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Herein, we report a B(C6F5)3-catalyzed dearomative hydrosilylation of 2,1-borazaronaphthalenes with hydrosilanes, enabling efficient access to BN-isosteres of 1,2-dihydronaphthalenes under mild, metal-free conditions. The method features broad substrate scope, excellent functional-group tolerance, and gram-scale applicability, providing a versatile platform for constructing partially saturated BN bioisosteres.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03267","type":"journal-article","created":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T16:02:08Z","timestamp":1788537728000},"page":"11661-11666","source":"Crossref","is-referenced-by-count":0,"title":["B(C6F5)3-Catalyzed\nDearomative Hydrosilylation of 2,1-Borazaronaphthalenes"],"prefix":"10.1021","volume":"28","author":[{"given":"Chengyu","family":"Du","sequence":"first","affiliation":[{"name":"South-Central Minzu University , , ,","place":["Wuhan, P. R. China, 430074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Panmei","family":"Zhang","sequence":"additional","affiliation":[{"name":"South-Central Minzu University , , ,","place":["Wuhan, P. R. China, 430074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongxia","family":"Li","sequence":"additional","affiliation":[{"name":"Chongqing University , , ,","place":["Chongqing, P. R. China, 401331"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1097-8526","authenticated-orcid":true,"given":"Ruopeng","family":"Bai","sequence":"additional","affiliation":[{"name":"Chongqing University , , ,","place":["Chongqing, P. R. China, 401331"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4960-0838","authenticated-orcid":true,"given":"Hua","family":"Zhang","sequence":"additional","affiliation":[{"name":"South-Central Minzu University , , ,","place":["Wuhan, P. R. 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