{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T15:08:40Z","timestamp":1789139320154,"version":"build-2803163510"},"reference-count":79,"publisher":"American Chemical Society (ACS)","issue":"36","license":[{"start":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T00:00:00Z","timestamp":1787961600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T00:00:00Z","timestamp":1787961600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T00:00:00Z","timestamp":1787961600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22577011"],"award-info":[{"award-number":["22577011"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013160","name":"Venture and Innovation Support Program for Chongqing Overseas Returnees","doi-asserted-by":"publisher","award":["cx2025044"],"award-info":[{"award-number":["cx2025044"]}],"id":[{"id":"10.13039\/501100013160","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Selenoglycosides display diverse biological activities, yet methods for their efficient and stereoselective syntheses remain underdeveloped. Herein, we present a silver-catalyzed C\u2013Se cross-coupling strategy for the synthesis of a diverse array of (hetero)aryl\/vinyl selenoglycosides from readily accessible glycosylselenosulfonates and boronic acids. This water-compatible protocol features mild conditions, outstanding stereoselectivity, and high functional group tolerance. Mechanistic studies revealed that this reaction follows a radical pathway. Notably, the efficient preparation of selenogliflozin analogues as potential SGLT2 inhibitors highlighted the synthetic practicality of this approach. Collectively, this work provides a practical platform for the rapid and stereoselective construction of Se-glycoside libraries for drug discovery.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03201","type":"journal-article","created":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T13:00:23Z","timestamp":1788354023000},"page":"11264-11270","source":"Crossref","is-referenced-by-count":0,"title":["Stereocontrolled Synthesis of (Hetero)aryl\/vinyl Selenoglycosides\nvia a Silver-Catalyzed Aqueous C\u2013Se Cross-Coupling Reaction"],"prefix":"10.1021","volume":"28","author":[{"given":"Zhiheng","family":"Yue","sequence":"first","affiliation":[{"name":"Chongqing University , , ,","place":["Chongqing, China, 401331"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoxue","family":"Tao","sequence":"additional","affiliation":[{"name":"Chongqing University , , ,","place":["Chongqing, China, 401331"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qili","family":"Jiang","sequence":"additional","affiliation":[{"name":"Chongqing University , , ,","place":["Chongqing, China, 401331"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhihua","family":"Xia","sequence":"additional","affiliation":[{"name":"People\u2019s Hospital of Chongqing Banan District , , ,","place":["Chongqing, China, 401320"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5398-5240","authenticated-orcid":true,"given":"Yuanwei","family":"Dai","sequence":"additional","affiliation":[{"name":"Chongqing University , , ,","place":["Chongqing, China, 401331"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,29]]},"reference":[{"key":"2026091110071395100_cit1","doi-asserted-by":"publisher","first-page":"2357","DOI":"10.1126\/science.1059820","article-title":"Chemical\nglycobiology","volume":"291","author":"Bertozzi","year":"2001","journal-title":"Science"},{"key":"2026091110071395100_cit2a","doi-asserted-by":"publisher","first-page":"729","DOI":"10.1038\/s41580-020-00294-x","article-title":"Global view of human protein glycosylation\npathways and functions","volume":"21","author":"Schjoldager","year":"2020","journal-title":"Nat. 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Chem."},{"key":"2026091110071395100_cit17a","doi-asserted-by":"publisher","first-page":"9107","DOI":"10.1016\/j.tetlet.2004.10.022","article-title":"Homogeneous\nAzidophenylselenylation of Glycals Using TMSN3-Ph2Se2-PhI(OAc)2","volume":"45","author":"Mironov","year":"2004","journal-title":"Tetrahedron\nLett."},{"key":"2026091110071395100_cit17b","doi-asserted-by":"publisher","first-page":"6122","DOI":"10.1021\/jo00074a048","article-title":"Synthesis of phenyl 2-azido-2-deoxy-1-selenoglycosides\nfrom glycals","volume":"58","author":"Santoyo-Gonzalez","year":"1993","journal-title":"J. Org. Chem."},{"key":"2026091110071395100_cit17c","doi-asserted-by":"publisher","first-page":"8256","DOI":"10.1021\/jo00105a051","article-title":"Seleno glycosides.\n2. Synthesis of Phenyl 2-(N-Acetylamino)- and 2-Azido-2-deoxy-1-seleno-\u03b1-D-glycopyranosides\nvia Azido-phenylselenylation of Diversely Protected Glycals","volume":"59","author":"Czernecki","year":"1994","journal-title":"J. Org. 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