{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T16:11:24Z","timestamp":1789747884136,"version":"4.0.1"},"reference-count":40,"publisher":"American Chemical Society (ACS)","issue":"37","license":[{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100003787","name":"Natural Science Foundation of Hebei Province","doi-asserted-by":"publisher","award":["B2025201101"],"award-info":[{"award-number":["B2025201101"]}],"id":[{"id":"10.13039\/501100003787","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008047","name":"Hebei University","doi-asserted-by":"publisher","award":["IT2023B01"],"award-info":[{"award-number":["IT2023B01"]}],"id":[{"id":"10.13039\/501100008047","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Hebei Province Innovation Capability Enhancement Plan Project","award":["22567632H"],"award-info":[{"award-number":["22567632H"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,18]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>This study reports a novel class of bench-stable, oxime ester-derived bifunctional fluorosulfamoyl reagents for photosensitized 1,n-fluorosulfonamidylimination of alkenes. Upon visible-light irradiation, these reagents undergo energy-transfer-mediated homolysis, simultaneously generating a transient fluorosulfonamide radical and a persistent iminyl radical. This dual-radical system enables efficient 1,2- and 1,4-fluorosulfonamidylimination of alkenes, thereby providing direct access to valuable amino-aliphatic sulfamoyl fluorides under mild conditions. The utility of this method is demonstrated by the late-stage modification of bioactive molecules and further diversification of products via SuFEx click chemistry and selective deprotection.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03073","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T19:57:31Z","timestamp":1788465451000},"page":"11506-11511","source":"Crossref","is-referenced-by-count":0,"title":["Photosensitized\n1,n-Fluorosulfonamidylimination of\nAlkenes to Access Amino-Aliphatic Sulfamoyl Fluorides Using Bifunctional\nFluorosulfonamoyl Reagents"],"prefix":"10.1021","volume":"28","author":[{"given":"Jia-Hua","family":"Yang","sequence":"first","affiliation":[{"name":"Hebei University , , ,","place":["Baoding, P. R. China, 071002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yun-Qi","family":"Lin","sequence":"additional","affiliation":[{"name":"Hebei University , , ,","place":["Baoding, P. R. China, 071002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ni-Ping","family":"Pei","sequence":"additional","affiliation":[{"name":"Hebei University , , ,","place":["Baoding, P. R. China, 071002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian-Hong","family":"Zhang","sequence":"additional","affiliation":[{"name":"Hebei University , , ,","place":["Baoding, P. R. China, 071002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun-Zhao","family":"Ma","sequence":"additional","affiliation":[{"name":"Hebei University , , ,","place":["Baoding, P. R. China, 071002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin","family":"Qi","sequence":"additional","affiliation":[{"name":"Hebei University , , ,","place":["Baoding, P. R. China, 071002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5069-5945","authenticated-orcid":true,"given":"Wei","family":"Li","sequence":"additional","affiliation":[{"name":"Hebei University , , ,","place":["Baoding, P. R. China, 071002"]},{"name":"Hebei University , , ,","place":["Baoding, P. R. China, 071002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2411-2758","authenticated-orcid":true,"given":"Li-Jing","family":"Wang","sequence":"additional","affiliation":[{"name":"Hebei University , , ,","place":["Baoding, P. R. China, 071002"]},{"name":"Hebei University , , ,","place":["Baoding, P. R. China, 071002"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,3]]},"reference":[{"key":"2026091809414163200_cit1a","doi-asserted-by":"publisher","first-page":"9430","DOI":"10.1002\/anie.201309399","article-title":"Sulfur(VI)\nfluoride exchange (SuFEx): another good reaction for click chemistry","volume":"53","author":"Dong","year":"2014","journal-title":"Angew. Chem. Int. Ed."},{"key":"2026091809414163200_cit1b","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202300536","article-title":"Linkage Chemistry of S(VI) Fluorides","volume":"29","author":"Zeng","year":"2023","journal-title":"Chem.\u2500Eur. J."},{"key":"2026091809414163200_cit1c","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwad123","article-title":"Advances in the construction of diverse\nSuFEx linkers","volume":"10","author":"Zeng","year":"2023","journal-title":"Natl. Sci. 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