{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,29]],"date-time":"2026-10-29T12:08:02Z","timestamp":1793275682847,"version":"4.5.0"},"reference-count":37,"publisher":"American Chemical Society (ACS)","issue":"34","license":[{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["CHE-2235826"],"award-info":[{"award-number":["CHE-2235826"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100005565","name":"Johnson & Johnson Innovative Medicine","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/100005565","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100013994","name":"Nadace Experientia","doi-asserted-by":"publisher","award":["2024\/001\/CHV"],"award-info":[{"award-number":["2024\/001\/CHV"]}],"id":[{"id":"10.13039\/100013994","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,28]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Arylboronic esters are indispensable intermediates in synthesis. We report a direct deaminative borylation of anilines enabled by anomeric amide activation with copper catalysis. The transformation proceeds via in situ generation of aryl radicals from isodiazene intermediates, followed by interception with a Cu\u2013Bpin species derived from bis(pinacolato)diboron. Key to the success of this process is the use of an N-fluorosulfonamide oxidant, which promotes copper catalyst turnover and generates an electrophilic radical competent for polarity-matched hydrogen-atom transfer with the isodiazene intermediate. The method operates under mild conditions, tolerates electron-neutral and electron-rich anilines, and is applicable to pharmaceutically relevant substrates. The resulting aryl boronates can be further elaborated through oxidation or Suzuki\u2013Miyaura cross-coupling, enabling modular C\u2013C bond formation from simple aniline precursors.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03334","type":"journal-article","created":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T08:02:04Z","timestamp":1786435324000},"page":"10882-10886","source":"Crossref","is-referenced-by-count":2,"title":["Copper-Catalyzed\nDirect Deaminative Borylation of\nAnilines \u2013 A Retro-Chan\u2013Evans\u2013Lam Reaction"],"prefix":"10.1021","volume":"28","author":[{"given":"Va\u0301clav","family":"Chmela","sequence":"first","affiliation":[{"name":"University of Chicago , , , ,","place":["Chicago, Illinois, United States, 60637"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Caroline N.","family":"Broude","sequence":"additional","affiliation":[{"name":"University of Chicago , , , ,","place":["Chicago, Illinois, United States, 60637"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5530-8606","authenticated-orcid":true,"given":"Christopher B.","family":"Kelly","sequence":"additional","affiliation":[{"name":"Johnson & Johnson Innovative Medicine , , , ,","place":["Spring House, Pennsylvania, United States, 19477"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4461-363X","authenticated-orcid":true,"given":"Mark D.","family":"Levin","sequence":"additional","affiliation":[{"name":"University of Chicago , , , ,","place":["Chicago, Illinois, United States, 60637"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,11]]},"reference":[{"issue":"21","key":"2026090200203755200_cit1","doi-asserted-by":"publisher","first-page":"5062","DOI":"10.1002\/anie.201107017","article-title":"Palladium-Catalyzed\nCross-Coupling: A Historical Contextual Perspective to the 2010 Nobel\nPrize","volume":"51","author":"Johansson Seechurn","year":"2012","journal-title":"Angew. 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