":"publisher","first-page":"13281","DOI":"10.1021\/acs.orglett.5c04285","article-title":"Chemoselectively Atmospheric Hydrogenation\nof Two C = C bonds of \u03b1,\u03b2-Unsaturated\nDiketones Derived from Bio-Based 5-HMF Catalyzed by a Metal\u2013Ligand\nBifunctional Iridium Catalyst","volume":"27","author":"Dong","year":"2025","journal-title":"Org. Lett."},{"key":"2026090409092841100_cit21","doi-asserted-by":"publisher","first-page":"2278","DOI":"10.1021\/ol2005424","article-title":"Dehydrogenative\nOxidation of Primary and Secondary Alcohols Catalyzed by a Cp*Ir Complex\nHaving a Functional C,N-Chelate Ligand","volume":"13","author":"Fujita","year":"2011","journal-title":"Org.\nLett."},{"key":"2026090409092841100_cit22a","doi-asserted-by":"publisher","first-page":"2294","DOI":"10.1021\/cr9003133","article-title":"Discovery, Applications, and Catalytic Mechanisms of\nShvo\u2019s Catalyst","volume":"110","author":"Conley","year":"2010","journal-title":"Chem. Rev."},{"key":"2026090409092841100_cit22b","doi-asserted-by":"publisher","first-page":"1300","DOI":"10.1021\/ar700134q","article-title":"Asymmetric Transfer Hydrogenation\nof Ketones with Bifunctional Transition Metal-Based Molecular Catalysts","volume":"40","author":"Ikariya","year":"2007","journal-title":"Acc. Chem. Res."},{"key":"2026090409092841100_cit23a","doi-asserted-by":"publisher","first-page":"3011","DOI":"10.1021\/acssuschemeng.0c09229","article-title":"Biobased C6-Furans\nin Organic Synthesis and Industry:\nCycloaddition Chemistry as a Key Approach to Aromatic Building Blocks","volume":"9","author":"Kucherov","year":"2021","journal-title":"ACS Sustainable Chem. Eng."},{"key":"2026090409092841100_cit23b","doi-asserted-by":"publisher","first-page":"10701","DOI":"10.1021\/acs.chemrev.4c00087","article-title":"Benzenoid Aromatics\nfrom Renewable Resources","volume":"124","author":"Zheng","year":"2024","journal-title":"Chem. Rev."}],"container-title":["Organic Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.orglett.6c02882","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/orlef7\/article-pdf\/28\/35\/10942\/67392458\/acs.orglett.6c02882.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/orlef7\/article-pdf\/28\/35\/10942\/67392458\/acs.orglett.6c02882.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T14:05:25Z","timestamp":1788530725000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/orlef7\/article\/28\/35\/10942\/5328197\/Alkylation-of-Ketones-with-Bio-Based-2-5"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,24]]},"references-count":57,"journal-issue":{"issue":"35","published-online":{"date-parts":[[2026,8,24]]},"published-print":{"date-parts":[[2026,9,4]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.orglett.6c02882","relation":{},"ISSN":["1523-7060","1523-7052"],"issn-type":[{"value":"1523-7060","type":"print"},{"value":"1523-7052","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,24]]}}}