{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T15:28:08Z","timestamp":1786721288292,"version":"build-2736575974"},"reference-count":55,"publisher":"American Chemical Society (ACS)","issue":"32","license":[{"start":{"date-parts":[[2026,8,2]],"date-time":"2026-08-02T00:00:00Z","timestamp":1785628800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,2]],"date-time":"2026-08-02T00:00:00Z","timestamp":1785628800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,2]],"date-time":"2026-08-02T00:00:00Z","timestamp":1785628800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22571018"],"award-info":[{"award-number":["22571018"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22571021"],"award-info":[{"award-number":["22571021"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,14]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Chiral sulfoxides serve as pivotal precursors for the synthesis of organic sulfides and hold significant application value in the biomedicine and organic synthesis. This work describes a Rh\/(S,S)-f-spiroPhos-catalyzed asymmetric hydrogenation enabling highly efficient kinetic resolution of racemic \u03b1,\u03b2-unsaturated sulfoxides. By this strategy, a series of multisubstituted vinyl chiral sulfoxides with only sulfur chiral centers and chiral sulfoxides bearing both carbon and sulfur chiral centers can be simultaneously afforded with excellent diastereoselectivities and enantioselectivities (up to &amp;gt;20:1 dr, 99% ee). The selectivity factor (s) reaches up to 1057. Furthermore, the resulting hydrogenation products can be readily transformed into chiral sulfones, chiral thioethers and chiral sulfonamides without any erosion of ee values under mild conditions.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c02887","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T14:33:00Z","timestamp":1785853980000},"page":"10347-10352","source":"Crossref","is-referenced-by-count":0,"title":["Kinetic Resolution of \u03b1,\u03b2-Unsaturated\nSulfoxides via Rh-Catalyzed Asymmetric Hydrogenation"],"prefix":"10.1021","volume":"28","author":[{"given":"Fei","family":"Xing","sequence":"first","affiliation":[{"name":"Beijing Normal University , , ,","place":["Beijing, China, 100875"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingling","family":"Ou","sequence":"additional","affiliation":[{"name":"Beijing Normal University , , ,","place":["Beijing, China, 100875"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7455-460X","authenticated-orcid":true,"given":"Guofu","family":"Zi","sequence":"additional","affiliation":[{"name":"Beijing Normal University , , ,","place":["Beijing, China, 100875"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuping","family":"Huang","sequence":"additional","affiliation":[{"name":"SINOPEC , , ,","place":["Beijing, China, 100083"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3571-456X","authenticated-orcid":true,"given":"Guohua","family":"Hou","sequence":"additional","affiliation":[{"name":"Beijing Normal University , , ,","place":["Beijing, China, 100875"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,2]]},"reference":[{"key":"2026081410095881000_cit1a","doi-asserted-by":"publisher","first-page":"3651","DOI":"10.1021\/cr990372u","article-title":"Recent Developments\nin the Synthesis and Utilization of Chiral Sulfoxides","volume":"103","author":"Ferna\u0301ndez","year":"2003","journal-title":"Chem. Rev."},{"key":"2026081410095881000_cit1b","doi-asserted-by":"publisher","first-page":"4147","DOI":"10.1021\/acs.chemrev.6b00517","article-title":"Chiral Organosulfur\nLigands\/Catalysts with a Stereogenic Sulfur Atom: Applications in\nAsymmetric Synthesis","volume":"117","author":"Otocka","year":"2017","journal-title":"Chem. Rev."},{"key":"2026081410095881000_cit1c","doi-asserted-by":"publisher","first-page":"5026","DOI":"10.1002\/anie.201411073","article-title":"Development of Chiral Sulfoxide Ligands\nfor Asymmetric Catalysis","volume":"54","author":"Trost","year":"2015","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026081410095881000_cit1d","doi-asserted-by":"publisher","first-page":"145","DOI":"10.1080\/10426507.2016.1252366","article-title":"Stereochemistry of organic sulfur\ncompounds: More than 100 years of history, current state and further\nchallenges","volume":"192","author":"Drabowicz","year":"2017","journal-title":"Phosphorus, Sulfur"},{"key":"2026081410095881000_cit1e","doi-asserted-by":"publisher","first-page":"671","DOI":"10.1021\/acssuschemeng.1c07636","article-title":"Prospects and Challenges in Organosulfur\nChemistry","volume":"10","author":"Wang","year":"2022","journal-title":"ACS Sustainable Chem. Eng."},{"key":"2026081410095881000_cit1f","doi-asserted-by":"publisher","first-page":"7699","DOI":"10.1007\/s00253-014-5932-z","article-title":"Biotechnological production\nof chiral organic sulfoxides: current state and perspectives","volume":"98","author":"Matsui","year":"2014","journal-title":"Appl. Microbiol Biot"},{"key":"2026081410095881000_cit2a","doi-asserted-by":"publisher","first-page":"3431","DOI":"10.6023\/cjoc202103046","article-title":"Progress on\nBiological\nActivity Study and Enantioselective Synthesis of Sulfoxides","volume":"41","author":"Zhu","year":"2021","journal-title":"Chin. J. Org. Chem."},{"key":"2026081410095881000_cit2b","doi-asserted-by":"publisher","first-page":"609","DOI":"10.1039\/b418284g","article-title":"Role of sulfur\nchirality in the chemical processes of biology","volume":"34","author":"Bentley","year":"2005","journal-title":"Chem. Soc. Rev."},{"key":"2026081410095881000_cit2c","doi-asserted-by":"publisher","first-page":"4578","DOI":"10.1021\/acs.chemrev.0c00002","article-title":"Modern Stereoselective Synthesis of Chiral Sulfinyl\nCompounds","volume":"120","author":"Wojaczyn\u0301ska","year":"2020","journal-title":"Chem. Rev."},{"key":"2026081410095881000_cit3","doi-asserted-by":"publisher","first-page":"3881","DOI":"10.1021\/acs.jmedchem.9b01663","article-title":"Small-Molecule\nAntagonist Targeting Exportin-1 via Rational Structure-Based\nDiscovery","volume":"63","author":"Tian","year":"2020","journal-title":"J. Med. Chem."},{"key":"2026081410095881000_cit4","doi-asserted-by":"publisher","first-page":"391","DOI":"10.1021\/acs.jmedchem.9b01938","article-title":"Structure-Activity\nRelationships of Novel Thiazole-Based Modafinil Analogues Acting at\nMonoamine Transporters","volume":"63","author":"Kalaba","year":"2020","journal-title":"J. Med. Chem."},{"key":"2026081410095881000_cit5a","doi-asserted-by":"publisher","first-page":"3834","DOI":"10.1039\/C4CS00524D","article-title":"The emergence\nof sulfoxides\nas efficient ligands in transition metal catalysis","volume":"44","author":"Sipos","year":"2015","journal-title":"Chem. Soc. Rev."},{"key":"2026081410095881000_cit5b","doi-asserted-by":"publisher","first-page":"123","DOI":"10.1016\/S0040-4039(00)60073-4","article-title":"C2-Symmetric bis-sulfoxides as chiral\nligands in metal catalysed asymmetric diels-alder reactions","volume":"34","author":"Khiar","year":"1993","journal-title":"Tetrahedron Lett."},{"key":"2026081410095881000_cit5c","doi-asserted-by":"publisher","first-page":"4207","DOI":"10.1002\/anie.201209485","article-title":"Hydrogen-Bond-Promoted Palladium Catalysis: Allylic Alkylation of\nIndoles with Unsymmetrical 1,3-Disubstituted Allyl Acetates Using\nChiral Bis(sulfoxide) Phosphine Ligands","volume":"52","author":"Du","year":"2013","journal-title":"Angew.\nChem., Int. Ed."},{"key":"2026081410095881000_cit5d","doi-asserted-by":"publisher","first-page":"9842","DOI":"10.1002\/anie.201601540","article-title":"C\u2013H Coupling Reactions Directed by Sulfoxides:\nTeaching an Old Functional Group New Tricks","volume":"55","author":"Pulis","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081410095881000_cit5e","doi-asserted-by":"publisher","first-page":"5168","DOI":"10.1055\/a-1930-6979","article-title":"Recent Advances for Chiral Sulfoxides\nin Asymmetric Catalysis","volume":"54","author":"Yang","year":"2022","journal-title":"Synthesis"},{"key":"2026081410095881000_cit5f","doi-asserted-by":"publisher","first-page":"7681","DOI":"10.1002\/anie.201102586","article-title":"Chiral Sulfoxide-Olefin\nLigands: Completely Switchable Stereoselectivity in Rhodium-Catalyzed\nAsymmetric Conjugate Additions","volume":"50","author":"Chen","year":"2011","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026081410095881000_cit5g","doi-asserted-by":"publisher","first-page":"4552","DOI":"10.1021\/ja1005477","article-title":"A C2-Symmetric Chiral Bis-Sulfoxide Ligand in a Rhodium-Catalyzed\nReaction: Asymmetric 1,4-Addition of Sodium Tetraarylborates to Chromenones","volume":"132","author":"Chen","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"2026081410095881000_cit6a","doi-asserted-by":"publisher","first-page":"1049","DOI":"10.1016\/S0040-4039(01)80097-6","article-title":"An efficient asymmetric oxidation\nof sulfides to sulfoxides","volume":"25","author":"Pitchen","year":"1984","journal-title":"Tetrahedron Lett."},{"key":"2026081410095881000_cit6b","doi-asserted-by":"publisher","first-page":"8188","DOI":"10.1021\/ja00338a030","article-title":"An efficient\nasymmetric oxidation of sulfides to sulfoxides","volume":"106","author":"Pitchen","year":"1984","journal-title":"J. Am. Chem. Soc."},{"key":"2026081410095881000_cit6c","doi-asserted-by":"publisher","first-page":"325","DOI":"10.1055\/s-1984-30829","article-title":"Synthesis of Chiral\nSulfoxides by Metal-Catalyzed Oxidation with t-Butyl Hydroperoxide","volume":"1984","author":"Di Furia","year":"1984","journal-title":"Synthesis"},{"key":"2026081410095881000_cit6d","doi-asserted-by":"publisher","first-page":"4225","DOI":"10.1002\/anie.200460236","article-title":"Highly Enantioselective Iron-Catalyzed Sulfide Oxidation with Aqueous\nHydrogen Peroxide under Simple Reaction Conditions","volume":"43","author":"Legros","year":"2004","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081410095881000_cit6e","doi-asserted-by":"publisher","first-page":"13455","DOI":"10.1038\/ncomms13455","article-title":"Bisguanidinium dinuclear oxodiperoxomolybdosulfate\nion pair-catalyzed enantioselective sulfoxidation","volume":"7","author":"Zong","year":"2016","journal-title":"Nat. Commun."},{"key":"2026081410095881000_cit6f","doi-asserted-by":"publisher","first-page":"2402429","DOI":"10.1002\/advs.202402429","article-title":"Bifunctional Squaramide-Catalyzed Oxidative Kinetic\nResolution: Simultaneous Access to Axially Chiral Thioether and Sulfoxide","volume":"11","author":"Wen","year":"2024","journal-title":"Adv. Sci."},{"key":"2026081410095881000_cit6g","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.202400708","article-title":"Recent Advances in\nBiocatalytic Preparation of Chiral Sulfoxides","volume":"14","author":"Song","year":"2025","journal-title":"Asian J. Org. Chem."},{"key":"2026081410095881000_cit7a","doi-asserted-by":"publisher","first-page":"8337","DOI":"10.1021\/jacs.7b03623","article-title":"Palladium-Catalyzed Enantioselective Arylation of Aryl\nSulfenate Anions: A Combined Experimental and Computational Study","volume":"139","author":"Jia","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"2026081410095881000_cit7b","doi-asserted-by":"publisher","first-page":"960","DOI":"10.1021\/acs.orglett.8b03943","article-title":"Palladium-Catalyzed\nEnantioselective Alkenylation of Sulfenate Anions","volume":"21","author":"Wu","year":"2019","journal-title":"Org. Lett."},{"key":"2026081410095881000_cit7c","doi-asserted-by":"publisher","first-page":"3170","DOI":"10.1021\/ol2010962","article-title":"Organocatalytic\nAsymmetric Synthesis of Sulfoxides from Sulfenic Acid Anions Mediated\nby a Cinchona-Derived Phase-Transfer Reagent","volume":"13","author":"Gelat","year":"2011","journal-title":"Org. Lett."},{"key":"2026081410095881000_cit8a","doi-asserted-by":"publisher","first-page":"966","DOI":"10.1002\/chem.201303850","article-title":"Iron-Catalyzed Imidative\nKinetic Resolution of Racemic Sulfoxides","volume":"20","author":"Wang","year":"2014","journal-title":"Chem.\u2500Eur.\nJ."},{"key":"2026081410095881000_cit8b","doi-asserted-by":"publisher","first-page":"3070","DOI":"10.6023\/cjoc201805034","article-title":"Oxidation Kinetics Resolution of Racemic Aromatic Sulfoxides by Chiral\nPorphyrin-Inspired N4 Ligand with Manganese Complex","volume":"38","author":"Yang","year":"2018","journal-title":"Chin. J. Org. Chem."},{"key":"2026081410095881000_cit8c","doi-asserted-by":"publisher","first-page":"4890","DOI":"10.1021\/acscatal.7b00968","article-title":"Highly Chemoselective and Enantioselective Catalytic Oxidation of\nHeteroaromatic Sulfides via High-Valent Manganese(IV)-Oxo Cation Radical\nOxidizing Intermediates","volume":"7","author":"Dai","year":"2017","journal-title":"ACS Catal."},{"key":"2026081410095881000_cit8d","doi-asserted-by":"publisher","first-page":"9849","DOI":"10.1002\/anie.201805858","article-title":"Chemoenzymatic Deracemization of\nChiral Sulfoxides","volume":"57","author":"Nosek","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081410095881000_cit8e","doi-asserted-by":"publisher","first-page":"3284","DOI":"10.1002\/cctc.201800279","article-title":"Biocatalytic\nPreparation of Chiral Sulfoxides through Asymmetric Reductive Resolution\nby Methionine Sulfoxide Reductase A","volume":"10","author":"Peng","year":"2018","journal-title":"ChemCatChem."},{"key":"2026081410095881000_cit8f","doi-asserted-by":"publisher","first-page":"5129","DOI":"10.1002\/anie.201801146","article-title":"Palladium-Catalyzed Enantioselective\nC\u2013H Olefination of Diaryl Sulfoxides through Parallel Kinetic\nResolution and Desymmetrization","volume":"57","author":"Zhu","year":"2018","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026081410095881000_cit8g","doi-asserted-by":"publisher","first-page":"7207","DOI":"10.1021\/acscatal.0c02109","article-title":"Dual-Ligand-Enabled\nIr(III)-Catalyzed Enantioselective C-H Amidation for the Synthesis\nof Chiral Sulfoxides","volume":"10","author":"Liu","year":"2020","journal-title":"ACS Catal."},{"key":"2026081410095881000_cit9a","doi-asserted-by":"publisher","first-page":"1471","DOI":"10.1038\/s41467-025-56860-4","article-title":"Iron-catalysed stereoselective NH\ntransfer enables dynamic kinetic\nresolution of sulfoxides","volume":"16","author":"Fan","year":"2025","journal-title":"Nat. Commun."},{"key":"2026081410095881000_cit9b","doi-asserted-by":"publisher","first-page":"4793","DOI":"10.1038\/s41467-022-32428-4","article-title":"Chalcogen bond-guided conformational isomerization\nenables catalytic dynamic kinetic resolution of sulfoxides","volume":"13","author":"Liu","year":"2022","journal-title":"Nat. Commun."},{"key":"2026081410095881000_cit10a","doi-asserted-by":"publisher","first-page":"317","DOI":"10.1039\/D2SC05310A","article-title":"Rhodium-catalyzed enantioselective\nC-H alkynylation of sulfoxides in diverse patterns: desymmetrization,\nkinetic resolution, and parallel kinetic resolution","volume":"14","author":"Kong","year":"2023","journal-title":"Chem. Sci."},{"key":"2026081410095881000_cit10b","doi-asserted-by":"publisher","first-page":"7910","DOI":"10.1021\/acs.orglett.1c02918","article-title":"Synthesis of Chiral\nSulfoxides via Pd(II)-Catalyzed Enantioselective C-H Alkynylation\/Kinetic\nResolution of 2-(Arylsulfinyl)pyridines","volume":"23","author":"Zhou","year":"2021","journal-title":"Org.\nLett."},{"key":"2026081410095881000_cit11","doi-asserted-by":"publisher","first-page":"3417","DOI":"10.1039\/D3OB00402C","article-title":"Kinetic resolution of sulfoxides with high enantioselectivity using\na new homologue of methionine sulfoxide reductase B","volume":"21","author":"Zhao","year":"2023","journal-title":"Org. Biomol. Chem."},{"key":"2026081410095881000_cit12a","doi-asserted-by":"publisher","first-page":"10788","DOI":"10.1021\/acs.joc.1c01011","article-title":"Nickel-Catalyzed\nAsymmetric Hydrogenation for Kinetic\nResolution of [2.2]Paracyclophane-Derived Cyclic N-Sulfonylimines","volume":"86","author":"Zhao","year":"2021","journal-title":"J. Org. Chem."},{"key":"2026081410095881000_cit12b","doi-asserted-by":"publisher","first-page":"10413","DOI":"10.1021\/jacs.6b06009","article-title":"Kinetic Resolution of Axially Chiral 5- or 8-Substituted\nQuinolines via Asymmetric Transfer Hydrogenation","volume":"138","author":"Wang","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"2026081410095881000_cit12c","doi-asserted-by":"publisher","first-page":"6609","DOI":"10.1039\/D1QO01310F","article-title":"Kinetic resolution of azaflavanones\nvia a RuPHOX-Ru catalyzed asymmetric hydrogenation","volume":"8","author":"Zhu","year":"2021","journal-title":"Org. Chem. Front."},{"key":"2026081410095881000_cit12d","doi-asserted-by":"publisher","first-page":"708","DOI":"10.1021\/jo00238a048","article-title":"Kinetic resolution of racemic allylic alcohols by BINAP-ruthenium(II)\ncatalyzed hydrogenation","volume":"53","author":"Kitamura","year":"1988","journal-title":"J. Org. Chem."},{"key":"2026081410095881000_cit12e","doi-asserted-by":"publisher","first-page":"17426","DOI":"10.1021\/ja510990v","article-title":"Remote Ester Group Leads to Efficient Kinetic Resolution\nof Racemic Aliphatic Alcohols via Asymmetric Hydrogenation","volume":"136","author":"Yang","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"2026081410095881000_cit12f","doi-asserted-by":"publisher","first-page":"1937","DOI":"10.1039\/D0SC05276K","article-title":"Kinetic resolution of racemic allylic alcohols via\niridium-catalyzed asymmetric hydrogenation: scope, synthetic applications\nand insight into the origin of selectivity","volume":"12","author":"Wu","year":"2021","journal-title":"Chem. Sci."},{"key":"2026081410095881000_cit12g","doi-asserted-by":"publisher","first-page":"7019","DOI":"10.1021\/acs.orglett.9b02606","article-title":"Stereoselective Catalytic Synthesis of P-Stereogenic\nOxides via Hydrogenative Kinetic Resolution","volume":"21","author":"Ferna\u0301ndez-Pe\u0301rez","year":"2019","journal-title":"Org. Lett."},{"key":"2026081410095881000_cit12h","doi-asserted-by":"publisher","first-page":"4331","DOI":"10.1002\/ejoc.202000592","article-title":"Exploiting\nSubstrate Diversity for Preparing Synthetically Valuable Sulfoxides\nvia Asymmetric Hydrogenative Kinetic Resolution","volume":"2020","author":"Ferna\u0301ndez-Pe\u0301rez","year":"2020","journal-title":"Eur. J. Org. Chem."},{"key":"2026081410095881000_cit12i","doi-asserted-by":"publisher","first-page":"2603","DOI":"10.1021\/acscatal.9b05444","article-title":"Kinetic Resolution\nof Racemic 3,4-Disubstituted 1,4,5,6-Tetrahydropyridine and 3,4-Disubstituted\n1,4- Dihydropyridines via Rh-Catalyzed Asymmetric Hydrogenation","volume":"10","author":"Li","year":"2020","journal-title":"ACS Catal."},{"key":"2026081410095881000_cit12j","doi-asserted-by":"publisher","first-page":"111929","DOI":"10.1016\/j.cclet.2025.111929","article-title":"Recent advances on\nasymmetric reduction via dynamic kinetic resolution","volume":"37","author":"Zhou","year":"2026","journal-title":"Chin. Chem. Lett."},{"key":"2026081410095881000_cit13","doi-asserted-by":"publisher","first-page":"4114","DOI":"10.1021\/acs.orglett.5b02139","article-title":"Hydrogenative\nKinetic Resolution of Vinyl Sulfoxides","volume":"17","author":"Lao","year":"2015","journal-title":"Org.\nLett."},{"key":"2026081410095881000_cit14","doi-asserted-by":"publisher","first-page":"1749","DOI":"10.1021\/jacs.8b12657","article-title":"Highly Efficient\nEnantioselective Synthesis of Chiral Sulfones by\nRh-Catalyzed Asymmetric Hydrogenation","volume":"141","author":"Yan","year":"2019","journal-title":"J. Am.\nChem. Soc."},{"key":"2026081410095881000_cit15a","doi-asserted-by":"publisher","first-page":"3095","DOI":"10.1021\/acs.orglett.5c00903","article-title":"Diastereo- and Enantioselective Catalytic\nKinetic Resolution of 2-Substituted 3-Nitro-2H-chromenes","volume":"27","author":"Su","year":"2025","journal-title":"Org. Lett."},{"key":"2026081410095881000_cit15b","doi-asserted-by":"publisher","first-page":"633","DOI":"10.1021\/ar030156e","article-title":"On the Mechanism of Stereoselection\nin Rh-Catalyzed Asymmetric Hydrogenation: A General Approach for Predicting\nthe Sense of Enantioselectivity","volume":"37","author":"Gridnev","year":"2004","journal-title":"Acc. Chem.\nRes."},{"key":"2026081410095881000_cit15c","doi-asserted-by":"publisher","first-page":"1539","DOI":"10.1002\/cjoc.70495","article-title":"Enantioselective Synthesis of C-B Axial Chirality via\nIsothiourea-Catalyzed Acylative Kinetic Resolution","volume":"44","author":"Wang","year":"2026","journal-title":"Chin. J. Chem."}],"container-title":["Organic Letters"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.orglett.6c02887","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/orlef7\/article-pdf\/28\/32\/10347\/66354705\/acs.orglett.6c02887.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/orlef7\/article-pdf\/28\/32\/10347\/66354705\/acs.orglett.6c02887.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T14:32:21Z","timestamp":1786717941000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/orlef7\/article\/28\/32\/10347\/5238339\/Kinetic-Resolution-of-Unsaturated-Sulfoxides-via"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,2]]},"references-count":55,"journal-issue":{"issue":"32","published-online":{"date-parts":[[2026,8,2]]},"published-print":{"date-parts":[[2026,8,14]]}},"URL":"https:\/\/doi.org\/10.1021\/acs.orglett.6c02887","relation":{},"ISSN":["1523-7060","1523-7052"],"issn-type":[{"value":"1523-7060","type":"print"},{"value":"1523-7052","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,2]]}}}