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Herein, we report a photoinduced, metal-free strategy that generates a ligated boryl radical in situ to activate aliphatic aldehydes, enabling their direct coupling with vinyl halides and alkynyl bromides to afford the corresponding allylic and propargylic alcohols. This method exhibits broad functional group tolerance and is applicable to the late-stage modification of complex molecules. Gram-scale synthesis and product derivatizations further demonstrate the synthetic utility of this protocol.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03086","type":"journal-article","created":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T07:02:08Z","timestamp":1786690928000},"page":"10816-10821","source":"Crossref","is-referenced-by-count":0,"title":["Photoinduced\nReductive Coupling of Aliphatic Aldehydes\nwith Vinyl\/Alkynyl Halides to Access Allylic and Propargylic Alcohols\nvia a Ligated Boryl Radical"],"prefix":"10.1021","volume":"28","author":[{"given":"Ruo-Ping","family":"Zheng","sequence":"first","affiliation":[{"name":"Shantou University , , ,","place":["Shantou, P. R. China, 515063"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ting-Ting","family":"Miao","sequence":"additional","affiliation":[{"name":"Shantou University , , ,","place":["Shantou, P. R. 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