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This atom-economical protocol proceeds under mild conditions with broad functional group tolerance and is readily scalable to gram quantities, delivering drug-like scaffolds directly from simple arylethylenes. By obviation of the need for pre-assembled cyclic precursors, this strategy streamlines the fused-ring construction via radical annulation and establishes a powerful platform for C-4 functionalization of pyridines.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03004","type":"journal-article","created":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T21:22:20Z","timestamp":1788211340000},"page":"10995-11000","source":"Crossref","is-referenced-by-count":0,"title":["Photocatalytic\nStyrene [4 + 2] Cycloaddition\/Decyanative\nPyridylation Cascade for the Synthesis of 4-(Tetralyn-1-yl)pyridines"],"prefix":"10.1021","volume":"28","author":[{"given":"Yan","family":"Dai","sequence":"first","affiliation":[{"name":"Zhejiang Sci-Tech University , , , ,","place":["Hangzhou, Zhejiang, P. R. 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